全文获取类型
收费全文 | 968篇 |
免费 | 38篇 |
国内免费 | 332篇 |
专业分类
安全科学 | 52篇 |
废物处理 | 67篇 |
环保管理 | 99篇 |
综合类 | 494篇 |
基础理论 | 145篇 |
污染及防治 | 346篇 |
评价与监测 | 49篇 |
社会与环境 | 50篇 |
灾害及防治 | 36篇 |
出版年
2023年 | 19篇 |
2022年 | 45篇 |
2021年 | 36篇 |
2020年 | 30篇 |
2019年 | 33篇 |
2018年 | 45篇 |
2017年 | 47篇 |
2016年 | 49篇 |
2015年 | 43篇 |
2014年 | 57篇 |
2013年 | 96篇 |
2012年 | 67篇 |
2011年 | 90篇 |
2010年 | 68篇 |
2009年 | 56篇 |
2008年 | 56篇 |
2007年 | 63篇 |
2006年 | 48篇 |
2005年 | 46篇 |
2004年 | 29篇 |
2003年 | 32篇 |
2002年 | 31篇 |
2001年 | 21篇 |
2000年 | 38篇 |
1999年 | 25篇 |
1998年 | 27篇 |
1997年 | 26篇 |
1996年 | 25篇 |
1995年 | 13篇 |
1994年 | 15篇 |
1993年 | 6篇 |
1992年 | 12篇 |
1991年 | 11篇 |
1990年 | 15篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有1338条查询结果,搜索用时 559 毫秒
391.
392.
Quantifying Terrestrial Ecosystem Carbon Dynamics in the Jinsha Watershed, Upper Yangtze, China from 1975 to 2000 总被引:1,自引:0,他引:1
Shuqing Zhao Shuguang Liu Runsheng Yin Zhengpeng Li Yulin Deng Kun Tan Xiangzheng Deng David Rothstein Jiaguo Qi 《Environmental management》2010,45(3):466-475
Quantifying the spatial and temporal dynamics of carbon stocks in terrestrial ecosystems and carbon fluxes between the terrestrial
biosphere and the atmosphere is critical to our understanding of regional patterns of carbon budgets. Here we use the General
Ensemble biogeochemical Modeling System to simulate the terrestrial ecosystem carbon dynamics in the Jinsha watershed of China’s
upper Yangtze basin from 1975 to 2000, based on unique combinations of spatial and temporal dynamics of major driving forces,
such as climate, soil properties, nitrogen deposition, and land use and land cover changes. Our analysis demonstrates that
the Jinsha watershed ecosystems acted as a carbon sink during the period of 1975–2000, with an average rate of 0.36 Mg/ha/yr,
primarily resulting from regional climate variation and local land use and land cover change. Vegetation biomass accumulation
accounted for 90.6% of the sink, while soil organic carbon loss before 1992 led to a lower net gain of carbon in the watershed,
and after that soils became a small sink. Ecosystem carbon sink/source patterns showed a high degree of spatial heterogeneity.
Carbon sinks were associated with forest areas without disturbances, whereas carbon sources were primarily caused by stand-replacing
disturbances. It is critical to adequately represent the detailed fast-changing dynamics of land use activities in regional
biogeochemical models to determine the spatial and temporal evolution of regional carbon sink/source patterns. 相似文献
393.
大气气溶胶酸度的研究进展 总被引:1,自引:0,他引:1
大气气溶胶的环境效应、气候效应和健康效应均与气溶胶的物理化学性质直接相关,其中大气气溶胶酸度是其重要的性质之一。大气气溶胶酸度对酸沉降、灰霾的形成具有重要作用,并影响大气非均相化学反应,相关研究已成为国际研究的热点。对国内外学者近年来在大气气溶胶酸度对大气环境与人体健康的影响、大气气溶胶酸度的影响因素与变化规律、大气气溶胶酸度/酸化缓冲能力的测定与计算方法、大气气溶胶酸性成分采集系统等方面的研究进展作了较系统的综述,并对大气气溶胶酸度研究未来的发展进行了展望。 相似文献
394.
传统的金刚石生产中提纯工艺采用大量的硝酸、硫酸和盐酸进行处理,会产生大量的有害气体、含酸废水和含有大量镍等重金属离子的废弃物,既浪费资源义对环境造成严重污染.通过实验在生产工艺中增加了电解工序,把电解工序应用于酸煮去杂工序之前,用电化学的方法回收80%以上的金属镍,提高了后处理效率,达到在生产过程中控制和减少污染物的产生,从源头上减少化工原料的投入和使用.以年产18亿克拉人造金刚石企业为个案,对比了粉体触媒法合成高品级人造金刚石生产中用电解法后处理与传统的酸煮法后处理2种工艺中污染物产生、处理费用和效益.结果表明,与传统的酸煮法后处理2种工艺相比,电解法后处理工艺可使混合酸(硝酸、硫酸和盐酸)用量减少11 400 t/a,含镍污泥产生量减少2 250 t/a,生产废水排放量减少10.05万m3/a,氢氧化钠(30%)用量减少1 300 t/a,新鲜水用量减少16万m3/a,而用电量和柴油用量分别增加1 000万kWh/a和200 t/a,由此年创利润916万元. 相似文献
395.
