全文获取类型
收费全文 | 21768篇 |
免费 | 260篇 |
国内免费 | 172篇 |
专业分类
安全科学 | 672篇 |
废物处理 | 805篇 |
环保管理 | 3051篇 |
综合类 | 5796篇 |
基础理论 | 4785篇 |
环境理论 | 10篇 |
污染及防治 | 5013篇 |
评价与监测 | 1171篇 |
社会与环境 | 782篇 |
灾害及防治 | 115篇 |
出版年
2022年 | 172篇 |
2019年 | 159篇 |
2018年 | 312篇 |
2017年 | 304篇 |
2016年 | 449篇 |
2015年 | 329篇 |
2014年 | 464篇 |
2013年 | 1532篇 |
2012年 | 582篇 |
2011年 | 796篇 |
2010年 | 682篇 |
2009年 | 774篇 |
2008年 | 812篇 |
2007年 | 832篇 |
2006年 | 729篇 |
2005年 | 645篇 |
2004年 | 668篇 |
2003年 | 592篇 |
2002年 | 565篇 |
2001年 | 698篇 |
2000年 | 497篇 |
1999年 | 345篇 |
1998年 | 272篇 |
1997年 | 248篇 |
1996年 | 248篇 |
1995年 | 304篇 |
1994年 | 311篇 |
1993年 | 269篇 |
1992年 | 278篇 |
1991年 | 268篇 |
1990年 | 286篇 |
1989年 | 261篇 |
1988年 | 208篇 |
1987年 | 216篇 |
1986年 | 216篇 |
1985年 | 215篇 |
1984年 | 237篇 |
1983年 | 222篇 |
1982年 | 240篇 |
1981年 | 245篇 |
1980年 | 198篇 |
1979年 | 194篇 |
1978年 | 175篇 |
1977年 | 153篇 |
1976年 | 149篇 |
1974年 | 151篇 |
1968年 | 157篇 |
1967年 | 184篇 |
1966年 | 154篇 |
1964年 | 152篇 |
排序方式: 共有10000条查询结果,搜索用时 11 毫秒
841.
Thomas H. Hutchinson Amanda Beesley Patricia E. Frickers James W. Readman Jenny P. Shaw Jürg Oliver Straub 《Environment international》2009,35(6):931-936
In case of an avian-influenza-derived human flu pandemic, an inordinately high use of medicines over several weeks is predicted, in particular for the recommended influenza antiviral oseltamivir (Tamiflu). While the risk of oseltamivir to sewage works and freshwater bodies has already been assessed, the fact that a large percentage of the human population worldwide lives relatively close to the sea raises concern for its environmental compatibility in coastal marine waters. The potential risk of high oseltamivir use to the marine compartment is assessed in this publication, based on the 2003 European Community Technical Guidance Document (TGD) for risk assessment. Subchronic embryo–larval ecotoxicity tests with three marine invertebrates (Pomatoceros triqueter, Annelida; Mytilus edulis, Mollusca; Paracentrotus lividus, Echinodermata) and chronic growth inhibition tests with two different groups of marine microalgae (Isochrysis galbana, Haptophyta; Skeletonema costatum, Heterokontophyta) were performed with the active substance oseltamivir carboxylic acid to derive a dependable marine predicted no-effect concentration (PNEC). This was compared to a predicted environmental concentration (PEC) for oseltamivir in coastal waters, based on the worst-case freshwater PEC. The PEC/PNEC risk characterisation ratio for the marine compartment is well below 1, which in the terminology of the TGD signifies no immediate concern. Further, while oseltamivir may be persistent (P), it is not bioaccumulative (B) nor highly ecotoxic (T) and therefore not a PBT substance. In conclusion, even a high pandemic use of oseltamivir would not lead to a significant risk for the marine compartment, in confirmation of the risk assessment for sewage works and freshwaters. 相似文献
842.
