全文获取类型
收费全文 | 239篇 |
免费 | 7篇 |
国内免费 | 5篇 |
专业分类
安全科学 | 22篇 |
废物处理 | 6篇 |
环保管理 | 49篇 |
综合类 | 49篇 |
基础理论 | 52篇 |
环境理论 | 1篇 |
污染及防治 | 39篇 |
评价与监测 | 18篇 |
社会与环境 | 13篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 14篇 |
2015年 | 5篇 |
2014年 | 8篇 |
2013年 | 18篇 |
2012年 | 13篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 13篇 |
2006年 | 17篇 |
2005年 | 10篇 |
2004年 | 5篇 |
2003年 | 13篇 |
2002年 | 5篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 1篇 |
排序方式: 共有251条查询结果,搜索用时 15 毫秒
181.
182.
Skipperud L Oughton DH Rosten LS Wharton MJ Day JP 《Journal of environmental radioactivity》2007,98(3):251-263
In recent years, developments in ICP-MS have led to improved methods for determination of long-lived radionuclides. This paper reports the use of NH(4)OH as a matrix modifier and ETV sample introduction for the determination of technetium-99 ((99)Tc) in a variety of environmental and biological samples, using Re as carrier and (99m)Tc as yield monitor in the chemical separation method. Addition of an excess of NH(4)OH led to a stable (99)Tc signal, reduced memory effect, better reproducibility and reduced detection limits. Following radiochemical separation of (99)Tc from the sample matrix, detection limits in the order of a few microBq have been achieved. ETV has also proved applicable for rapid, direct analysis of a number of environmental samples having relatively high concentrations of (99)Tc (sediment extracts and river water close to nuclear installations). However, in this case, control of matrix effects (signal reduction and enhancement) using standard additions is necessary. 相似文献
183.
184.
David C. Snyder James J. Schauer Deborah S. Gross Jay R. Turner 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4033-4042
Single-particle mass spectra were collected using an Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) during December of 2003 and February of 2004 at an industrially impacted location in East St. Louis, IL. Hourly integrated peak areas for twenty ions were evaluated for their suitability in representing metals/metalloids, particularly those reported in the US EPA Toxic Release Inventory (TRI). Of the initial twenty ions examined, six (Al, As, Cu, Hg, Ti, and V) were found to be unsuitable due to strong isobaric interferences with commonly observed organic fragments, and one (Be) was found to have no significant signal. The usability of three ions (Co, Cr, and Mn) was limited due to suspected isobaric interferences based on temporal comparisons with commonly observed organic fragments. The identity of the remaining ions (Sb, Ba, Cd, Ca, Fe, Ni, Pb, K, Se, and Zn) was substantiated by comparing their signals with the integrated hourly signals of one or more isotope ions. When compared with one-in-six day integrated elemental data as determined by X-ray fluorescence spectroscopy (XRF), the daily integrated ATOFMS signal for several metal ions revealed a semi-quantitative relationship between ATOFMS peak area and XRF concentrations, although in some cases comparison of these measurements were poor at low elemental concentrations/ion signals due to isobaric interferences. A method of estimating the impact of local point sources was developed using hourly integrated ATOFMS peak areas, and this method attributed as much as 85% of the concentration of individual metals observed at the study site to local point sources. Hourly surface wind data were used in conjunction with TRI facility emissions data to reveal likely point sources impacting metal concentrations at the study site and to illustrate the utility of using single-particle mass spectral data to characterize atmospheric metals and identify point sources. 相似文献
185.
Vincent Y. Seaman Deborah H. Bennett Thomas M. Cahill 《Atmospheric environment (Oxford, England : 1994)》2009,43(39):6199-6204
Acrolein (2-propenal) is a common constituent of both indoor and outdoor air, can exacerbate asthma in children, and may contribute to other chronic lung diseases. Recent studies have found high indoor levels of acrolein and other carbonyls compared to outdoor ambient concentrations. Heated cooking oils produce considerable amounts of acrolein, thus cooking is likely an important source of indoor acrolein. A series of cooking experiments were conducted to determine the emission rates of acrolein and other volatile carbonyls for different types of cooking oils (canola, soybean, corn and olive oils) and deep-frying different food items. Similar concentrations and emission rates of carbonyls were found when different vegetable oils were used to deep-fry the same food product. The food item being deep-fried was generally not a significant source of carbonyls compared to the cooking oil. The oil cooking events resulted in high concentrations of acrolein that were in the range of 26.4–64.5 μg m?3. These concentrations exceed all the chronic regulatory exposure limits and many of the acute exposure limits. The air exchange rate and the decay rate of the carbonyls were monitored to estimate the half-life of the carbonyls. The half-life for acrolein was 14.4 ± 2.6 h, which indicates that indoor acrolein concentrations can persist for considerable time after cooking in poorly-ventilated homes. 相似文献
186.
