全文获取类型
收费全文 | 1396篇 |
免费 | 91篇 |
国内免费 | 520篇 |
专业分类
安全科学 | 117篇 |
废物处理 | 105篇 |
环保管理 | 105篇 |
综合类 | 801篇 |
基础理论 | 264篇 |
污染及防治 | 461篇 |
评价与监测 | 47篇 |
社会与环境 | 40篇 |
灾害及防治 | 67篇 |
出版年
2024年 | 8篇 |
2023年 | 36篇 |
2022年 | 78篇 |
2021年 | 62篇 |
2020年 | 65篇 |
2019年 | 41篇 |
2018年 | 59篇 |
2017年 | 57篇 |
2016年 | 78篇 |
2015年 | 105篇 |
2014年 | 105篇 |
2013年 | 134篇 |
2012年 | 108篇 |
2011年 | 142篇 |
2010年 | 106篇 |
2009年 | 95篇 |
2008年 | 81篇 |
2007年 | 77篇 |
2006年 | 59篇 |
2005年 | 59篇 |
2004年 | 48篇 |
2003年 | 59篇 |
2002年 | 43篇 |
2001年 | 36篇 |
2000年 | 42篇 |
1999年 | 50篇 |
1998年 | 33篇 |
1997年 | 29篇 |
1996年 | 16篇 |
1995年 | 25篇 |
1994年 | 24篇 |
1993年 | 16篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 2篇 |
排序方式: 共有2007条查询结果,搜索用时 48 毫秒
141.
在含油污水水质分析的基础上,采用烧杯实验和分光光度法研究絮凝剂的絮凝效果。筛选出以无机絮凝剂硫酸铝与两性高分子聚合物CE-3090的复配体系,同时研究了影响絮凝效果的因素并探究了其影响机理。结果表明:在温度为40℃,pH为7.72,170 r/min时高速搅拌1 min,然后50 r/min低速搅拌5 min,硫酸铝的加量为90 mg/L、CE-3090的加量为0.5 mg/L,絮凝沉降30 min后其絮凝效果较好。实验证明:该复配处理剂处理含油污水后,含油量和杂质含量都达到了SY/T 5329-94《碎屑岩油藏注水水质推荐指标及分析方法》油田污水回注的要求。 相似文献
142.
我国体制转轨时期,面对当前的腐败,究其原因除了腐败本身具有的顽固性尚未得到根本遇制外,缺少科学的廉政考核体系也是一个重要原因.本文从我国公务员康政概念开始,通过一系列指标体系的测量,充分利用现代科技不断进行制度和方法的创新,不断完善我国公务员康政考核的指标体系. 相似文献
143.
连续采样与五日法采样效果及费用的对比分析 总被引:2,自引:0,他引:2
通过对连续采样与五日法采样五种方法监测结果及所需费用的比较,得出连续采样方法监测结果更具有代表性,合理性,一次性投资大,但运行费用并不高的结论。 相似文献
144.
为了研究运动对2,3,7,8-四氯二苯并二恶英(2,3,7,8-TCDD)急性暴露大鼠肝组织酶活性的影响,将40只雄性Wistar大鼠随机分为正常对照组(NC)、染毒组(NT)、运动对照组(EC)、运动染毒组(ET)。染毒组(NT组与ET组)腹腔注射10μg·kg-1(以单位体重计)的TCDD,对照组(NC组与EC组)腹腔注射等量的玉米油;NT、NC组静养4周,ET、EC组运动(尾部负重5%游泳30分钟)4周。4周后,称重并宰杀大鼠,分离肝组织,称重后-80℃保存待测7-乙氧基异吩恶唑酮脱乙基酶(EROD)、7-乙氧基香豆素-O-脱乙基酶(ECOD)及芳香烃羟化酶(AHH)的活性。将数据进行多因素方差分析(MAVONA)处理,结果表明,染毒可降低大鼠体重,增加肝湿重和肝相对重量、增加EROD、ECOD活性;运动可增加大鼠肝相对重量、增加AHH的活性;染毒后运动可降低EROD、ECOD的活性。结论:急性10μg·kg-1(以单位体重计)TCDD染毒后4周可增加大鼠肝相对重量;4周的运动能有效降低TCDD对EROD、ECOD活性的激活作用。 相似文献
145.
