全文获取类型
收费全文 | 3809篇 |
免费 | 101篇 |
国内免费 | 1346篇 |
专业分类
安全科学 | 209篇 |
废物处理 | 214篇 |
环保管理 | 305篇 |
综合类 | 1862篇 |
基础理论 | 691篇 |
环境理论 | 1篇 |
污染及防治 | 1541篇 |
评价与监测 | 147篇 |
社会与环境 | 125篇 |
灾害及防治 | 161篇 |
出版年
2024年 | 1篇 |
2023年 | 63篇 |
2022年 | 183篇 |
2021年 | 125篇 |
2020年 | 95篇 |
2019年 | 87篇 |
2018年 | 146篇 |
2017年 | 161篇 |
2016年 | 165篇 |
2015年 | 209篇 |
2014年 | 299篇 |
2013年 | 366篇 |
2012年 | 327篇 |
2011年 | 304篇 |
2010年 | 233篇 |
2009年 | 270篇 |
2008年 | 265篇 |
2007年 | 222篇 |
2006年 | 209篇 |
2005年 | 150篇 |
2004年 | 114篇 |
2003年 | 143篇 |
2002年 | 128篇 |
2001年 | 109篇 |
2000年 | 120篇 |
1999年 | 130篇 |
1998年 | 142篇 |
1997年 | 84篇 |
1996年 | 77篇 |
1995年 | 74篇 |
1994年 | 59篇 |
1993年 | 56篇 |
1992年 | 48篇 |
1991年 | 15篇 |
1990年 | 19篇 |
1989年 | 11篇 |
1988年 | 12篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有5256条查询结果,搜索用时 226 毫秒
491.
Guanjie Jiang Yonghong Liu Li Huang Qingling Fu Youjun Deng Hongqing Hu 《环境科学学报(英文版)》2012,24(5):919-925
Lead (Pb) chemical fixation is an important environmental aspect for human health. Phosphate rocks (PRs) were utilized as an adsorbent to remove Pb from aqueous solution. Raw PRs and oxalic acid-activated PRs (APRs) were used to investigate the effect of chemical modification on the Pb-binding capacity in the pH range 2.0-5.0. The Pb adsorption rate of all treatments above pH 3.0 reached 90%. The Pb binding on PRs and APRs was pH-independent, except at pH 2.0 in activated treatments. The X-ray diffraction analysis confirmed that the raw PRs formed cerussite after reacting with the Pb solution, whereas the APRs formed pyromorphite. The Fourier Transform Infrared spectroscopy analysis indicated that carbonate (CO32-) in raw PRs and phosphate (PO43-) groups in APRs played an important role in the Pb-binding process. After adsorption, anomalous block-shaped particles were observed by scanning electron microscopy with energy dispersive spectroscopy. The X-ray photoelectron spectroscopy data further indicated that both chemical and physical reactions occurred during the adsorption process according to the binding energy. Because of lower solubility of pyromorphite compared to cerussite, the APRs are more effective in immobilizing Pb than that of PRs. 相似文献
492.
Ultrafine particle emission characteristics of diesel engine by on-board and test bench measurement 总被引:1,自引:0,他引:1
Cheng Huang Diming Lou Zhiyuan Hu Piqiang Tan Di Yao Wei Hu Peng Li Jin Ren Changhong Chen 《环境科学学报(英文版)》2012,24(11):1972-1978
This study investigated the emission characteristics of ultrafine particles based on test bench and on-board measurements. The bench test results showed the ultrafine particle number concentration of the diesel engine to be in the range of (0.56-8.35) × 108 cm-3. The on-board measurement results illustrated that the ultrafine particles were strongly correlated with changes in real-world driving cycles. The particle number concentration was down to 2.0 × 106 cm-3 and 2.7 × 107 cm-3 under decelerating and idling operations and as high as 5.0 × 108 cm-3 under accelerating operation. It was also indicated that the particle number measured by the two methods increased with the growth of engine load at each engine speed in both cases. The particle number presented a "U" shaped distribution with changing speed at high engine load conditions, which implies that the particle number will reach its lowest level at medium engine speeds. The particle sizes of both measurements showed single mode distributions. The peak of particle size was located at about 50-80 nm in the accumulation mode particle range. Nucleation mode particles will significantly increase at low engine load operations like idling and decelerating caused by the high concentration of unburned organic compounds. 相似文献
493.
494.
495.
496.
497.
