EDTA优化纳米Pd/Fe对2,4-D的催化脱氯研究

采用EDTA优化纳米Pd/Fe催化脱氯水中2,4-二氯苯氧乙酸(2,4-D),并考察了EDTA投加浓度、pH、钯化率、温度等因素对2,4-D还原的影响.结果表明,EDTA的加入络合了纳米Pd/Fe在催化脱氯过程中生成的铁离子,抑制纳米Pd/Fe颗粒表面钝化层的形成,提高了体系的反应活性.适宜的EDTA浓度、低pH、高钯化率、低温等有利于2,4-D的还原脱氯.当EDTA浓度为25.0 mmol·L-1,纳米铁含量为1.0 g·L-1,初始pH=4.3、钯化率为0.5%,温度为25.0℃,搅拌速率为200 r·min~(-1)时,反应50 min,10.0 mg·L-1的2,4-D去除率及苯氧乙酸(PA)生成率均达到100%.     

怪异的「碧利斯」

2006年强热带风暴“碧利斯”,气象专家用“怪异”两个字形容它。其特点是,形状怪异,没有统一的台风中心：路径怪异,移动速度忽快忽慢。专家们指出,这类热带风暴风力不是特别强,但含水量比较大,容易发生强降雨。7月14日12时50分,怪异的强热带风暴“碧利斯”如期在福建省霞浦县北壁镇登陆。     

绿色

绿色是生命的原色,是季节变换的符号。但是在现实生活中,她的内涵己在不断变化并得到升华而被广泛地应用。在上世纪70年代,世界单一个环保组织“绿色和平环境保护组织”就是以“绿色”作为头冠,在欧     

立足保障提高防震减灾能力

近年来,青岛市重视防震减灾工作,围绕地震监测预报、震害防御、应急救援三大工作体系建设,积极推动防震减灾工作不断发展。进一步提高了防震减灾综合能力。逐步完善机构设置1997年,设立青岛市地震局,专门负责防震减灾行政管理;2001年,在市级机关机构改革中,将市地震局设为市政府直属部门,从市科技局所属的二级局升格为正局级部门,主管全市防震     

饱和粉末活性炭电化学再生研究

采用电化学再生法对吸附处理染料废水产生的饱和粉末活性炭(PAC)进行再生,以NaCl为电解质,考察了电源类型、pH、再生时间、电压和NaCl浓度对活性炭再生率的影响,并对活性炭表面酸性含氧官能团进行测定。结果表明:(1)在pH=1、直流电压为6V、NaCl为6g/L、再生90min的最佳条件下,采用单室反应器,饱和PAC再生率达到59.09%。(2)电极循环伏安曲线结果表明,饱和PAC电极表面发生氧化反应,与主电极直接和间接氧化共同作用,使活性炭表面吸附的污染物降解。活性炭表面酸性含氧官能团滴定和红外光谱测试结果进一步表明,电化学再生法使活性炭表面基团得到恢复。     

我国循环经济行业2009年发展综述

概述了2009年我国循环经济发展状况,以及国家颁布的相关法规、政策和指导性文件,分析了钢铁、有色金属、煤炭、水泥、电力、造纸等行业利用新技术发展循环经济取得的成效,指出了国内循环经济行业发展中存在的主要问题,提出了解决对策及建议。     

我国机动车污染防治行业2009年发展综述

综述了2009年我国机动车污染防治行业的发展环境及市场特点、主要(骨干)企业发展情况,分析了2009年行业发展中存在的主要问题,提出了解决对策和建议,并对行业的发展进行了展望。     

Concentrations,atmospheric partitioning,and air–water/soil surface exchange of polychlorinated dibenzo-p-dioxin and dibenzofuran along the upper reaches of the Haihe River basin,North China

Polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/PCDF) were overall measured and compared in ambient air, water, soils, and sediments along the upper reaches of the Haihe River of North China, so as to evaluate their concentrations, profiles, and to understand the processes of gas–particle partitioning and air–water/soil exchange. The following results were obtained: (1) The average concentrations (toxic equivalents, TEQs) of 2,3,7,8-PCDD/PCDF in air, water, sediment, and soil samples were 4,855 fg/m³, 9.5 pg/L, 99.2 pg/g dry weight (dw), and 56.4 pg/g (203 fg TEQ/m³, 0.46 pg TEQ/L, 2.2 pg TEQ/g dw, and 1.3 pg TEQ/g, respectively), respectively. (2) Although OCDF, 1,2,3,4,6,7,8-HpCDF, OCDD, and 1,2,3,4,6,7,8-HpCDD were the dominant congeners among four environmental sinks, obvious discrepancies of these congener and homologue patterns of PCDD/PCDF were observed still. (3) Significant linear correlations for PCDD/PCDF were observed between the gas–particle partition coefficient (K _p) and the subcooled liquid vapor pressure (P _L ⁰) and octanol–air partition coefficient (K _oa). (4) Fugacity fraction values of air–water exchange indicated that most of PCDD/PCDF homologues were dominated by net volatilization from water into air. The low-chlorinated PCDD/PCDF (tetra- to hexa-) presented a strong net volatilization from the soil into air, while high-chlorinated PCDD/PCDF (hepta- to octa-) were mainly close to equilibrium for air–soil exchange.     

Concentration and health risk evaluation of heavy metals in market-sold vegetables and fishes based on questionnaires in Beijing,China

Concentrations of heavy metals (As, Cd, Pb, Cu, Ni, Fe, Mn, and Zn) in market vegetables and fishes in Beijing, China, are investigated, and their health risk to local consumers is evaluated by calculating the target hazard quotient (THQ). The heavy metal concentrations in vegetables and fishes ranged from not detectable (ND) to 0.21 mg/kg fresh weight (f.w.) (As), ND to 0.10 mg/kg f.w. (Cd), and n.d to 0.57 mg/kg f.w. (Pb), with average concentrations of 0.17, 0.04, and 0.24 mg/kg f.w., respectively. The measured concentrations of As, Cd, Pb, Cu, Ni, Fe, Mn, and Zn are generally lower than the safety limits given by the Chinese regulation safety and quality standards of agriculture products (GB2762-2012). As, Cd, and Pb contaminations are found in vegetables and fishes. The exceeding standard rates are 19 % for As, 3 % for Cd, and 25 % for Pb. Pb contaminations are found quite focused on the fish samples from traditional agri-product markets. The paper further analyzed the health risk of heavy metals in vegetables and fishes respectively from supermarkets and traditional agri-product markets; the results showed that the fishes of traditional agri-product markets have higher health risk, while the supermarkets have vegetables of higher heavy metal risk, and the supervision should be strengthened in the fish supply channels in traditional agri-product markets.     

Research of the Response of Ecosystem to LUCC in Miyun County, Beijing： Based on Ecosystem Services Valuation

Miyun County,located in the northeast of Chinese capital Beijing,was underwent remarkable variations in land use in recent years.This paper aimed to detect changes in land use of Miyun from 1997 to 2005,and to qualify the response of ecosystem to LUCC based on ecosystem services valuation.With two-periods TM images,we got land use change data,and then ecosystem services values were calculated using ecosystem services valuation coefficients proposed by Chinese scholar Xie Gaodi.Results showed that water area,farm land and unused land decreased while residential land,forest land,grassland and orchard land increased during the study period.The loss of ESV was RMB 206 million and the main reason was the decrease of water area and farm land area.As for spatial variation,there were most dramatically land use change and ESV decline in reservoir ecological protection region.The coefficient sensitivity analysis indicates that valuation coefficients used in the study are suitable and results are reasonable.The driving forces of ESV loss were rapid population growth and economic development.More work should be done to make eco-environment stay healthy.