胶质芽孢杆菌、黑曲霉及与沸石联合对模拟废水中Fe3+处理研究

研究沸石、胶质芽孢杆菌(Bacillus mucilaginosus)、黑曲霉(Aspergillus Niger)、胶质芽孢杆菌与沸石联合以及黑曲霉与沸石联合对模拟废水中Fe3+的吸附等温曲线,分析它们对Fe3+模拟废水的吸附及絮凝作用。结果表明：沸石对Fe3+吸附作用符合Freundlich方程;胶质芽孢杆菌分泌含...     

低温下混合菌降解柴油过程中脱氢酶活性的变化

研究了低温(10℃)下混合菌降解柴油过程中脱氢酶活性在不同反应时间、柴油初始质量浓度、混合菌液加入量等条件下的变化情况.实验结果表明:在柴油初始质量浓度为 100 mg/L 时,脱氢酶的活性始终较低;在柴油初始质量浓度为 300,600,900 mr,/L 时,反应第 1 天脱氢酶的活性相差不大,随反应时间的延长,柴油...     

Combination with catalyzed Fe(0)-carbon microelectrolysis and activated carbon adsorption for advanced reclaimed water treatment: simultaneous nitrate and biorefractory organics removal

A process combining catalyzed Fe(0)-carbon microelectrolysis (IC-ME) with activated carbon (AC) adsorption was developed for advanced reclaimed water treatment. Simultaneous nitrate reduction and chemical oxygen demand (COD) removal were achieved, and the effects of composite catalyst (CC) addition, AC addition, and initial pH were investigated. The reaction kinetics and reaction mechanisms were calculated and analyzed. The results showed that CC addition could enhance the reduction rate of nitrate and effectively inhibit the production of ammonia. Moreover, AC addition increased the adsorption capacity of biorefractory organic compounds (BROs) and enhanced the degradation of BRO. The reduction of NO₃^?–N at different pH values was consistently greater than 96.9%, and NH₄⁺–N was suppressed by high pH. The presence of CC ensured the reaction rate of IC-ME at high pH. The reaction kinetics orders and constants were calculated. Catalyzed iron scrap (IS)-AC showed much better nitrate reduction and BRO degradation performances than IS-AC and AC. The IC-ME showed great potential for application to nitrate and BRO reduction in reclaimed water.

     

Study on a new correlation between diffusion coefficient and temperature in porous building materials

The diffusion coefficient (D) and partition coefficient (K_ma) are the two important parameters used to predict the volatile organic compound (VOC) emission or sorption characteristics in porous building materials. D and K_ma may be strongly affected by temperature (T). In this study, we derived a new correlation between D and T based on the assumption that molecular diffusion is dominant, and evaluated this correlation using a series of existing experimental data. The modeling results using the new correlation agree well with the experimental data. The correlation would be useful for assessment of indoor air quality under different environmental (temperature) conditions.     

污染物负荷对曝气生物滤池处理效果的影响研究

考察了进水有机负荷和氨氮负荷对曝气生物滤池出水水质的影响.结果表明,系统COD、氨氮和TN的去除率随进水有机负荷的增加而下降,在氨氮为28.3～33.6 mg/L、TN为39.0～45.8 mg/L条件下,有机负荷小于3.53 kg/(ms3·d)时,出水COD、氨氮和TN分别小于50、5、15 mg/L,去除率分别在85%、85%和65%以上;氨氮和TN的去除率随氨氮负荷的增加而下降,在COD为287.6～313.4 mg/L、氨氮负荷小于0.56 kg/(m3·d)时,出水氨氮小于8 mg/L,去除率在85%以上,出水TN小于15mg/L,去除率在65%以上.     

红萍净化水产养殖水体的研究

利用红萍(Azolla)对富营养化水产养殖水体进行净化研究。结果表明,红萍能显著增加水体中的DO,增氧幅度随流量在16.88%～70.46%之间变化,随着养殖水体流经的层数增多或者处理的时间延长,红萍对水体的增氧量加大,水中DO最终趋向一个常数值K;同时,红萍对水体中的NH₃-N和TP都有明显的去除效果,NH₃-N去除率随流量在9.86%～38.90%间波动,TP的去除率则随流量的变化在5.80%～38.43%之间波动。可见,红萍是净化水质的良好材料,能有效改善水产养殖水环境。利用红萍净化水体将为解决高密度集约化水产养殖的瓶颈提供新途径,实现水产养殖用水的封闭循环利用。     

