长江经济带知识产权空间格局与区域经济发展耦合性研究

区域创新能力差异与协调性的研究对推动长江经济带发展具有重要的现实意义。知识产权资源是创新发展的基础,知识产权区域布局更是与经济发展息息相关。该文构建知识产权发展水平评价指标体系,基于空间自相关、象限法以及耦合协调度等研究方法,研究长江经济带知识产权区域布局及空间演化,并与经济发展进行耦合关系的分析。研究发现:近年来长江经济带的知识产权资源快速发展,具有明显的空间集聚性,表现出东高西低的布局特征;东部的长三角地区是知识产权发展水平较好同时较为均衡的区域;整体上知识产权与经济发展具有较好的耦合关系,但经济发展水平较高的城市,多数城市的知识产权布局仍略为滞后于经济发展,因此创新驱动仍成为制约长江经济带经济发展的关键因素。     

Increasing the recovery of heavy metal ions using two microbial fuel cells operating in parallel with no power output

The present study aimed to improve the performance of microbial fuel cells (MFCs) by using an intermittent connection period without power output. Connecting two MFCs in parallel improved the voltage output of both MFCs until the voltage stabilized. Electric energy was accumulated in two MFCs containing heavy metal ions copper, zinc, and cadmium as electron acceptors by connection in parallel for several hours. The system was then switched to discharge mode with single MFCs with a 1000-Ω resistor connected between anode and cathode. This method successfully achieved highly efficient removal of heavy metal ions. Even when the anolyte was run in sequencing batch mode, the insufficient voltage and power needed to recover heavy metals from the cathode of MFCs can be complemented by the developed method. The average removal ratio of heavy metal ions in sequencing batch mode was 67 % after 10 h. When the discharge time was 20 h, the removal ratios of zinc, copper, and cadmium were 91.5, 86.7, and 83.57 %, respectively; the average removal ratio of these ions after 20 h was only 52.1 % for the control group. Therefore, the average removal efficiency of heavy metal ions increased by 1.75 times using the electrons stored from the bacteria under the open-circuit conditions in parallel mode. Electrochemical impedance data showed that the anode had lower solution resistance and polarization resistance in the parallel stage than as a single MFC, and capacitance increased with the length of time in parallel.

     

Deep learning architecture for air quality predictions

With the rapid development of urbanization and industrialization, many developing countries are suffering from heavy air pollution. Governments and citizens have expressed increasing concern regarding air pollution because it affects human health and sustainable development worldwide. Current air quality prediction methods mainly use shallow models; however, these methods produce unsatisfactory results, which inspired us to investigate methods of predicting air quality based on deep architecture models. In this paper, a novel spatiotemporal deep learning (STDL)-based air quality prediction method that inherently considers spatial and temporal correlations is proposed. A stacked autoencoder (SAE) model is used to extract inherent air quality features, and it is trained in a greedy layer-wise manner. Compared with traditional time series prediction models, our model can predict the air quality of all stations simultaneously and shows the temporal stability in all seasons. Moreover, a comparison with the spatiotemporal artificial neural network (STANN), auto regression moving average (ARMA), and support vector regression (SVR) models demonstrates that the proposed method of performing air quality predictions has a superior performance.     

欧美经验对我国“十三五”大气污染防治战略的启示

当前,我国大气污染形势严峻,复合型污染特征突出。新修订的《中华人民共和国环境保护法》、《中华人民共和国大气污染防治法》、《环境空气质量标准》以及《大气污染防治行动计划》的发布和实施,对我国大气污染防治工作提出了更高要求。"十三五"时期是我国环境保护负重前行困难期和大有作为关键期,也是我国改善大气环境质量的攻坚期,需要系统谋划大气污染防治战略。欧盟和美国在制定大气污染防治战略时,以改善空气质量为核心,构建了涵盖一次污染物和二次污染物的多污染物目标体系,规定了环境浓度、排放量、直观感受(能见度)、健康以及管理等约束性指标,并且针对大气污染防治政策分析实施的成本与收益,开发相应的模型工具,基于收益成本比进行科学决策。本文对欧美环境规划和战略中的多污染物协同控制目标体系以及大气污染防治政策成本效益评估经验进行梳理,分析我国大气污染防治战略的现状和问题,并提出相关政策建议,以期为解决"心肺之患"、实现环保"十三五"总体目标提供参考。     

基于安徽省土地利用变化的地形梯度效应分析

为揭示地形因素与土地利用空间格局演变的关系,以安徽省2000年、2005年以及2010年Landsat TM影像和DEM数据为数据源,利用坡向、地形起伏度、坡度变率和地形位指数多种地形因子,并结合地学信息图谱分析理论从综合角度系统研究土地利用结构时空分异格局在地形梯度上的变化特点及其规律。结果表明:1)研究区主要的土地利用类型是耕地和林地,其次是建设用地和未利用土地,且建设用地面积逐期增加趋势显著。2)2000~2010年研究区不同土地利用类型在不同地形梯度区间的分异规律存在明显差异。低地形梯度范围是耕地、水域和建设用地的优势分布区;中地形梯度范围是草地的集中分布区;林地的优势分布区集中在高地形梯度范围。3)2000~2010年研究区土地利用图谱以稳定型和后期变化型为主,低地形梯度和高地形梯度是稳定型图谱的集中分布区,中低、中高和高地形梯度范围是后期变化型图谱的优势分布区。2000~2005年林地的优势分布区有向较低地形位梯度扩张的趋势,其中,耕地是主要的转入来源。2005~2010年耕地的优势分布区有向较高地形位梯度扩张的趋势,变化模式主要为:"林地–耕地"、"未利用地–耕地"和"草地–耕地"。     

