Integrating Geographic Information System network analysis and nighttime light satellite imagery to optimize landfill regionalization on a regional level

More than half of financial resources allocated for municipal solid waste management are typically spent on waste collection and transportation. An optimized landfill siting and waste collection system can save fuel costs, reduce collection truck emissions, and provide higher accessibility with lower traffic impacts. In this study, a data-driven analytical framework is developed to optimize population coverage by landfills using network analysis and satellite imagery. Two scenarios, SC1 and SC2, with different truck travel times were used to simulate generation-site–disposal-site distances in three Canadian provinces. Under status quo conditions, Landfill Regionalization Index (LFRI) ranging from 0 to 2 population centers per landfill in all three jurisdictions. LFRI consistently improved after optimization, with average LFRI ranging from 1.3 to 2.0 population centers per landfill. Lower average truck travel times and better coverage of the population centers are generally observed in the optimized systems. The proposed analytical method is found effective in improving landfill regionalization. Under SC1 and SC2, LFRI percentages of improvement ranging from 58.3% to 64.5% and 22.7% to 59.4%, respectively. Separation distance between the generation and disposal sites and truck capacity appear not a decisive factor in the optimization process. The proposed optimization framework is generally applicable to regions with different geographical and demographical attributes, and is particularly applicable in rural regions with sparsely located population centers.

     

Response of sugar maple to calcium addition to northern hardwood forest

Watershed budget studies at the Hubbard Brook Experimental Forest (HBEF), New Hampshire, USA, have demonstrated high calcium depletion of soil during the 20th century due, in part, to acid deposition. Over the past 25 years, tree growth (especially for sugar maple) has declined on the experimental watersheds at the HBEF. In October 1999, 0.85 Mg Ca/ha was added to Watershed 1 (W1) at the HBEF in the form of wollastonite (CaSiO3), a treatment that, by summer 2002, had raised the pH in the Oie horizon from 3.8 to 5.0 and, in the Oa horizon, from 3.9 to 4.2. We measured the response of sugar maple to the calcium fertilization treatment on W1. Foliar calcium concentration of canopy sugar maples in W1 increased markedly beginning the second year after treatment, and foliar manganese declined in years four and five. By 2005, the crown condition of sugar maple was much healthier in the treated watershed as compared with the untreated reference watershed (W6). Following high seed production in 2000 and 2002, the density of sugar maple seedlings increased significantly on W1 in comparison with W6 in 2001 and 2003. Survivorship of the 2003 cohort through July 2005 was much higher on W1 (36.6%) than W6 (10.2%). In 2003, sugar maple germinants on W1 were approximately 50% larger than those in reference plots, and foliar chlorophyll concentrations were significantly greater (0.27 g/m2 vs. 0.23 g/m2 leaf area). Foliage and fine-root calcium concentrations were roughly twice as high, and manganese concentrations twice as low in the treated than the reference seedlings in 2003 and 2004. Mycorrhizal colonization of seedlings was also much greater in the treated (22.4% of root length) than the reference sites (4.4%). A similar, though less dramatic, difference was observed for mycorrhizal colonization of mature sugar maples (56% vs. 35%). These results reinforce and extend other regional observations that sugar maple decline in the northeastern United States and southern Canada is caused in part by anthropogenic effects on soil calcium status, but the causal interactions among inorganic nutrition, physiological stress, mycorrhizal colonization, and seedling growth and health remain to be established.     

Ecological risk assessments of endocrine disrupting organotin compounds using marine neogastropods in Hong Kong

