Spatiotemporal pattern of reference crop evapotranspiration and its response to meteorological factors in Northwest China over years 2000–2019

Agricultural irrigation water in Northwest China accounts for more than 80% of total local water consumption, which is 1.23 times that of China. However, Northwest China is the most water-scarce place in China. Water scarcity in restricts crop growth and production. Reference crop evapotranspiration (ET₀) is important for agricultural water management. Understanding the reason for ET₀ change is helpful to provide a basis for rational planning of agricultural irrigation systems to conserve water. This study investigated the temporal and spatial variation characteristics of ET₀ at 181 meteorological stations in Northwest China from 2000 to 2019. And the sensitive factors and dominant factors affecting ET₀ change were quantitatively identified based on sensitivity analysis and contribution rate evaluation. Results showed that (1) a significant increase in maximum and minimum temperature (T_max and T_min), a significant decrease in sunshine duration (SD) and relative humidity (RH), and a slight increase in wind speed at 10 m height (U₁₀) were observed. (2) Annual ET₀ had an insignificant increasing trend. Spring and autumn ET₀ contributed greatly to the growth of annual ET₀, especially in March, May, September, October, and November. ET₀ in HH (Yellow River Basin area) had decreased at annual scale, while other subregions were the opposite trend. Significant differences in monthly and seasonal changes in the spatial distribution of ET₀. (3) U₁₀ was the dominating contribution factor related to annual ET₀ variability, followed by T_min, RH, T_max, and SD. In seasonal time scale, T_min, SD, U₁₀, and RH were the most dominant factors in spring, summer, autumn, and winter respectively. (4) Spatial distribution for contribution rates of various meteorological factors showed significant diversity among various subregions. The positive contribution of U₁₀ was the major cause of the increase in ET₀ in semi-arid grassland area (BGH), the southwest of “Qice line” (QCXXN), and the southeast of “Qice line” (QCXDN); the significant increase in T_min contributed most in Qaidam Basin (CDM), Hexi inland river basin (HX), the northeast of “Qice line” (QCXDB), and the northwest of “Qice line” (QCXXB), while the contribution of decreasing SD offsets the positive effects of other factors, leading to the decrease in ET₀ in HH. Our work illustrates that water management measures should be different at different spatial and temporal scales. The effect of U₁₀ can be offset by covering, to reduce evaporation and maintain water in BGH, QCXXN, and QCXDN. And high-temperature resistant varieties are planted to adapt to temperature growth in CDM, HX, QCXDB, and QCXXB. Agricultural water management strategies should be formulated and selected according to local conditions.

     

火焰原子吸收法测定总铜不确定度的评定

依据线性最小二乘法的数学特性,提出采用火焰原子吸收法测定地表水中总铜的不确定度的简化评定方法,通过识别和分析不确定度源,对不确定度进行量化,计算合成标准不确定度。此方法适用于地下水、地表水和废水中的总铜含量直接法测定中不确定度的快速评定。     

溶解氧对人工湿地处理受污染城市河流水体效果的影响

研究了溶解氧在人工湿地中的分布对受污染城市河流水体处理效果的影响规律及其意义,为城市受污染景观水体处理或雨水处理人工湿地的工程设计提供有效的自然复氧估算方法和设置措施.结果表明,由于自然复氧不利引起的溶解氧不足(<2 mg/L)是导致人工湿地出水水质恶化的主要原因.自然跌水是一种有效的人工湿地充氧方式,其充氧效果可用氧亏比r根据水温、水质以及充氧形式等外部条件参数进行估算.推流态的湿地床内,溶解氧分布与生物量分布以及有机物的去除规律呈现明显的相关性,而对TP沿程去除速率影响不大.设置多级多段跌水有利于均衡湿地床填料内的溶解氧分布,促进硝化反应,保证出水水质.     

杀菌剂对湖泊水体温室气体浓度分析的影响

通过往湖泊水样中添加杀菌剂(CuSO4和HgCl2),利用平衡法,用气相色谱仪测定CO2、CH4、N2O浓度,研究杀菌剂(CuSO4和HgCl2)添加对湖泊水体CO2、CH4、N2O浓度分析的影响.实验设计:对照组(CK)不加任何试剂;处理组T1加1mL CuSO4溶液,T2加5 mL CuSO4溶液,T3加0.5 mL HgCl2溶液;每组的水样分两批分析:(Ⅰ)预处理完成后立即分析和(Ⅱ)预处理完成后静置两天再分析.结果表明,CuSO4和HgCl2的添加均能明显增加水体中CO2的浓度,CK(Ⅰ)和CK(Ⅱ)的CO2平均浓度分别为(11.5±1.47)μmol·L-1和(14.38±1.59)μmol·L-1,T1(Ⅰ)和T1(Ⅱ)的CO2平均浓度分别为(376±70)μmol·L-1和(448±246.83)μmol·L-1;T2(Ⅰ)和T2(Ⅱ)的CO2平均浓度分别为(885±51.53)μmol·L-1和(988.83±101.96)μmol·L-1;T3(Ⅰ)和T3(Ⅱ)的CO2平均浓度分别为(287.19±30.01)μmol·L-1和(331.33±22.06)μmol·L-1.但CuSO4和HgCl2添加对水体中CH4和N2O的浓度没有影响.对比Ⅰ和Ⅱ的实验结果可知,在水样预处理完成后需当天分析其温室气体(CO2、CH4、N2O)浓度.本研究表明,杀菌剂的添加能显著增加水体CO2的浓度.     

