Speciation and distribution of copper in a mining soil using multiple synchrotron-based bulk and microscopic techniques

Molecular-level understanding of soil Cu speciation and distribution assists in management of Cu contamination in mining sites. In this study, one soil sample, collected from a mining site contaminated since 1950s, was characterized complementarily by multiple synchrotron-based bulk and spatially resolved techniques for the speciation and distribution of Cu as well as other related elements (Fe, Ca, Mn, K, Al, and Si). Bulk X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopy revealed that soil Cu was predominantly associated with Fe oxides instead of soil organic matter. This agreed with the closest association of Cu to Fe by microscopic X-ray fluorescence (U-XRF) and scanning transmission X-ray microscopy (STXM) nanoanalysis, along with the non-occurrence of photoreduction of soil Cu(II) by quick Cu L_3,2-edge XANES spectroscopy (Q-XANES) which often occurs when Cu organic complexes are present. Furthermore, bulk-EXAFS and STXM-coupled Fe L_3,2-edge nano-XANES analysis revealed soil Cu adsorbed primarily to Fe(III) oxides by inner-sphere complexation. Additionally, Cu K-edge μ-XANES, L_3,2-edge bulk-XANES, and successive Q-XANES results identified the presence of Cu₂S rather than radiation-damage artifacts dominant in certain microsites of the mining soil. This study demonstrates the great benefits in use of multiple combined synchrotron-based techniques for comprehensive understanding of Cu speciation in heterogeneous soil matrix, which facilitates our prediction of Cu reactivity and environmental fate in the mining site.     

Understanding Conceptual Climate Change Meanings and Preferences of Multi-Actor Professional Leadership in New York

This article sets out to evaluate the range of meanings and preferences for the concepts of adaptation, resilience, mitigation and coping of a variety of professionals in New York who are undertaking leadership positions in developing climate change policies and practices. This article positions a normative set of simplified meanings for each of the aforementioned concepts based on a review of existing literature. Utilizing a survey, these normative meanings are evaluated by and between the: (a) concepts and meanings; (b) concepts and applications and (c) applications and preferences, as applied to various risk-based scenarios ranging from sea-level rise to heat waves. This survey tests the hypotheses that the respondents: (i) are unable to consistently match the concept of resiliency with the normative meanings or applications: and (ii) will not consistently show a preference for resilience applications or outcomes ahead of other concepts. The results of the survey confirm both hypotheses, which is demonstrative of the inadequacy of the current framework dominated by a narrowly defined framework for resilience. It is anticipated that the results of this article will advance an argument for the necessity to develop consistent meanings for concepts which bridge the scientific, policy and popular domains.     

The Role of Mineral Weathering Rate Determinations in Generating Uncertainties in the Calculation of Critical Loads of Acidity and their Exceedance

Current legislation within Europe aimed at limitingecosystem damage resulting from inputs of atmosphericpollution is based on the critical load concept. Mineralweathering rates are central to the calculation ofcritical loads (acceptable levels) of acid deposition.The authors have undertaken a number of studies whichillustrate the complications and limitations inherent inpredicting mineral weathering rates and the implicationswhich these have for critical loads calculations andmapping. Calculated weathering rates and critical loadsfor two acid-sensitive parent materials (greywackes andgranites) are presented and are used to illustrate theimpact that uncertainty can have on critical loadexceedances. The results have obvious implications forportraying the uncertainties of critical loads to policy makers.     

Curtin industrial safety trial: Managerial behavior and program effectiveness

Behavior-based safety has been found universally efficacious when evaluated under controlled conditions. The Curtin Trial aimed to test the general acceptability of behavior-based safety in Australian industry. A 50% failure rate was observed. This paper presents the results of a qualitative analysis of observed managerial behavior in relation to program effectiveness. Field notes taken in the course of 325 hours of participant observation during implementation of behavior-based safety in 9 work areas were analyzed qualitatively and categorized. These data were compared with statistical results of the safety program's effectiveness on improving safe practices and good housekeeping. Nine dimensions to managerial behavior were identified which were associated with program effectiveness. A relatively small number of studies investigating organizational characteristics and safety have found generally similar social environmental features to those observed in this study. Behavior-based safety appears to be effective only in organizations with recognizable managerial styles.     

Stakeholder Involvement in Coastal Decision-making Processes

This article discusses the current framework of coastal decision making which tends to exclude participation by individuals and those without a strong institutional representation. A distinction is drawn between institutional and local stakeholders to illustrate weaknesses in the existing decision framework. It is argued that particularly in the coastal environment, the relationship between changes in physical form and changes in social welfare is critical to understanding how decision making may engage more fully with local stakeholders and ultimately improve decision outcomes. A reordering of stakeholder engagement in decision systems at the coast is proposed and a framework is outlined which enhances the capacity of local stakeholders to influence decision making.     

Vulnerability of exporting nations to the development of a carbon label in the United Kingdom

Carbon labels inform consumers about the amount of greenhouse gases (GHGs) released during the production and consumption of goods, including food. In the future consumer and legislative responses to carbon labels may favour goods with lower emissions, and thereby change established supply chains. This may have unintended consequences.We present the carbon footprint of three horticultural goods of different origins supplied to the United Kingdom market: lettuce, broccoli and green beans. Analysis of these footprints enables the characterisation of three different classes of vulnerability which are related to: transport, national economy and supply chain specifics.There is no simple relationship between the characteristics of an exporting country and its vulnerability to the introduction of a carbon label. Geographically distant developing countries with a high level of substitutable exports to the UK are most vulnerable. However, many developing countries have low vulnerability as their main exports are tropical crops which would be hard to substitute with local produce.In the short term it is unlikely that consumers will respond to carbon labels in such a way that will have major impacts in the horticultural sector. Labels which require contractual reductions in GHG emissions may have greater impacts in the short term.     

Status and trends of terrestrial arthropod abundance and diversity in the North Atlantic region of the Arctic

Ambio - The Circumpolar Biodiversity Monitoring Programme (CBMP) provides an opportunity to improve our knowledge of Arctic arthropod diversity, but initial baseline studies are required to...     

FOREST COVER,IMPERVIOUS‐SURFACE AREA,AND THE MITIGATION OF STORMWATER IMPACTS1

ABSTRACT: For 20 years, King County, Washington, has implemented progressively more demanding structural and nonstructural strategies in an attempt to protect aquatic resources and declining salmon populations from the cumulative effects of urbanization. This history holds lessons for planners, engineers, and resource managers throughout other urbanizing regions. Detention ponds, even with increasingly restrictive designs, have still proven inadequate to prevent channel erosion. Costly structural retrofits of urbanized watersheds can mitigate certain problems, such as flooding or erosion, but cannot restore the predevelopment flow regime or habitat conditions. Widespread conversion of forest to pasture or grass in rural areas, generally unregulated by most jurisdictions, degrades aquatic systems even when watershed imperviousness remains low. Preservation of aquatic resources in developing areas will require integrated mitigation, which must including impervious‐surface limits, forest‐retention policies, stormwater detention, riparian‐buffer maintenance, and protection of wetlands and unstable slopes. New management goals are needed for those watersheds whose existing development precludes significant ecosystem recovery; the same goals cannot be achieved in both developed and undeveloped watersheds.