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11.
人工神经网络用于铅的化学形态模拟计算   总被引:1,自引:0,他引:1  
邓勃  莫华 《干旱环境监测》1996,10(3):155-162
用前馈线性网络法求解水体系中Pb(2+)与OH-之间的反应常数,不同训练算法对求解结果的精度、收敛速度及权值均有影响.结果表明,批处理算法的精度最好,权值不出现负值,但运算时间最长;在线算法的精度虽不如批处理算法,而比数据变换-在线算法好,权值有时会出现负值.运算时间较长;数据变换-在线算法的优点是运算时间短,但相对误差较大,权值出现负值的机会多。采用反馈网络模拟计算铅的各种化学形态的浓度.用物料核算的方法对反馈网络模型进行检验表明,此种模型用于平衡计算是可行的,详细分析了理论模拟和实验曲线的差异的原因,温度的影响最小,在4<pH<9时,CO有重要的影响.在国代检验时,n值取整所引入的误差的影响亦不可忽视。从本文的结果可以看到,采用前馈网络和反馈网络相结合的方法考察水体中的化学形态是可行的.从而为解决这一类问题提供了一种可能的途径.  相似文献   
12.
The concentrations of lead, zinc, copper and cadmium accumulated by 12 emergent-rooted wetland plant species including different populations of Leersia hexandra, Juncus effusus and Equisetum ramosisti were investigated in field conditions of China. The results showed that metal accumulation by wetland plants differed among species, populations and tissues. Populations grown in substrata with elevated metals contained significantly higher metals in plants. Metals accumulated by wetland plants were mostly distributed in root tissues, suggesting that an exclusion strategy for metal tolerance widely exists in them. That some species/populations could accumulate relatively high metal concentrations (far above the toxic concentration to plants) in their shoots indicates that internal detoxification metal tolerance mechanism(s) are also included. The factors affecting metal accumulation by wetland plants include metal concentrations, pH, and nutrient status in substrata. Mostly concentrations of Pb and Cu in both aboveground and underground tissues of the plants were significantly positively related to their total and/or DTPA-extractable fractions in substrata while negatively to soil N and P, respectively. The potential use of these wetland plants in phytoremediation is also discussed.  相似文献   
13.
Using the monthly hydrogeochemical data of ChangLe River system from 2004 to 2008, total nitrogen (TN) export load (S(n)) from nonpoint sources (NPS) to stream and in-stream attenuation load (A(L)) was estimated by the inverse and forward format of an existing in-stream nutrient transport equation, respectively. Estimated S(n) contributed 96 ± 2% of TN entering the river system, while A(L) reduced the input TN by 23 ± 14% in average. In-stream TN attenuation efficiency in high flow periods (10 ± 5% in average for the entire river system) was much lower than that in low flow periods (39 ± 17%). TN attenuation efficiency in tributaries (28 ± 16% in average) was much higher than that in mainstream (11 ± 8%). Hydrological conditions are important in determining the spatio-temporal distributions of NPS TN export, stream attenuation and discharge. Increasing the water residence time might be a practical method for mitigating stream TN.  相似文献   
14.
应用灰色系统理论,根据江苏省地震工程研究院的地震科技开发资料,分别以项目负责人的年龄、学历、职称、职务、学科作为比较数列,对年度内完成的实际合同额进行了多因素灰色关联分析,排出了关联序。研究结果客观地揭示了开发能力与人的各种因素——年龄、学历、职称、职务、学科之间的相互关系,为市场经济条件下,地震科技人才的开发、培养和应用,提供了科学依据。  相似文献   
15.
