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791.
Perfluorooctanoic acid(PFOA)is recalcitrant to degrade and mineralize.Here,the effect of temperature on the photolytic decomposition of PFOA was investigated.The decomposition of PFOA was enhanced from 34% to 99% in 60 min of exposure when the temperature was increased from 25 to 85°C under UV light(201–600 nm).The limited degree of decomposition at 25°C was due to low quantum yield,which was increased by a factor of 12 at 85°C.Under the imposed conditions,the defluorination ratio increased from 8% at 25°C to 50% at85°C in 60 min.Production of perfluorinated carboxylic acids(PFCAs,C7–C5),PFCAs(C4–C3)and TFA(trifluoroacetic acid,C2)accelerated and attained a maximum within 30 to 90 min at 85°C.However,these reactions did not occur at 25°C despite extended irradiation to180 min.PFOA was decomposed in a step-wise process by surrendering one CF2unit.In each cyclical process,increased temperature enhanced the quantum yields of irradiation and reactions between water molecules and intermediates radicals.The energy consumption for removing eachμmol of PFOA was reduced from 82.5 k J at 25°C to 10.9 k J at 85°C using photolysis.Photolysis coupled with heat achieved high rates of PFOA degradation and defluorination. 相似文献
792.
Yan Zhang Lujun Chen Renhua Sun Tianjiao Dai Jinping Tian Wei Zheng Donghui Wen 《环境科学学报(英文版)》2016,28(6):57-68
Anthropogenic activities usually contaminate water environments, and have led to the eutrophication of many estuaries and shifts in microbial communities. In this study, the temporal and spatial changes of the microbial community in an industrial effluent receiving area in Hangzhou Bay were investigated by 454 pyrosequencing. The bacterial community showed higher richness and biodiversity than the archaeal community in all sediments. Proteobacteria dominated in the bacterial communities of all the samples; Marine_Group_Ⅰ and Methanomicrobia were the two dominant archaeal classes in the effluent receiving area. PCoA and AMOVA revealed strong seasonal but minor spatial changes in both bacterial and archaeal communities in the sediments. The seasonal changes of the bacterial community were less significant than those of the archaeal community, which mainly consisted of fluctuations in abundance of a large proportion of longstanding species rather than the appearance and disappearance of major archaeal species. Temperature was found to positively correlate with the dominant bacteria, Betaproteobacteria, and negatively correlate with the dominant archaea,Marine_Group_Ⅰ; and might be the primary driving force for the seasonal variation of the microbial community. 相似文献
793.
采用农药三唑醇生产过程中产生的含铝酸性废水为原料,合成了聚合硫酸铝(PAS)液体混凝剂,并用于厂区污水站好氧池出水的混凝处理。考察了碱化剂用量、聚合温度、聚合时间等合成条件及PAS加入量、混凝pH等混凝条件对混凝效果的影响,并比较了PAS与商售聚合氯化铝(PAC)的混凝效果。实验结果表明:在n(碱化剂)∶n(硫酸铝)为2.1∶1、聚合温度为80℃、聚合时间为60 min的条件下,所得PAS液体混凝剂产品的w(Al2O3)为7.8%~9.0%,盐基度为45%~60%,pH为3.5~4.0,产量为0.75 t/t(以废水计);在PAS加入量为2.0 m L/L、混凝pH为10.0时,COD和SS的去除率则分别达到14.6%和83.0%;该PAS可替代厂区常规使用的商售PAC,日节约废水处理成本5 922元。 相似文献
794.
Modified soils(MSs) are being increasingly used as geo-engineering materials for the sedimentation removal of cyanobacterial blooms. Cationic starch(CS) has been tested as an effective soil modifier, but little is known about its potential impacts on the treated water.This study investigated dissolved organic matters in the bloom water after algal removal using cationic starch modified soils(CS-MSs). Results showed that the dissolved organic carbon(DOC) could be decreased by CS-MS flocculation and the use of higher charge density CS yielded a greater DOC reduction. When CS with the charge density of 0.052, 0.102 and0.293 meq/g were used, DOC was decreased from 3.4 to 3.0, 2.3 and 1.7 mg/L, respectively.The excitation–emission matrix fluorescence spectroscopy and UV254 analysis indicated that CS-MS exhibits an ability to remove some soluble organics, which contributed to the DOC reduction. However, the use of low charge density CS posed a potential risk of DOC increase due to the high CS loading for effective algal removal. When CS with the charge density of 0.044 meq/g was used, DOC was increased from 3.4 to 3.9 mg/L. This study suggested, when CS-MS is used for cyanobacterial bloom removal, the content of dissolved organic matters in the treated water can be controlled by optimizing the charge density of CS. For the settled organic matters, other measures(e.g., capping treatments using oxygen loaded materials) should be jointly applied after algal flocculation. 相似文献
795.