描述了散货码头粉尘污染现状,分析比较了几种常用的积尘清扫方法。为了有效清扫散货码头的积尘,提出采用集中式真空吸尘系统。文章从系统形式、水力计算方法和工程实例等方面简单介绍了集中式真空吸尘系统。印尼Paiton燃煤电厂码头工程设计采用了集中式真空吸尘系统进行积尘清扫,工程建成投产一年多来,积尘清扫效果明显,有效地降低了粉尘污染。实例说明,真空吸尘是解决散货码头积尘清扫问题较为有效的方式。 相似文献
498.
Huagang Huang Tingqiang Li D. K. Gupt Zhenli He Xiao-e Yang Bingnan Ni Mao Li 《环境科学学报(英文版)》2012,24(3):376-386
Improving the efficacy of phytoextraction is critical for its successful application in metal contaminated soils. Mineral nutrition affects plant growth and metal absorption and subsequently the accumulation of heavy metal through hyper-accumulator plants. This study assessed the effects of di-hydrogen phosphates (KH2PO4, Ca(H2PO4)2, NaH2PO4 and NH4H2PO4) application at three levels (22, 88 and 352 mg P/kg soil) on Sedum alfredii growth and metal uptake by three consecutive harvests on aged and Zn/Cd combined contaminated paddy soil. The addition of phosphates (P) significantly increased the amount of Zn taken up by S. alfredii due to increased shoot Zn concentration and dry matter yield (DMY) (P<0.05). The highest phytoextraction of Zn and Cd was observed in KH2PO4 and NH4H2PO4 treatment at 352 mg P/kg soil. The amount of Zn removed by phytoextraction increased in the order of 1st clipping<2nd clipping<3rd clipping, and for Cd extraction the order was 2nd clipping<1st clipping<3rd clipping. These results indicate that the application of P fertilizers coupled with multiple cuttings can enhance the removal of Zn and Cd from contaminated soils by S. alfredii, thus shortening the time needed for accomplishing remediation goals. 相似文献
499.
为研究黄河源区多环芳烃(PAHs)的污染历史,于2016年7月在鄂陵湖中采集了沉积物柱芯,采用210Pb定年,利用气相色谱串联三重四级杆质谱仪(GC-MS/MS)分析了16种PAHs,运用有序聚类分析对PAHs的垂向分布进行分带,并采取主成分分析及多元线性回归定量分析了PAHs的来源.结果表明,鄂陵湖沉积柱的沉积速率为0.176cm/a,慢于青藏高原多数湖泊.总PAHs的含量为11.3~54.7ng/g,平均值为29.2ng/g,与其他高原和偏远地区湖泊沉积物相比,处于较低水平,可被视为PAHs的全球沉积物背景值.PAHs的垂向变化分为1948年以前、1948~1976和1976~2016年3个时间段,5~6环PAHs在1948~2016年间呈上升趋势,与青海省人口及大型牲畜数量显著相关,反映了鄂陵湖地区近70a来的人类活动以农牧业为主.PAHs来源分为本地源(23%)以及长距离迁移与本地混合源(77%).本地源的垂向变化与5~6环PAHs一致,代表了青藏高原地区以牛粪饼为主要燃料的生物质燃烧源. 相似文献
500.
Manganese and ammonium pollution in surface water sources has become a serious issue.In this study, a pilot-scale filtration system was used to investigate the effect of ammonium on manganese removal during the simultaneous removal of ammonium and manganese from surface water using a manganese co-oxide filter film(MeO_x ). The results showed that the manganese removal efficiency of MeO_x in the absence of ammonium was high and stable, and the removal efficiency could reach 70% even at 5.5 °C. When the influent ammonium concentration was lower than 0.7 mg/L, ammonium and manganese could be removed simultaneously. However, at an ammonium concentration of 1.5 mg/L, the manganese removal efficiency of the filter gradually decreased with time(from 96% to 46.20%). Nevertheless, there was no impact of manganese on ammonium removal. The mechanism by which ammonium negatively affected manganese removal was investigated, demonstrating that ammonium affected manganese removal mainly through two possible mechanisms. On one hand, the decreased p H caused by ammonium oxidation was unfavorable for the oxidation of manganese by MeO_x ; on the other hand, the presence of ammonium slowed the growth of new MeO_x and retarded the increase in the specific surface area of the Me Ox-coated sand, and induced changes in the morphology and crystal structure of Me Ox. Consequently, the manganese removal efficiency of the filter decreased when ammonium was present in the inlet water. 相似文献