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151.
Gagne S Lesage J Ostiguy C Cloutier Y Van Tra H 《Journal of environmental monitoring : JEM》2005,7(2):145-150
Occupational exposures to isocyanates can lead to occupational asthma. Once sensitized, some workers could react to isocyanate monomers at concentrations below 1% of the Permissible Exposure Limit of 5 ppb in air. Currently available methods are not sufficiently sensitive to adequately evaluate isocyanates present at these levels in workplace air. This article describes a novel method for isocyanate determination allowing the ultratrace quantification in workplace air of hexamethylene diisocyanate, 2,4-toluene diisocyanate and 2,6-toluene diisocyanate monomers. Sampling is performed during a complete workshift at a flow rate of 1 L min(-1) with a cassette containing a 1-(2-methoxyphenyl)piperazine-impregnated 25 mm filter. Analysis is performed using liquid chromatography hyphenated with coordination ionspray tandem mass spectrometry. The analytical method's linearity was measured for a concentration range varying from the limit of detection of 0.04-0.13 ng mL(-1), depending on the monomer, up to approximately 32 ng mL(-1) for every isocyanate monomer, all with correlation coefficients (R(2)) greater than 0.999. The analytical method's lower limit of quantification combined with an adapted sampling strategy allow the quantification of isocyanate monomers down to 0.04 ppt for an 8 h work shift when a lithium adduct is used, which is more than 300 times lower than the most sensitive method currently available. This novel method can be used to confirm the very low level of isocyanate monomers for the safe reassignment of sensitized workers and it is also useful for charting the isocyanate dispersion tail in workplace environments. 相似文献
152.
Roose P Van Thuyne G Belpaire C Raemaekers M Brinkman UA 《Journal of environmental monitoring : JEM》2003,5(6):876-884
Twenty freshwater eels caught in Flanders (Belgium) were analysed by GC-MS for a total of 52 VOCs. The most prominent VOCs are the BTEX and a number of chlorinated compounds such as chloroform and tetrachloroethene. The observed concentrations which, typically, were in the low ng/g wet weight range, could be linked to the major emission sources and the present study gives new evidence that combustion of fossil fuels is a major source of BTEX in the environment. The concentration levels in eels seem to be a reflection of the actual concentrations in their environment. For eels from the same location similar patterns and concentrations were observed, and the concentrations agree with what can be expected from those of the water column. Generally speaking, the observed concentrations do not seem to pose a threat for organisms. More definite statements will, however, require a larger dataset. The study suggests that the yellow eel can possibly be used as a biomonitor or sentinel organism for VOCs. 相似文献
153.
Versonnen BJ Goemans G Belpaire C Janssen CR 《Environmental pollution (Barking, Essex : 1987)》2004,128(3):363-371
As part of a large-scale monitoring program of bioaccumulating contaminants in the European eel (Anguilla anguilla) in Flanders (Belgium), we investigated potential effects of xenoestrogens in these fish. The present paper describes the results of the plasma vitellogenin (VTG) content, measured in 142 eels sampled at 20 different locations, in relation to the internal pollution levels. To validate the blood VTG assays, a small number of eels (n=8) was exposed to 10 microg ethinylestradiol/l (EE2) for 9 days. In this experiment, VTG was detected as a protein with a molecular weight of 214 kDa and confirmed by Western blotting. Compared with the solvent controls, significantly higher concentrations of VTG were measured in EE2 exposed eel. However, the VTG content was relatively low compared with other fish species exposed to high concentrations of estrogens. The plasma VTG content of eels from the field study was very low, despite a very high internal load of endocrine disrupters. These results, together with previously published studies, suggest that immature yellow European eel might not be the best sentinel species to study the effects of estrogenic compounds on VTG levels of wild fish populations. 相似文献
154.
Ecosystem Decay of Amazonian Forest Fragments: a 22-Year Investigation 总被引:49,自引:1,他引:49
155.