L. León Vintró P.I. Mitchell A. Omarova M. Burkitbayev H. Jiménez Nápoles N.D. Priest 《Journal of environmental radioactivity》2009
New data are reported on the concentrations, isotopic composition and speciation of americium, plutonium and uranium in surface and ground waters in the Sarzhal region of the Semipalatinsk Test Site, and an adjacent area including the settlement of Sarzhal. The data relate to filtered water and suspended particulate from (a) streams originating in the Degelen Mountains, (b) the Tel′kem 1 and Tel′kem 2 atomic craters, and (c) wells on farms located within the study area and at Sarzhal. The measurements show that 241Am, 239,240Pu and 238U concentrations in well waters within the study area are in the range 0.04–87 mBq dm−3, 0.7–99 mBq dm−3, and 74–213 mBq dm−3, respectively, and for 241Am and 239,240Pu are elevated above the levels expected solely on the basis of global fallout. Concentrations in streams sourced in the Degelen Mountains are similar, while concentrations in the two water-filled atomic craters are somewhat higher. Suspended particulate concentrations in well waters vary considerably, though median values are very low, at 0.01 mBq dm−3, 0.08 mBq dm−3 and 0.32 mBq dm−3 for 241Am, 239,240Pu and 238U, respectively. The 235U/238U isotopic ratio in almost all well and stream waters is slightly elevated above the ‘best estimate’ value for natural uranium worldwide, suggesting that some of the uranium in these waters is of test-site provenance. Redox analysis shows that on average most of the plutonium present in the microfiltered fraction of these waters is in a chemically reduced form (mean 69%; 95% confidence interval 53–85%). In the case of the atomic craters, the proportion is even higher. As expected, all of the americium present appears to be in a reduced form. Calculations suggest that annual committed effective doses to individual adults arising from the daily ingestion of these well waters are in the range 11–42 μSv (mean 21 μSv). Presently, the ground water feeding these wells would not appear to be contaminated with radioactivity from past underground testing in the Degelen Mountains or from the Tel′kem explosions. 相似文献
843.
Association of plutonium with sediments from the Ob and Yenisey Rivers and Estuaries 总被引:1,自引:0,他引:1
Lindis Skipperud Justin Brown L. Keith Fifield Deborah H. Oughton Brit Salbu 《Journal of environmental radioactivity》2009
The present study applied sequential extraction techniques to investigate the binding and mobility of plutonium (Pu) in sediments from the rivers and estuaries of the Ob and Yenisey. As a study site, the Ob and Yenisey are particularly interesting as both rivers have weapons-grade Pu sources in their catchment areas, including the Russian Pu production and reprocessing plants at Mayak, Tomsk-7 and Krashnoyarsk, and the Semipalantinsk nuclear weapons testing site in Kazakhstan. Plutonium activity and 240Pu/239Pu ratios were determined using accelerator mass spectrometry (AMS). Sequential extractions showed that between 47 and 80% of the Pu in Yenisey River sediments and 35–53% of the Pu in soils around the Techa River are mobilized with weak oxidising agents, which can indicate that Pu is bound to organic material. In contrast, Pu in Ob and Yenisey Estuarine sediments was more strongly bound, with 60–100% being found in the HNO3-extractable fraction. This change in speciation could reflect either that Pu bound to organic material in the Techa and Yenisey River sediments becomes more fixed to the sediments with time, or that organic-bound Pu is mobilized and released to the water when the sediments encounter the more saline water of the Ob and Yenisey estuaries. In general, 240Pu/239Pu ratios were relatively consistent between different extraction fractions, although, in whole sediments, an increase in ratio was observed with distance from the source. This reflects the increased influence of weapon fallout from catchment runoff within the river systems, as compared to the weapons-grade sources close to the production and reprocessing plants. Knowledge of Pu speciation in the Ob and Yenisey Rivers, and the processes controlling its behaviour in estuarine systems, can improve predictions of its transfer and subsequent environmental impact to Arctic Seas. 相似文献
844.
Spohn P Hirsch C Hasler F Bruinink A Krug HF Wick P 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1134-1139
Since the discovery of fullerenes in 1985, these carbon nanospheres have attracted attention regarding their physico/chemical properties. Despite little knowledge about their impact on the environment and human health, the production of fullerenes has already reached an industrial scale. However, the toxicity of C60 is still controversially discussed.The aim of this study was to clarify the biological effects of tetrahydrofuran (THF) suspended C60 fullerene in comparison to water stirred C60 fullerene suspensions. Beyond that, we analyzed the effects on the Crustacea Daphnia magna an indicator for ecotoxicological effects and the human lung epithelial cell line A549 as a simplified model for the respiratory tract.We could demonstrate that water-soluble side products which were formed in THF nC60 suspension were responsible for the observed acute toxic effects, whereas fullerenes themselves had no negative effect regardless of the preparative route on either A549 cell in vitro or D. magna in vivo. 相似文献
845.
846.
K.H. Reckhow S.S. Qian R.D. Harmel 《Journal of the American Water Resources Association》2009,45(2):369-377
Abstract: Multilevel or hierarchical models have been applied for a number of years in the social sciences but only relatively recently in the environmental sciences. These models can be developed in either a frequentist or Bayesian context and have similarities to other methods such as empirical Bayes analysis and random coefficients regression. In essence, multilevel models take advantage of the hierarchical structure that exists in many multivariate datasets; for example, water quality measurements may be taken from individual lakes, lakes are located in various climatic zones, lakes may be natural or man‐made, and so on. The groups, or levels, may effectively yield different responses or behaviors (e.g., nutrient load response in lakes) that often make retaining group membership more effective when developing a predictive model than when working with either all of the data together or working separately with the individuals. Here, we develop a multilevel model of the impact of farm level best management practices (BMPs) on phosphorus runoff. The result of this research is a model with parameters which vary with key practice categories and thus may be used to evaluate the effectiveness of these practices on phosphorus runoff. For example, it was found that the effect of fertilizer application rate on farm‐scale phosphorus loss is a function of the application method, the hydrologic soil group, and the land use (crop type). Further, results indicate that the most effective method for controlling fertilizer loss is through soil injection. In summary, the resultant multilevel model can be used to estimate phosphorus loss from farms and hence serve as a useful tool for BMP selection. 相似文献
847.