一株高效脱硫脱氨氮菌的分离、鉴定及系统发育分析

从运行稳定的能同步脱臭的曝气生物滤池中采集样品,富集分离获得一株能高效脱硫脱氨氮的菌株TS-1。对分离菌株进行形态观察、生理生化试验及16S rRNA基因序列分析,结果表明,该菌株TS-1为革兰氏阳性菌,杆状;菌落在营养琼脂培养基上呈圆形,表面光滑,乳白色半透明;V-P试验阴性,能水解淀粉和明胶,利用柠檬酸盐生长;对菌株进行16S rRNA的PCR扩增,扩增产物测序结果表明分离菌株TS-1与巨大芽孢杆菌（Bacillus megaterium）同源性达到99%;以16S rRNA同源性为基础构建了包括24株相关种属细菌在内的系统发育树,在系统发育树中,分离菌株TS1与Bacillus megaterium在同一分支。结合形态观察、生理生化试验及16S rRNA基因序列分析结果,将其初步鉴定为巨大芽孢杆菌（Bacillus megaterium）。在常温（30±2）℃、转速为150 r/min的条件下,处理pH 7、S^2-和NH⁺₄-N分别为80 mg/L和88 mg/L的水样40 h,硫化物和氨氮的脱除率分别为91.8%和96.6%。     

高效菌藻塘系统对农村污水中磷的强化去除效果研究

研究了高效菌藻塘系统处理太湖地区农村生活污水除磷效果及其强化措施。高效菌藻塘和水生生物塘HRT分别为8 d和4 d,进水总磷浓度为1.7～17.1 mg/L,出水总磷浓度全年平均值为3.33 mg/L,高效菌藻塘系统的除磷能力欠佳。通过降低水生生物塘内水深、采用废弃石膏作为填料构建了新型复合水生生物塘,HRT=1.6 d条件下,复合水生生物塘出水总磷可保持在1 mg/L以下,可达到GB18918-2002一级B排放标准。     

金融深化对绿色发展的门槛效应分析

在绿色发展的过程中,金融作为现代经济体系中必不可少的一环正扮演着越来越重要的角色。从一般的理论认知和实践而言,可从金融的深化和广化两个角度来看待金融发展。相对金融广化而言,金融深化更能体现金融对于资本的配置功能和金融体系不断完善的过程,它通过引导投资边际收益率促进绿色发展的效率,进而影响整个绿色经济系统的全要素生产率。本文通过构建一个经济内生增长模型来检验金融深化对绿色发展的影响效应,以2003—2014年中国280个地级单元的面板数据为样本,采用面板门槛模型分析其内在作用的非对称性。结果表明:(1)模型推导发现,金融深化作用在不同生产部门所占份额的配置未达到最优时,金融深化对绿色发展存在门槛效应,即金融深化对绿色发展作用存在可能的非对称性;否则,二者以近似对数函数的关系相互作用。(2)实证发现,金融深化对绿色发展在中国地级层面存在一重门槛效应,似然比检验结果表明该门槛效应在1%的临界值下显著,并且其门槛值大小为0.635 5,门限回归结果显示金融深化对绿色发展在门限值前后的偏效应系数分别为-0.056 8和0.129 9,说明中国金融深化与绿色发展的关系呈现库兹涅茨曲线的倒U形形状。(3)稳健性检验发现,控制变量对金融深化导致的绿色发展门槛效应的扰动仅体现在P值的变化范围之内且变化幅度较小,门限值的大小及置信区间不会发生明显变化,反映中国金融深化与绿色发展的关系结构依然稳健。显然,应当大力推进金融深化过程,突破"门槛效应"的制约,充分发挥金融深化对资本的配置效应,从而推动中国绿色发展进程。     

Characteristics of PM<Subscript>2.5</Subscript>, CO<Subscript>2</Subscript> and particle-number concentration in mass transit railway carriages in Hong Kong

Fine particulate matter (PM_2.5) levels, carbon dioxide (CO₂) levels and particle-number concentrations (PNC) were monitored in train carriages on seven routes of the mass transit railway in Hong Kong between March and May 2014, using real-time monitoring instruments. The 8-h average PM_2.5 levels in carriages on the seven routes ranged from 24.1 to 49.8 µg/m³, higher than levels in Finland and similar to those in New York, and in most cases exceeding the standard set by the World Health Organisation (25 µg/m³). The CO₂ concentration ranged from 714 to 1801 ppm on four of the routes, generally exceeding indoor air quality guidelines (1000 ppm over 8 h) and reaching levels as high as those in Beijing. PNC ranged from 1506 to 11,570 particles/cm³, lower than readings in Sydney and higher than readings in Taipei. Correlation analysis indicated that the number of passengers in a given carriage did not affect the PM_2.5 concentration or PNC in the carriage. However, a significant positive correlation (p < 0.001, R ² = 0.834) was observed between passenger numbers and CO₂ levels, with each passenger contributing approximately 7.7–9.8 ppm of CO₂. The real-time measurements of PM_2.5 and PNC varied considerably, rising when carriage doors opened on arrival at a station and when passengers inside the carriage were more active. This suggests that air pollutants outside the train and passenger movements may contribute to PM_2.5 levels and PNC. Assessment of the risk associated with PM_2.5 exposure revealed that children are most severely affected by PM_2.5 pollution, followed in order by juveniles, adults and the elderly. In addition, females were found to be more vulnerable to PM_2.5 pollution than males (p < 0.001), and different subway lines were associated with different levels of risk.