Claude D'Ercole Léon Boubli Jacqueline Franck Michel Casta Jean-Robert Harle Catherine Chagnon Ludovic Cravello Michèle Leclaire Bernard Blanc 《黑龙江环境通报》1995,15(12):1171-1175
We describe the case of a patient with systemic lupus erythematosus, treated by corticosteroids, who presented during two successive pregnancies with serological reactivation of toxoplasmosis associated with fetal lesions. The first infected fetus died in utero with signs of hydrops. The second fetus was treated in utero with a combination of sulfadoxine and pyrimethamine, administered to the mother, and is now well. The increasing number of immunocompromised pregnant patients with immunity to Toxoplasma gondii may lead to a higher risk of reactivation of maternal toxoplasmosis and congenital infection. 相似文献
156.
Olivier Maire Jean Claude Duchêne Jean Michel Amouroux Antoine Grémare 《Marine Biology》2007,151(2):737-749
The activity and surface sediment displacement by the terebellid polychaete Eupolymnia nebulosa were monitored, using new image acquisition and image analysis procedures. We used a video sensor mounted on a motorized
table, to acquire adjacent images of the whole studied aquarium within about 2 s. These images were then grouped within a
composite image acquired every 15 s. Consecutive composite images were compared to infer activity and surface sediment displacement.
This procedure proved efficient for E. nebulosa as indicated by (1) the continuity of the tentacles within composite images, and (2) the direct comparison of images and
detected activities. There were important temporal changes in the relative importance of the three main types of activity:
feeding, tube-building and (both partial and total) emergence from the tube, accounting, respectively, for 75, 15 and 10%
of the entire experiment duration. Activity intensity (cm2 min-1) was assessed through the surface of pixels with grey levels differing by more than 20 (on a 0–255 scale) between two consecutive
images. Feeding was associated with low activity intensity, whereas tube-building and emergence from the tubes were associated
with high activity intensities. Surface sediment displacement mostly resulted from tentacle activity both during feeding and
tube-building and was almost zero when worms emerged from their tube. We used our experimental set up to assess spatial changes
in activity intensity and particle displacements along the tentacles. Most of the activity occurred within the first 4–6 cm
from the tube aperture. Particle loss during their transfer along the tentacles preferentially affected larger particles as
postulated by the model of particle selection and transport in tentaculate deposit-feeders. Moreover, the speed of the particles
along the tentacles correlated negatively with their size. This contributed to increase in the residence time of larger particles
on the tentacles and thus, to further enhance their probability of being lost. The size distributions of particles during
feeding and tube-building did not differ significantly although visual observations confirmed the preferential use of larger
particles for tube-building. This suggests the existence of a sorting step occurring elsewhere than on the tentacles as already
demonstrated for spionid polychaetes. 相似文献
157.
Restoration ecology of riverine wetlands: I. A scientific base 总被引:10,自引:0,他引:10
158.
Annie‐Claude Parent François Anctil Véronique Cantin Marie‐Amélie Boucher 《Journal of the American Water Resources Association》2008,44(3):679-688
Abstract: Snowmelt largely affects runoff in watersheds in Nordic countries. Neural networks (NN) are particularly attractive for streamflow forecasting whereas they rely at least on daily streamflow and precipitation observations. The selection of pertinent model inputs is a major concern in NNs implementation. This study investigates performance of auxiliary NN inputs that allow short‐term streamflow forecasting without resorting to a deterministic snowmelt routine. A case study is presented for the Rivière des Anglais watershed (700 km2) located in Southern Québec, Canada. Streamflow (Q), precipitations (rain R and snow S, or total P), temperature (T) and snow lying (A) observations, combined with climatic and snowmelt proxy data, including snowmelt flow (QSM) obtained from a deterministic model, were tested. NN implemented with antecedent Q and R produced the largest gains in performance. Introducing increments of A and T to the NNs further improved the performance. Long‐term averages, seasonal data, and QSM failed to improve the networks. 相似文献
159.
Francesca Romana Grati Denise Molina Gomes Jose Carlos Pinto B. Ferreira Celine Dupont Viola Alesi Laetitia Gouas Nina Horelli-Kuitunen Kwong Wai Choy Sandra García-Herrero Alberto Gonzalez de la Vega Krzysztof Piotrowski Rita Genesio Gloria Queipo Barbara Malvestiti Bérénice Hervé Brigitte Benzacken Antonio Novelli Philippe Vago Kirsi Piippo Tak Yeung Leung Federico Maggi Thibault Quibel Anne Claude Tabet Giuseppe Simoni François Vialard 《黑龙江环境通报》2015,35(8):801-809
160.