春季广州城区空气中VOCs来源解析

2013年4月在广州市区对大气中挥发性有机化合物(VOCs)进行了观测,对其变化特征和来源进行了分析。结果表明,观测期间测得的VOC总平均混合比为41.35×10~(-9),表现为烷烃芳香烃烯烃炔烃;利用PMF解析出观测时段内影响广州市区的9个VOCs主要来源,各源占比情况依次为:LPG排放老化VOC汽油挥发石化、未知源汽油车排放油漆溶剂柴油车排放天然源;与机动车相关和工业相关的来源分别占到了大气VOCs的46.8%和21.0%。     

Occurrence,sources, and ecological risks of PBDEs,PCBs, OCPs,and PAHs in surface sediments of the Yangtze River Delta city cluster,China

Polybrominated diphenyl ethers (PBDEs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs) in 25 surface sediments in three cities (Nantong, Wuxi, and Suzhou) in the Yangtze River Delta, eastern China were measured. The mean concentrations were 378, 45.8, 1.98, 4,002 ng/g for PBDEs, OCPs, PCBs, and PAHs, respectively. Their levels in the sediments in the three cities were generally consistent with the city industrialization. PBDEs and OCPs were markedly dominated by deca-BDE (>90 %) and DDTs (>70 %). A principle component analysis of the analytes identified three major factors suggesting different sources of the contaminants in the sediments. PBDEs and the organic carbon in the sediments have common sources from industrial activities; whereas OCPs and PCBs, correlated with the second factor, were mainly from historical sources. The third factor with loadings of PAHs is indicative of various combustion sources. Ecological risk assessment indicated that the potential highest risk is from DDTs, for which 22 sites exceed the effects range low (ERL) values and three sites exceed the effects range median (ERM) value.     

Simulation of substrate degradation in composting of sewage sludge

To simulate the substrate degradation kinetics of the composting process, this paper develops a mathematical model with a first-order reaction assumption and heat/mass balance equations. A pilot-scale composting test with a mixture of sewage sludge and wheat straw was conducted in an insulated reactor. The BVS (biodegradable volatile solids) degradation process, matrix mass, MC (moisture content), DM (dry matter) and VS (volatile solid) were simulated numerically by the model and experimental data. The numerical simulation offered a method for simulating k (the first-order rate constant) and estimating k₂₀ (the first-order rate constant at 20 °C). After comparison with experimental values, the relative error of the simulation value of the mass of the compost at maturity was 0.22%, MC 2.9%, DM 4.9% and VS 5.2%, which mean that the simulation is a good fit. The k of sewage sludge was simulated, and k₂₀, k_20s (first-order rate coefficient of slow fraction of BVS at 20 °C) of the sewage sludge were estimated as 0.082 and 0.015 d^?1, respectively.     

WATCH

Abstract

The development of everthing follows its own law, which does not change at people's own sweet will. Therefore, we must study the development of things so as to grasp the essence of things in their deep meanings, explore the direction of their development, and make them better serve the people. As a part of the thought of sustainable development, city environment art will be of active significance to the perfection of the thought and will also be the concrete embodiment of the synthetic index of economic development. Such a thesis, starting from the macroscopic angle, and relying on the leading thought of sustainable development, takes hold of the development trend of city environment art, and explores the various problems that have arisen in city environment in the process of city management by combining thoughts on city planning, so as to guide urban harmonious development theoretically. The present paper expounds on the views comprehensively and, through the synthetic analysis on city planning, city environment, art esthetics and the thought of sustainable development, makes a detailed analysis of the effects of the present rapid city development on city environment.     

Optimization of hydrogen distribution systems with pressure constraints

Hydrogenation units are often operated at high pressure, requiring the use of compressors which are one of the most expensive chemical processing equipment. Optimizing a hydrogen network should therefore take into consideration not only purity and flowrate constraints but also pressure requirements. In this paper, based on the hydrogen surplus diagram approach, the average pressure profiles of hydrogen sources and sinks are proposed through the introduction of a system’s minimum pressure drop Δp. Combined with the traditional purity profiles, whether a source can meet a sink either for hydrogen concentration or for pressure requirements can be determined intuitively. In cases where the pressure of a source is not sufficient for a sink, installing a hydrogen compressor or using another source with higher purity and pressure could be potential solutions. A cost equation is established to determine which of the two solutions is economically more viable. For different matching situations between sources and sinks, strategies for optimum placement of compression equipment within a given hydrogen network are proposed. A case study is used to illustrate the application and effectiveness of the proposed method.     

Trip-Based Explanatory Variables For Estimating Vehicle Fuel Consumption and Emission Rates

The current state-of-practice in the US for estimatingvehicle emissions is based on a single traffic-relatedexplanatory variable, namely average speed. Research,however, has demonstrated that the use of average speed asa single traffic-related variable is insufficient for theestimation of vehicle emissions. For example, although theEnvironmental Protection Agency (EPA) MOBILE5 model wouldindicate that a slowing of traffic typically increasesemissions, empirical research indicates the opposite inmany cases.The objective of this paper is to identify criticalaggregate trip variables as potential explanatory variablesfor the estimation of a vehicle's fuel consumption andemissions. Subsequently, statistical models for estimatingfuel consumption and emissions of hydrocarbon (HC), carbonmonoxide (CO), and oxides of nitrogen (NO_x) aredeveloped using these critical variables that include theaverage speed, speed variability, the level ofdeceleration, and the level of acceleration. The proposedmodels are demonstrated to be consistent with microscopicenergy and emission model estimates that are based on thevehicle's instantaneous speed and acceleration levels(coefficient of determination ranges from 0.88 to 0.96).     

构建煤矿职业安全卫生管理体系

安全生产是煤矿企业的头等大事。根据煤矿企业的实际特点 ,分析了煤矿安全生产管理的现状、特点和煤矿建立职业安全卫生管理体系的注意事项。讨论了建立煤矿职业安全卫生管理体系的步骤和方法     

工业企业安全生产管理的规范化研究

根据安全系统工程原理,探讨和提出了一种被当地试点所证明、可行的工业企业安全生产综合、简便的规范化管理方法。把国家有关安全生产法律法规有机地贯穿于基础规范管理工作过程之中;建立了动态性管理模式;为积极引导企业的安全管理工作,由事故管理向预防性管理,从行政管理向依法管理,由传统管理向技术性管理的方向转变,并为促进现代企业形成自主经营,相互制约,依法管理安全生产的运行机制提供了新思路