As active ingredients of anti-fouling paints that are widely used on ship hulls, organotin compounds, in particular tributyltin (TBT), are well-known endocrine disruptors causing sex changes in marine organisms and widespread in coastal waters and sediments worldwide. In this study, a comprehensive ecological risk assessment (ERA) of organotins was conducted in Hong Kong waters through determining the imposex status, sex ratio and tissue burdens of these compounds in the neogastropods, Thais clavigera and Thais luteostoma collected from 29 coastal sites. We also investigated the historical trend of organotin effects on these gastropods, and performed a probabilistic ERA based on tissue burden of TBT in the animals. Our results demonstrated that imposex indices were positively correlated with the body burden of organotins in the gastropods. Across all sites, the sex ratio (female:male) decreased significantly with increasing imposex levels or tissue burden of organotins, implying that such pollutants can result in a male-biased population, potentially leading to local extinction in extreme cases. Based on the ERA, 5.4% of all populations of T. clavigera are at risk due to exposure to TBT; the risks include growth inhibition, impairment of immune functions and reduced fitness. Seriously impacted areas included Aberdeen, Repulse Bay, Butterfly Beach, Mui Wo and Ha Mei Wan. A comparison with historical data revealed that there had been some improvement in the areas with low marine traffic, and distant from the major harbour/port. This could partly be due to the restriction on the use of TBT on small vessels (<25m in length) since 1992. Nevertheless, the organotin contamination still remains severe in areas with high marine traffic or adjacent to large harbours/ports. In particular, the situation in the northeastern waters of Hong Kong has been getting worst since 1996 that is probably associated with the rapid development of the cargo container port at Yantian in China.     

Nucleic acids and ATP to assess microbial biomass and activity in a marine biosedimentary system

 Sedimentary DNA, RNA and ATP concentrations were measured at six stations on a tidal flat in the German Wadden Sea from April to December 1995 to determine factors controlling microbial abundance and activity. Two stations (1 and 2) were located in a mussel bed (Mytilus edulis) in the middle of the flat, and the other four were arranged in a line following ebb tide direction. DNA and ATP concentrations were converted into carbon equivalents using literature coefficients and considered to represent total microbial biomass and viable microbial biomass, respectively. The difference between C_DNA and C_ATP was considered as detrital biomass. C_DNA and detrital C_DNA biomass both increased from spring to summer and decreased in autumn to reach lowest values in December. The most prominent seasonal increase was observed at the mussel bed stations and two adjacent stations. C_ATP biomass peaked in early spring, especially at the mussel bed stations, and showed a secondary peak in summer. Regression analysis yielded a highly significant relation between the silt content of the sediment and C_DNA and C_ATP. However, C_DNA and C_ATP biomass are not correlated if silt is taken into account. The relation between silt and microbial biomass in combination with the decrease of the silt content with distance from the mussel bed indicate the importance of mussel beds for the microbial activity on the tidal flat, most likely through deposition of feces and pseudofeces. The low silt content and microbial biomass in winter are attributed to resuspension events. The zero intercepts of the regressions between DNA and ATP or RNA suggest that extracellular DNA is absent in our samples. Hence, detrital C_DNA biomass in our samples probably consists of intact but dormant cells. Compared to other marine habitats the percentage of detrital C_DNA biomass on the tidal flat is quite high, i.e. up to >95% of the total C_DNA. However some doubt is expressed about the validity of factors used to convert ATP and DNA to carbon. The proportion of active biomass, expressed by the ratio C_ATP/C_DNA being the complement of the detrital C_DNA percentage shows a steady decrease with time and with diminishing distance towards the mussel beds. The role of a mussel bed as a biosedimentary system influencing spatial and temporal trends in specific activity is discussed. Received: 26 January 2000 / Accepted: 3 July 2000     

Assessment of heavy metal cations in sediments of Shing Mun River, Hong Kong

The extent of heavy metal cation contamination in the Shing Mun River has been assessed. Sediment samples were taken at eight strategic locations along the river system. The highest concentrations of copper (Cu, 1.66 mg/g), lead (Pb, 0.354 mg/g), zinc (Zn, 2.2 mg/g) and chromium (Cr, 0.047 mg/g) were found in the Fo Tan Nullah, a major tributary of the Shing Mun River. The highest concentrations of aluminum (114 mg/g) and cadmium (Cd, 0.047 mg/g) were found in the Shing Mun Main River Channel. These contaminated sediments, accumulated over the years on the river bed, could act as secondary sources of pollution to the overlying water column in the river.     

Simultaneous-count models to estimate abundance from counts of unmarked individuals with imperfect detection

We developed a method to estimate population abundance from simultaneous counts of unmarked individuals over multiple sites. We considered that at each sampling occasion, individuals in a population could be detected at 1 of the survey sites or remain undetected and used either multinomial or binomial simultaneous-count models to estimate abundance, the latter being equivalent to an N-mixture model with one site. We tested model performance with simulations over a range of detection probabilities, population sizes, growth rates, number of years, sampling occasions, and sites. We then applied our method to 3 critically endangered vulture species in Cambodia to demonstrate the real-world applicability of the model and to provide the first abundance estimates for these species in Cambodia. Our new approach works best when existing methods are expected to perform poorly (i.e., few sites and large variation in abundance among sites) and if individuals may move among sites between sampling occasions. The approach performed better when there were >8 sampling occasions and net probability of detection was high (>0.5). We believe our approach will be useful in particular for simultaneous surveys at aggregation sites, such as roosts. The method complements existing approaches for estimating abundance of unmarked individuals and is the first method designed specifically for simultaneous counts.     