Multifoci effects of injustice on counterproductive work behaviors and the moderating roles of symbolization and victim sensitivity 下载免费PDF全文
James J. Lavelle Christopher M. Harris Deborah E. Rupp David N. Herda Randall F. Young M. Blake Hargrove Meghan Ann Thornton‐Lugo Gary C. McMahan 《组织行为杂志》2018,39(8):1022-1039
Past research suggests that employees, in response to workplace experiences, selectively engage in targeted counterproductive work behaviors (CWBs). Taking a retributive justice and target similarity perspective, we predict that employee perceptions of unfairness from the organization uniquely predict CWB specifically targeted at the organization whereas employee perceptions of supervisory unfairness uniquely predict CWB specifically targeted at the supervisor. We further hypothesized that moral identity‐symbolization would strengthen these target‐similar relationships. Finally, drawing from the sensitivity to mean intentions model, we hypothesized that victim sensitivity would not only strengthen these target‐similar relationships but also lead to cross‐foci effects of multifoci fairness perceptions on targets of CWB. Results from 3 field studies of full‐time employees provided support for most of our hypothesized relationships. 相似文献
187.
Philippa Douglas Daniela Fecht Deborah Jarvis 《Frontiers of Environmental Science & Engineering》2021,15(3):40
188.
William S. Linn Edward L. Avol Deborah A. Shamoo Jill D. Whynot Karen R. Anderson Jack D. Hackney 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1323-1328
Young asthmatic adult volunteers (N = 27) were exposed in an environmental chamber to sulfuric acid aerosol at concentrations near 0, 122, 242, and 410 μg/m3, in purified background air at 22° C and 50 percent relative humidity. The polydisperse aerosol had a mass median aerodynamic diameter near 0.6 μm. Exposures occurred in random order at one-week intervals. Each lasted 1 h, during which subjects exercised (mean ventilation 42 L/min) and rested during alternate 10-min periods. Specific airway resistance and forced expiratory function were measured pre-exposure, after the initial exercise, and at end-exposure. Bronchial reactivity was determined by challenge with cold air immediately post-exposure. Symptoms were monitored during exposure for one week afterward. Exercise-induced bronchospasm was observed under all conditions. Physiologic and symptom changes possibly attributable to sulfuric acid exposure were small and not statistically significant. Our largely negative results contrast with positive findings elsewhere at lower acid doses. Possible explanations include different clinical characteristics of subjects and different routes of breathing. 相似文献
189.
Sylvia A. Edgerton Michael W. Holdren Deborah L. Smith Jitendra J. Shah 《Journal of the Air & Waste Management Association (1995)》2013,63(5):729-732
Airborne particulate matter from three ferrous foundries was sampled in granulometric fractions and analyzed by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDXA), X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS) to determine morphology and qualitative bulk and surface chemical compositions. Cluster and principal components analyses (PCA) were used as an aid for interpretation of results. A clear pattern of composition as a function of size emerges; in particular, trace metals accumulate in fine particles and volatile species on the surface of these. Chemical composition changes are also related to daily schedules where applicable: trace metals appear during pouring operations, silicon is generated during mold making and unmolding. Cluster and PCA greatly ease examination of data and offer pictorial representations of results; in particular, the chemical composition versus particle size relationship is very neatly illustrated by PCA graphs. 相似文献
190.
Deborah L. Swackhamer 《环境科学学报(英文版)》1991,3(3):15-21
The prevailing hypothesis, which states that the uptake of HOCs by phytoplankton is controlled by the compound's lipophilicity (Kow) was tested. The approach taken was to determine the factors that controlled the uptake of PCBs by phytoplankton under controlled laboratory conditions, and to develop a model that would describe bioaccumulation of PCBs in phytoplankton.The results demonstrate a relationship of BAF to Kow and to phytoplankton surface properties, as well as the data presented here, support the hypothesis that the mechanism of HOC uptake is a rapid surface sorption followed by a slower transfer into lipids in the cell matrix. The work on the kinetics of uptake indicates that equilibrium is reached slowly and that the rate of uptake is of similar magnitude as phytoplankton growth under normal field conditions.Thus a critical factor that controls the bioaccumulation of HOCs reach equilibrium in phytoplankton itself. 相似文献