湖北省生态足迹和生态承载力时空动态研究

研究湖北省内部可持续发展的趋势,以2005年、2010年、2013年统计数据为基础,应用生态足迹分析法核算湖北省17个市(州、林区)在三个时间节点的生态足迹与生态承载力,对各地区生态足迹和生态盈亏状况从时间和空间上进行动态研究。研究结果表明:湖北省17个市(州、林区)的总生态足迹和人均生态足迹呈迅速增长趋势,其中中部地区增长最快;2005年生态赤字最为严重的地区集中于以武汉为代表的中东部,2013年生态赤字最为严重的地区集中于中西部,生态赤字空间分布的重心逐渐由东部向西部转移;6种生态生产性土地增长速度由快到慢依次是建筑用地、化石能源、草地、水域、林地和耕地,其中潜江、恩施、天门、仙桃、黄冈等地建筑用地生态足迹增速最快,十堰、鄂州、黄石、荆州、荆门等地则是水域生态足迹增速最快,草地、水域、化石能源用地和耕地的生态足迹增长共同决定各地区人均生态足迹的变化趋势。     

Levels and distribution of Dechloranes in sediments of Lake Taihu,China

The occurrence and spatial distribution of dechloranes including mirex, dechlorane plus (DP), dechlorane (Dec) 602, Dec 603, and Dec 604 in surficial sediments of Lake Taihu were investigated in this study. The concentrations of mirex and DP ranged from below detection limit (BDL) to 1.29 ng g^?1 dw and 0.051 to 2.10 ng g^?1 dw, respectively. Dec 602, Dec 603, and Dec 604 on the other hand, were BDL in any of the samples. The contamination levels of DP were higher than that of Mirex at 21 of all 22 sampling sites. Levels of mirex and DP in the lake sediments were correlated when an extremely high mirex value was removed. Both mirex and DP levels were correlated with the amount of organic matters in the sediment samples. Spatial distribution of mirex and DP suggested that these two chemicals in the lake had similar input sources except for one site. Comparison to previously reported flame retardants’ levels in the sediments shows that DP levels were similar with the levels of tetrabromobisphenol A, hexabromocyclododecane but lower than PBDEs and organophosphates levels in Lake Taihu. The higher levels in the north-east part of Lake Taihu adjacent to two major cities: Wuxi and Suzhou, indicated that city effluent might be a major source for DP contamination in the lake.     

改性糠醛渣吸附脱硫废水中钙离子

石灰石-石膏法烟气脱硫技术中石灰石利用率低导致钙流失严重,为实现脱硫废水中Ca2+的资源化利用,进行糠醛渣改性和Ca2+的吸附特性研究。实验结果表明,利用H3PO4改性后的糠醛渣对脱硫废水中Ca2+具有较高的吸附率;在振荡的前30 min吸附率上升极快,至90 min时基本达到平衡吸附量;对Ca2+浓度对吸附率影响研究结果表明,平衡吸附量与平衡浓度关系符合Langmuir等温吸附方程;在初始Ca2+浓度为300 mg/L的溶液中加入3 g吸附剂,温度30℃条件下振荡90 min,平衡吸附量为8.41 mg/g。     

腐植酸强化苯酚厌氧发酵降解

在无外加电子受体的条件下,首次研究了腐植酸对活性污泥厌氧降解苯酚的影响。研究结果表明,腐植酸Suwannee River Humic Acid Standard(SR-HA)、Leonardite Humic Acid Standard(L-HA)和Pahokee Peat Humic Acid(PP-HA)作为氧化还原介体能够提高苯酚的厌氧发酵降解效率。其中腐植酸PP-HA对苯酚的厌氧降解表现出了最为明显的强化效果,反应进行36 h后,苯酚去除率提高了18.5%。当单独投加的PP-HA浓度在0至100 mg/L范围内,苯酚的厌氧降解效率随着腐植酸浓度增加而逐渐提高,而浓度大于100 mg/L后,腐植酸对苯酚降解效率的促进作用随着PP-HA浓度的增加逐渐减缓。除此之外,当低浓度的蒽醌-2-磺酸钠(AQS)(0.02 m M)和PP-HA(20 mg/L)在反应体系中共存时,相比于无介体存在的对照组,苯酚厌氧降解效率提高了约1.4倍。产物分析结果表明,乙酸和CH4作为苯酚发酵降解的重要产物被检测出来。最后,在氧化还原介体腐植酸的存在下,初步探讨了苯酚厌氧发酵降解的代谢途径。     

Pseudomonas sp.fz胞外分离物降解四溴双酚A

四溴双酚A(TBBPA)是全球消耗量最大的溴系阻燃剂。通过活性物质的定位、分离和TBBPA产物的分析等步骤,对Pseudomonas sp.fz胞外分离物降解TBBPA进行了研究。结果表明,存在于胞外的活性物质通过异丙基断裂和脱溴两条途径降解TBBPA。通过超滤,Sephadex G-10分离纯化得到了具有降解活性的小分子物质,分子量约为376~456 Da,初步鉴定为短肽类物质。这种小分子物质具有很好的热稳定性(30~80℃),在弱酸性条件下(2.0~5.0)活性较高,其活性还受金属离子、氧气和抑制剂(Na N3)的影响。此外,部分纯化的小分子物质在一定条件下能够产生羟基自由基(·OH)。