To obtain detailed information on the pyrolysis characteristics, a thermogravimetric study on the pyrolysis of 14 typical medical waste compositions was carried out in thermogravimetric analysis (TGA) equipment using dynamic techniques in a stream of N(2). An index representing pyrolysis reactivity of waste was presented. Kinetic parameters were obtained by Coats-Redfern method and used to model the TG curve. The results showed that: (a) Plastic, protein, cellulosic material, synthetic fibre, and rubber entered pyrolysis process in succession. (b) There was one decomposition stage in the pyrolysis of one-off medical glove, operating glove, cellulosic waste, absorbable catgut suture and adhesive plaster, while other components had two obvious weight loss stages. (c) The obtained apparent activation energy for second stage pyrolysis was comparably higher than that for first stage. (d) Each stage was controlled by only one kinetic mechanism, in which kinetic parameters were constant. (e) The degradation kinetics of medical waste may be affected by special physical and chemical treatment in the product manufacturing process. (f) Among 13 waste samples, the pyrolysis index of cellulosic matter was the highest, which indicated cellulosic matter had strong pyrolysis reactivity. (g) With increasing heating rate, TG curve and DTG peak shifted to high temperatures and main reaction interval of the sample became longer.  相似文献   
16.
三种偶氮染料降解历程在紫外-可见光谱上的表现   总被引:20,自引:2,他引:18  
吴峰  华河林  邓南圣 《环境化学》2000,19(4):348-351
本文对基本结构相似的三种偶氮染料橙黄Ⅱ、活性艳红X-3B和活性黑K-BR水溶液在铁粉还原-光氧化两步法处理中的紫外-可见光谱图作对比分析,依据其结构与特征吸收的关系,初步推测还原铁粉-光氧化法降解染料的历程。  相似文献   
17.
pH对铜在黄土中吸持及其形态的影响   总被引:22,自引:4,他引:22  
用黄土为吸持剂,以石英砂作对照,研究了pH对铜的吸持及形态的影响,并用MINTEQA2模型对铜离子的沉淀形态进行了理论计算.结果表明:无论吸持剂是石英砂还是黄土,随着pH的升高,吸持曲线都分为3区:低pH微吸持区、中pH吸持增长区和高pH强吸持区.含沙量一定,随着铜液初始浓度的增加,吸持量、可交换态含量和碳酸盐结合态含量均增加;铜液初始浓度一定,随着含沙量的增加,吸持量、可交换态含量和碳酸盐结合态含量均减少.MINTEQA2模型计算结果表明,对于不同的吸持剂,铜离子发生沉淀的比例及沉淀的物质组成是不同的;以黄土为吸持剂时,中pH范围内随着含沙量的增加铜离子沉淀的比例减少.  相似文献   
18.
用缺氧生物滤池与UASB相串联的工艺对杭州市天子岭垃圾填埋场惨滤液进行了中试试验。通过实验,总结了缺氧生物滤池的挂膜特性及UASB起动的成功经验。最终的试验结果表明:出水COD、BOD、SS分别稳定在900mg/L、150mg/L、250mg/L以下,缺氧生物滤池对渗滤液具有很好的预处理效果,不仅能脱吸部分NH3、CO2、H2S,而且能提高它的可生化性,为UASB的高效运行创造了良好的条件。  相似文献   
19.
小麦产量的遥感动态预估研究──以山东禹城县为例   总被引:3,自引:0,他引:3  
本文利用现代遥感信息、数理统计和回归分析方法,研究了禹城县试验区的小麦单产与卫星遥感信息(绿度)间的关系,并建立了小麦单产与绿度关系的预估模型;阐述了直接利用遥感宏观信息动态预估小麦产量的可行性和这一方法的应用前景。  相似文献   
20.
To characterize Streptomyces isolated from cattle feces for converting lignocellulose into reducing sugars, five Streptomyces strains were screened. All the strains could convert lignocellulose into reducing sugars. The strain A16 accumulate 3.3-folds more reducing sugars on cottonseed shells treated with ethanol than without the treatment (P?<?0.05). The five strains did not accumulate more reducing sugars on rice straws and wheat brans than those on cottonseed shells. Compared with A10 alone, the microbial combination of F1 + A10 accumulated 19, 61, and 25 % less reducing sugars on cottonseed shell, rice straw, and wheat bran than those by A10 solely, respectively (P?<?0.05). Further studies indicated that the activities of avicelase and xylanase were not correlated with the reducing sugar amount accumulated by the test strains. Strain A7 could produce more cellular lipids with xylose and glucose as the sole carbon sources. This study shows the potential for Streptomyces strains from herbivore feces to convert lignocelluloses into lipids and reducing sugars for fuel production.  相似文献   
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