396.
397.
Electrochemical oxidation for landfill leachate treatment 总被引:10,自引:0,他引:10
This paper aims at providing an overview of electrochemical oxidation processes used for treatment of landfill leachate. The typical characteristics of landfill leachate are briefly reviewed, and the reactor designs used for electro-oxidation of leachate are summarized. Electrochemical oxidation can significantly reduce concentrations of organic contaminants, ammonia, and color in leachate. Pretreatment methods, anode materials, pH, current density, chloride concentration, and other additional electrolytes can considerably influence performance. Although high energy consumption and potential chlorinated organics formation may limit its application, electrochemical oxidation is a promising and powerful technology for treatment of landfill leachate. 相似文献
398.
Jiang J Yang G Deng Z Huang Y Huang Z Feng X Zhou S Zhang C 《Waste management (New York, N.Y.)》2007,27(7):893-901
Developing countries have begun to investigate bioreactor landfills for municipal solid waste management. This paper describes the impacts of leachate recirculation and recirculation loadings on waste stabilization, landfill gas (LFG) generation and leachate characteristics. Four simulated anaerobic columns, R1-R4, were each filled with about 30 tons of waste and recirculated weekly with 1.6, 0.8 and 0.2m(3) leachate and 0.1m(3) tap water. The results indicated that the chemical oxygen demand (COD) half-time of leachate from R1 was about 180 days, which was 8-14 weeks shorter than that of R2-R4. A large amount of LFG was first produced in R1, and its generation rate was positively correlated to the COD or volatile fatty acid concentrations of influent leachates after the 30th week. By the 50th week of recirculation, the waste in R1 was more stabilized, with 931.2 kg COD or 175.6 kg total organic carbon released and with the highest landfill gas production. However, this contributed mainly to washout by leachate, which also resulted in the reduction of LFG generation potential and accumulation of ammonia and/or phosphorus in the early stage. Therefore, the regimes of leachate recirculation should be adjusted to the phases of waste stabilization to enhance efficiency of energy recovery. Integrated with the strategy of in situ leachate management, extra pre-treatment or post-treatment methods to remove the nutrients are recommended. 相似文献
399.
In this work, the formation of the inclusion complex of bisphenol Z (1,1-bis(4-hydroxyphenyl)cyclohexane, abbreviated as BPCH) with beta-cyclodextrin (beta-CD) has been studied, 1:1 inclusion complex can be obtained, the formation constant of the beta-CD/BPCH complex is 5.94x10(3)M(-1). The photodegradation behavior of BPCH was investigated under monochromatic UV irradiation (lambda=254 nm). The photodegradation rate constant of BPCH in aqueous solutions with beta-CD showed a 9.0-fold increase, and simultaneously the mineralization of BPCH can be enhanced by beta-CD. The influence factors on photodegradation of BPCH were also studied and described in details, such as concentration of beta-CD, initial concentration of BPCH, organic solvent and pH. The photodegradation of BPCH in the presence of beta-CD includes the direct photolysis and the photooxidation of BPCH during the photochemical process. Some predominant photodegradation products are 4-(2,4,5-trihydroxy-phenyl)-4-(4-hydroxyphenyl) butanoic acid, 5,5-bis(4-hydroxyphenyl)pentanoic acid, meta-hydroxylated BPCH, ortho-hydroxylated BPCH and 4-(1-(4-hydroxyphenyl)pentyl)phenol respectively. The enhancement of photodegradation of BPCH mainly results from moderate inclusion depth of BPCH molecule in the beta-CD cavity. This kind of inclusion structure allows BPCH molecule sufficient proximity to secondary hydroxyl groups of the beta-CD cavity, and these hydroxyl groups could be activated and converted to hydroxyl radicals under UV irradiation, which can enhance the photooxidation of BPCH. 相似文献
400.
We examined the concentrations of 11 trace metals in tissues from 10 body parts of Great Tits and Greenfinches collected at Badachu Park in the Western Mountains of Beijing, China to assess the metal accumulation level, distribution among body parts, and species and gender related variations. The highest concentrations of Hg, Ni, Zn, and Mn were found in the feather; Pb and Co in the bone; Cd, Cr, and Se in the kidney, and Cu in the liver and heart. Metal concentrations had substantial interspecific variation with Great Tits showing higher levels of Hg, Cr, Ni, and Mn than Greenfinches in tissues of most body parts. Gender related variations were body part and species specific. Meta-analyses using data from this study and other studies suggested that metal concentrations of Great Tits at our study site were relatively low and below the toxic levels. 相似文献