796.
为掌握长春市主城区净月大学城区PM2.5和PM10质量浓度的空间分布特征,选择了8处室外环境空间,使用YT-HPC3000 C型主动采样激光粉尘仪,对各样点进行了质量浓度监测。结果表明,与区域内室外8处样点的PM10质量浓度,以轻轨站处为最高,其他7处样点均好于二级标准;室内4处样点的PM2.5和PM10的质量浓度,食堂均未达标,其他3处样点均达标。在室内各样点,PM2.5与PM10的浓度空间分布呈现随高度升高而降低的趋势;在室外各样点,PM2.5与PM10的浓度分布与其所处垂向位置无明显相关关系。 相似文献
797.
Regional Environmental Change - China has a history and reputation of substantial exploitation of wildlife, and the harvest and trade of wild birds are common throughout the country, both for... 相似文献
798.
Sediment-water distribution of perfluorooctane sulfonate (PFOS) in Yangtze River Estuary 总被引:2,自引:0,他引:2
Analysis of Perfluorooctane sulfonate (PFOS) distribution in water and sediment in Yangtze River Estuary showed that the estuary was a sink for PFOS. Salinity was an important parameter in controlling the sediment-water interactions and the fate or transport of PFOS in the aquatic environment. As the salinity (S‰) increased from 0.18 to 3.31, the distribution coefficient (Kd) between sediment and water linearly increased from 0.76 to 4.70 L g−1. The study suggests that PFOS may be carried with the river water and transported for long distances before it reaches to the sea and largely scavenged to the sediment in the estuaries due to the dramatic change in salinity. 相似文献
799.
SUMMARY During the past half century, China has experienced increasingly severe land degradation, soil erosion, and desert expansion. Desertification is affecting one third of China's total territory and the annual accelerating rate of desertification spread is as high as 2460 km2 in China. In 1996, China developed a National Action Programme to Combat Desertification (NAP), which is aimed to apply new legal measures and technical approaches to slow down desertification processes and achieve a long-term goal — control desertification and alleviate poverty through continuous efforts to fight against desertification, stabilize mobile dunes, revegetate degraded rangeland and control soil erosion in arid, semi-arid, and dry sub-humid areas. The long-term and integrated strategies of China's NAP result in encouragement of social participation, legal institutional guarantees, policy making, and establishment of demonstrations/pilot projects to combat desertification at both national and provincial level. 相似文献
800.
The genotypic compositions of two populations of the brooding coral, Pocillopora damicornis, were studied by exhaustive sampling of adult colonies on a fine scale in southern Taiwan. In addition, 100 larvae were randomly
selected among more than 1,000 brooded larvae collected from a single broodparent within each population. Using 7 polymorphic
microsatellite markers, both populations were found to be highly clonal, and 7 clonal lineages were characterized. One clonal
lineage (C1) dominated both study areas and comprises 54.9% of all colonies sampled, while any of the other 6 clonal lineages
represented no more than 5%. Among the 100 larvae randomly selected for genotyping from each broodparent, the extent of clonal
reproduction was high, and only 29 and 6 larvae, respectively, were found to be genotypically different from their broodparent.
Among the 35 genotypically distinct larvae, 33 were thought to be derived from sexual reproduction, and 2 were assumed to
be clonal propagules that had undergone somatic mutations. Two genotypically identical larvae were also found in one of the
2 sexually derived larva arrays, indicating the possible existence of polyembryony. The high proportions of clonality in both
adult colonies and brooded larvae suggest that asexually produced larvae might significantly contribute to the recruitment
of local populations. The dense clonal population of P. damicornis in the study area favors the quick recolonization view of clonal propagules after disturbances. 相似文献