溧阳市1985~2011年环境空气质量变化规律的模糊综合评价

选用模糊综合评价法,对溧阳市1985~2011年环境空气质量进行了综合评价,选用SO2、NO2、TSP/PM10作为评价因素,通过计算各评价因素权重分配系数和隶属度,分析了长期空气环境质量变化趋势。结果表明:TSP/PM 10为1985年以来溧阳市首要环境空气质量制约因素,20世纪80年代中期全市空气质量主要隶属于一级标准,20世纪80年代后期主要隶属于二级标准,20世纪90年代初期主要隶属于三级标准,20世纪90年代中后期至今主要隶属于二级标准,近几年受TSP/PM1 0因素影响,在三级标准的隶属度有上升趋势;自20世纪90年代中期始,NO 2超越SO2成为继PM 10之后制约空气质量的第2大因素;经济发展对环境空气质量的规模效应较为显著,技术减排效应逐步显现。     

加油站油气回收效果检测及分析

对某地区4个加油站的油气回收改造效果进行了抽样检测。重点对一次油气回收中的回气量、回气浓度、回气压力和卸油速度以及二次油气回收中的密闭性、液阻和气液比等指标进行了测试,分析了存在的问题,并提出了相应的改造措施和建议。     

长春市双阳区农村生活污水排放情况分析

双阳区环境监测站与环境监察大队结合双阳区实际,选取双阳区南部低山丘陵区以山河街羊圈村、北部平原区以奢岭镇幸福村和双胜村、东北部水源地准保护区以齐家镇曙光村和长岭村为代表的5个行政村生活污水排放情况进行实地调研,同时对双阳区全区农村生活污水排放情况进行统计,从而得出双阳区各流域生活污水受纳量及受污染情况。     

Selective oxidation of benzyl alcohols to benzoic acid catalyzed by eco-friendly cobalt thioporphyrazine catalyst supported on silica-coated magnetic nanospheres

A novel magnetically recoverable thioporphyrazine catalyst (CoPz(S-Bu)8/SiO2@Fe3O4) was prepared by immobilization of the cobalt octkis(butylthio) porphyrazine complex (CoPz(S-Bu)8) on silica-coated magnetic nanospheres (SiO2@Fe3O4). The composite CoPz(S-Bu)8/SiO2@Fe3O4 appeared to be an active catalyst in the oxidation of benzyl alcohol in aqueous solution using hydrogen peroxide (H2O2) as oxidant under Xe-lamp irradiation, with 36.4% conversion of benzyl alcohol, about 99% selectivity for benzoic acid and turnover number (TON) of 61.7 at ambient temperature. The biomimetic catalyst CoPz(S-Bu)8 was supported on the magnetic carrier SiO2@Fe3O4 so as to suspend it in aqueous solution to react with substrates, utilizing its lipophilicity. Meanwhile the CoPz(S-Bu)8 can use its unique advantages to control the selectivity of photocatalytic oxidation without the substrate being subjected to deep oxidation. The influence of various reaction parameters on the conversion rate of benzyl alcohol and selectivity of benzoic acid was investigated in detail. Moreover, photocatalytic oxidation of substituted benzyl alcohols was obtained with high conversion and excellent selectivity, specifically conversion close to 70%, selectivity close to 100% and TON of 113.6 for para-position electron-donating groups. The selectivity and eco-friendliness of the biomimetic photocatalyst give it great potential for practical applications.     

污染物排放波动特征及对排污许可限值的影响

受生产活动变化的影响,企业的污染物排放具有一定的波动性,制定基于不同时间周期的污染物排污许可限值,是完善企业污染物排放监管的需要。以铁岭市企业在线监测数据为基础,采用短周期排放量与长周期排放量的比值β,研究了企业行业特征和规模对不同周期污染物排放量的影响。结果表明,行业对β值具有重要的影响,铁岭市屠宰行业、煤炭行业和污水处理厂COD日排放量与年排放量的比值β平均值分别为2.82、2.61和1.65,NH-N排放量Cr MDL 3的β平均值分别为2.9、3.49和2.59,表明污水处理厂相比屠宰行业和煤炭行业具有更强的稳定性。从企业规模来看,MDL企业规模较小时,由于生产稳定性差β值波动较大;企业规模较大时,β值趋于稳定。因此,制定不同周期的企业排污许可限值时,应基于不同的行业特征和企业规模给出不同的参考比值。