Temporal genetic variation in populations of the limpet Cellana grata from Hong Kong shores

Variations in the relative contributions of gene flow and spatial and temporal variation in recruitment are considered the major determinants of population genetic structure in marine organisms. Such variation can be assessed through repeated measures of the genetic structure of a species over time. To test the relative importance of these two phenomena, temporal variation in genetic composition was measured in the limpet Cellana grata, among four annual cohorts over 10 years at four rocky shores in Hong Kong. A total of 408 limpets, comprising individuals from 1998, 1999, 2006 and 2007 cohorts were screened for genetic variation using five microsatellite loci. Minor but significant genetic differentiation was detected among samples from the 1998/1999 collection (F _ST = 0.0023), but there was no significant differentiation among the 2006/2007 collection (F _ST = 0.0008). Partitioning of genetic variation among shores was also significant in 1998/1999 but not in the 2006/2007 collection, although there was no correlation between genetic and geographic distances. There was no significant difference between collections made in 1998/1999 and 2006/2007. This lack of clear structure implies a high level of gene flow, but differentiation with time may be the result of stochastic recruitment variation among shores. Estimates of effective population size were not high (599, 95% C.L. 352–11397), suggesting the potential susceptibility of the populations to genetic drift, although a significant bottleneck effect was not detected. These findings indicate that genetic structuring between populations of C. grata in space and time may result from spatio-temporal variation in recruitment, but the potential development of biologically significant differentiation is suppressed by a lack of consistency in recruitment variability and high connectivity among shores.     

Energy and environmental applications of carbon nanotubes

Energy and environment are major global issues inducing environmental pollution problems. Energy generation from conventional fossil fuels has been identified as the main culprit of environmental quality degradation and environmental pollution. In order to address these issues, nanotechnology plays an essential role in revolutionizing the device applications for energy conversion and storage, environmental monitoring, as well as green engineering of environmental friendly materials. Carbon nanotubes and their hybrid nanocomposites have received immense research attention for their potential applications in various fields due to their unique structural, electronic and mechanical properties. Here, we review the applications of carbon nanotubes (1) in energy conversion and storage such as in solar cells, fuel cells, hydrogen storage, lithium ion batteries and electrochemical supercapacitors, (2) in environmental monitoring and wastewater treatment for the detection and removal of gas pollutants, pathogens, dyes, heavy metals and pesticides and (3) in green nanocomposite design. Integration of carbon nanotubes in solar and fuel cells has increased the energy conversion efficiency of these energy conversion applications, which serve as the future sustainable energy sources. Carbon nanotubes doped with metal hydrides show high hydrogen storage capacity of around 6?wt% as a potential hydrogen storage medium. Carbon nanotubes nanocomposites have exhibited high energy capacity in lithium ion batteries and high specific capacitance in electrochemical supercapacitors, in addition to excellent cycle stability. High sensitivity and selectivity towards the detection of environmental pollutants are demonstrated by carbon nanotubes based sensors, as well as the anticipated potentials of carbon nanotubes as adsorbent to remove environmental pollutants, which show high adsorption capacity and good regeneration capability. Carbon nanotubes are employed as reinforcement material in green nanocomposites, which is advantageous in supplying the desired properties, in addition to the biodegradability. This article presents an overview of the advantages imparted by carbon nanotubes in electrochemical devices of energy applications and green nanocomposites, as well as nanosensor and adsorbent for environmental protection.     

Poly(2-ethyl-2-oxazoline) as β-Nucleating Agent for Poly(lactic acid) Blends with High Transparency and Hydrophilicity

Journal of Polymers and the Environment - This study aims to evaluate the effects of poly(2-ethyl-oxazoline) (PEOx) on the thermal properties, wettability, and optical properties of poly(lactic...