Abstract: The potential of remotely sensed time series of biophysical states of landscape to characterize soil moisture condition antecedent to radar estimates of precipitation is assessed in a statistical prediction model of streamflow in a 1,420 km2 watershed in south‐central Texas, Moderate Resolution Imaging Spectroradiometer (MODIS) time series biophysical products offer significant opportunities to characterize and quantify hydrologic state variables such as land surface temperature (LST) and vegetation state and status. Together with Next Generation Weather Radar (NEXRAD) precipitation estimates for the period 2002 through 2005, 16 raw and deseasoned time series of LST (day and night), vegetation indices, infrared reflectances, and water stress indices were linearly regressed against observed watershed streamflow on an eight‐day aggregated time period. Time offsets of 0 (synchronous with streamflow event), 8, and 16 days (leading streamflow event) were assessed for each of the 16 parameters to evaluate antecedent effects. The model results indicated a reasonable correlation (r2 = 0.67) when precipitation, daytime LST advanced 16 days, and a deseasoned moisture stress index were regressed against log‐transformed streamflow. The estimation model was applied to a validation period from January 2006 through March 2007, a period of 12 months of regional drought and base‐flow conditions followed by three months of above normal rainfall and a flood event. The model resulted in a Nash‐Sutcliffe estimation efficiency (E) of 0.45 for flow series (in log‐space) for the full 15‐month period, ?0.03 for the 2006 drought condition period, and 0.87 for the 2007 wet condition period. The overall model had a relative volume error of ?32%. The contribution of parameter uncertainties to model discrepancy was evaluated. 相似文献
848.
Convergence of Culture, Ecology, and Ethics: Management of Feral Swamp Buffalo in Northern Australia
Glenn Albrecht Clive R. McMahon David M. J. S. Bowman Corey J. A. Bradshaw 《Journal of Agricultural and Environmental Ethics》2009,22(4):361-378
This paper examines the identity of Asian swamp buffalo (Bubalus bubalis) from different value orientations. Buffalo were introduced into Northern (Top End) Australia in the early nineteenth century.
A team of transdisciplinary researchers, including an ethicist, has been engaged in field research on feral buffalo in Arnhem
Land over the past three years. Using historical documents, literature review, field observations, interviews with key informants,
and interaction with the Indigenous land owners, an understanding of the diverse views on the scientific, cultural, and economic
significance of buffalo was obtained. While the diverse stakeholders in buffalo exploitation and management have historically
delivered divergent value orientations on the nature of the human–buffalo relationship, we argue that over time there is the
possibility of values and ethical convergence. Such convergence is possible via transdisciplinary and transcultural agreement
on the value stances that constitute the construction of the being or identity of buffalo in the face of the overwhelming
need to manage population density and gross numbers. 相似文献
849.
Many studies on geological carbon dioxide (CO2) storage capacity neglect the influence of complex coupled processes which occur during and after the injection of CO2. Storage capacity is often overestimated since parts of the reservoirs cannot be reached by the CO2 plume due to gravity segregation and are thus not accessible for storage. This work investigates the effect of reservoir parameters like depth, temperature, absolute and relative permeability, and capillary pressure on the processes during CO2 injection and thus on estimates of effective storage capacity. The applied statistical characteristics of parameters are based on a large reservoir parameter database. Different measured relative permeability relations are considered. The methodology of estimating storage capacity is discussed. Using numerical 1D and 3D experiments, detailed time-dependent storage capacity estimates are derived. With respect to the concept developed in this work, it is possible to estimate effective CO2 storage capacity in saline aquifers. It is shown that effective CO2 mass stored in the reservoir varies by a factor of 20 for the reservoir setups considered. A high influence of the relative permeability relation on storage capacity is shown. 相似文献
850.
David Browne Bernadette ORegan Richard Moles 《Waste management (New York, N.Y.)》2009,29(10):2765-2771
This paper aims to measure product and waste flows in an Irish city-region using the principles of metabolism and mass balance. An empirical indicator to measure resource efficiency, using a ratio of waste disposal as a function of product consumption, was developed and it was found that total materials metabolic inefficiency fell by 31% from 0.13 in 1996 to 0.09 in 2002. The paper concludes by analyzing the strengths and weaknesses of this indicator and its potential application in the field of sustainable consumption and resource efficiency as well as making suggestions to improve and strengthen the indicator. 相似文献