Medical radioisotopes in the environment – following the pathway from patient to river sediment

Motivated by the detection of ¹³¹I in river sediment in routine long-term surveillance samples, a systematic short-term study of the wastewater treatment chain was planned and conducted. Inflow, effluent and primary sludge were collected on a daily basis during two weeks at a regional wastewater treatment plant. Samples were investigated by gamma spectroscopy. Four medically used isotopes could be identified (¹³¹I and ^99mTc regularly, ¹⁵³Sm and ¹²³I sporadically). The concentration levels coincide well with literature data for ¹³¹I, and with our own long-term data for ¹³¹I and ^99mTc for the same plant. Cosmogenic ⁷Be activity in primary sludge correlated well with rainfall intensity. Surface sediment was sampled at low tide at both shores of the river, up- and downstream of the plant. ¹³¹I was identified in all samples, with a sharp maximum (about 100 Bq kg⁻¹ d.m.) at the discharge point of the plant and lower levels elsewhere, decreasing monotonically in downstream direction. ⁷Be and ¹³⁷Cs showed the same behaviour, but no peak at the discharge point. Predictions from simple equilibrium models for the transport and sedimentation of ¹³¹I show good agreement with the experimental data and suggest that the wastewater treatment plant is the main source for this isotope.     

Valorisation of crude earth as sustainable building material: a case of international cooperation in the Logone Valley (Chad–Cameroon)

Deforestation is one of the most dramatic threats to environmental equilibrium and food safety in many regions of the world, and particularly in sub-Saharan Africa. It is enhanced by many kinds of human activities, among which is the earth brick-firing process that needs large amounts of wood for attaining and maintaining temperatures required during this process. In order to reduce deforestation, the present study investigated from different points of view the potential of crude earth to be used as building material, taking as a case study the Logone Valley located at the border between Chad and Cameroon. First, an on-site investigation was made to verify the state-of-the-art of brick production technologies and to evaluate their impact on the environment. Subsequently, morphological and geotechnical analyses on soil samples collected from different sites of the Logone Valley were carried out, to evaluate their suitability to brick production. Finally, a pilot plant for crude earthen brick production was set, particularly based on a new press designed for this purpose.     

Cork stoppers as an effective sorbent for water treatment: the removal of mercury at environmentally relevant concentrations and conditions

The technical feasibility of using stopper-derived cork as an effective biosorbent towards bivalent mercury at environmentally relevant concentrations and conditions was evaluated in this study. Only 25 mg/L of cork powder was able to achieve 94 % of mercury removal for an initial mercury concentration of 500 μg/L. It was found that under the conditions tested, the efficiency of mercury removal expressed as equilibrium removal percentage does not depend on the amount of cork or its particle size, but is very sensitive to initial metal concentration, with higher removal efficiencies at higher initial concentrations. Ion exchange was identified as one of the mechanisms involved in the sorption of Hg onto cork in the absence of ionic competition. Under ionic competition, stopper-derived cork showed to be extremely effective and selective for mercury in binary mixtures, while in complex matrices like seawater, moderate inhibition of the sorption process was observed, attributed to a change in mercury speciation. The loadings achieved are similar to the majority of literature values found for other biosorbents and for other metals, suggesting that cork stoppers can be recycled as an effective biosorbent for water treatment. However, the most interesting result is that equilibrium data show a very rare behaviour, with the isotherm presenting an almost square convex shape to the concentration axis, with an infinite slope for an Hg concentration in solution around 25 μg/L.     

Analyses of platinum group elements in mosses as indicators of road traffic emissions in Austria

The concentrations of platinum group elements (PGE; platinum, palladium, rhodium) and 17 other elements in mosses growing at 32 sampling sites along 12 roads in Austria were analysed. The study included passive monitoring of naturally growing mosses with an experimental design using mosses samples exposed in a tunnel experiment. PGEs (Pt, Pd, Rh) were analysed by ICP-MS (ELAN DRC II, Perkin Elmer SCIEX) according to EN ISO 17294-2 Tl.29. Mean concentrations of PGEs in five moss species were: Pt 7.07±9.97, Pd 2.8±5.2 und Rh 0.6±0.8 ng g⁻¹ dry weight. This is comparable to data derived from measurements of gasoline autocatalyst emissions or airborne particles (<10 μm). Compared to soils and road dust along highways, concentrations in mosses were lower by a factor of ten, compared to grasses they were comparable or somewhat higher. The ratios between the various PGEs were calculated as follows (mean values): Pt/Pd 7.9±10.2, Pt/Rh 12.6±8.3 and Pd/Rh 3.7±2.2. The number of light duty vehicles (<3.5 t) and the distance from the road were the main influential factors for PGE concentrations. Especially strong correlations could be found between Pt and Sb, Cu, Zn, and Cd (in decreasing order), which are all elements derived mainly from road traffic emissions. Cluster analysis (Partioning Around Medoids Method) separated elements derived mainly from soil dust (Ca, Al). An analysis of spatial deposition patterns of PGEs showed a reciprocal decrease of concentrations with increasing distance from the road, reaching background values at distances between 10 and 200 m, sometimes even more, but outside the spatial range of our investigation.     

Orchard management under the effects of climate change: implications for apple,plum, and almond growing

Environmental Science and Pollution Research - The authors analyzed certain species and varieties of fruit tree in which applied crop technology is used and also undergoes the effects of climate...     

Planning in collaborative wildlife management: A critical perspective

Wildlife managers are increasingly faced with planning and implementing wildlife management programs in collaboration with local governments, user groups, businesses and citizens. The planning process is inherently political as each group attempts to advance its interests. Current scholarship on the theory and practice of planning for wildlife management falls short of accounting for the politics of these processes. It is hoped that this paper will contribute to a theory of planning that both addresses the actual practices of wildlife planners and serves as a guide for future action. To this end, the dominant conceptualization of wildlife planning will be outlined and the study will draw on empirical and theoretical advances in the fields of adult education, organizational analysis and regional planning to construct a more politically-informed theoretical framework for understanding wildlife planning. This framework asserts that planning involves two types of negotiation of power and interests: (1) substantive negotiations which address procedural aspects of planning and (2) meta-negotiations which address political dynamics of planning. An earlier study will then be re-analyzed to illustrate how substantive and meta-negotiations occurred in a case of suburban deer management in the Northeast United States. It is concluded that accounting for issues of power and interests in wildlife planning theory provides a more complete representation of what wildlife managers actually do when planning programs and provides a guide for future wildlife planning practice. Future analyses of planning processes in wildlife management, or natural resources management more broadly, may reveal new insights if the concepts used to guide the analysis reported here provide an understanding of the politics involved.     

Some characteristics of a plume from a point source based on analytical solution of the two-dimensional advection–diffusion equation

The moments of the concentration distribution obtained using a recent analytical solution of the steady-state two-dimensional advection–diffusion equation are presented. The solving methodology is the Generalized Integral Laplace Transform Technique, which allows obtaining a reliable solution of the advection–diffusion equation without any restrictive assumption about the eddy diffusivity coefficients and wind speed profiles. The first four moments and value and position of maximum ground level concentration are calculated. The concentration standard deviation is compared against the semi-empirical ones used in operative Gaussian models.