A pot experiment was conducted to study the allelopathic effects of initial decomposing leaf litter of Cinnamomum camphora on growth and physiology of Impatiens balsamina. Three leaf litter treatments included 20, 40 and 80 g of C. camphora leaf litter mixed with 8 kg of soil, namely T1, T2, and T3, respectively. In order to test the effect of leaf litter addition on the permeability and ventilation of soil simultaneously, a parallel trial with steamed leaf litter was conducted with the three treatments of the leaf litter. The leaf litter was steamed for 2 d to remove the secondary metabolites as much as possible, dried, and then mixed with 8 kg of soil, namely Z1, Z2, and Z3, respectively. No leaf litter was added in control (CK). The growth parameters of I. balsamina were determined at the 20 d, 60 d, 100 d and 120 d after sowing and the main physiology indicators were determined at the 60 d. The results indicated that: (1) The ground surface diameter and height of I. balsamina were inhibited significantly at 60 d (P < 0.05). Photosynthetic pigments and gas exchange parameters of I. balsamina were inhibited significantly at 60 d, and the inhibition effect was stronger with increased amount of leaf litter addition. The chlorophyll content, Pn and Ls decreased significantly with increased amount of leaf litter (P < 0.05). The activity of superoxide dismutase (SOD) and peroxidase (POD) in leaves of I. balsamina decreased with the increase of leaf litter addition. The content of MDA in treatments T1, T2 and T3 were all higher than that in CK, which indicated that I. balsamina suffered oxidative damage in a certain degree. The content of free proline (Pro) and soluble sugar (SS) in leaves of I. balsamina decreased significantly with the increase of the leaf litter (P < 0.05), while the content of soluble protein (SP) increased. (2) In the parallel trial, 60 d after sowing, no obvious difference was observed between CK and any steamed leaf litter treatment in terms of the morphological and physiological features stated above (P > 0.05). It indicated that the soil physical properties were not greatly influenced by leaf litter addition in the dose interval designed, or that the release of secondary metabolites from decomposing leaf litter was probably a better reason to explain the inhibition of leaf litter treatment to I. balsamina growth. (3)The compound effect (CE) of leaf litter decomposition on I. balsamina was enhanced with increase of the leaf litter, to 0.169, 0.354, and 0.497, respectively, in treatments of T1, T2 and T3. The study indicated that initial decomposition of C. camphora leaf litter in soil reduces the content of photosynthetic pigments, inhibits photosynthetic capacity and resistance physiology of I. balsamina, weakens its adaptability to the environment, and restrains growth of the plant. © 2015, Science Press. All rights reserved. 相似文献
146.
Jianguo LIU Hui CAI Congcong MEI Mingxin WANG 《Frontiers of Environmental Science & Engineering》2015,9(5):905
The current study investigated the effects of nano-silicon (Si) and common Si on lead (Pb) toxicity, uptake, translocation, and accumulation in the rice cultivars Yangdao 6 and Yu 44 grown in soil containing two different Pb levels (500 mg·kg−1 and 1000 mg·kg−1). The results showed that Si application alleviated the toxic effects of Pb on rice growth. Under soil Pb treatments of 500 and 1000 mg·kg−1, the biomasses of plants supplied with common Si and nano-Si were 1.8%–5.2% and 3.3%–11.8% higher, respectively, than those of plants with no Si supply (control). Compared to the control, Pb concentrations in rice shoots supplied with common Si and nano-Si were reduced by 14.3%–31.4% and 27.6%–54.0%, respectively. Pb concentrations in rice grains treated with common Si and nano-Si decreased by 21.3%–40.9% and 38.6%–64.8%, respectively. Pb translocation factors (TFs) from roots to shoots decreased by 15.0%–29.3% and 25.6%–50.8%, respectively. The TFs from shoots to grains reduced by 8.3%–13.7% and 15.3%–21.1%, respectively, after Si application. The magnitudes of the effects observed on plants decreased in the following order: nano-Si treatment>common Si treatment and high-grain-Pb-accumulating cultivar (Yangdao 6)>low-grain-Pb-accumulating cultivar (Yu 44) and heavy Pb stress (1000 mg·kg−1)>moderate Pb stress (500 mg·kg−1)>no Pb treatment. The results of the study indicate that nano-Si is more efficient than common Si in ameliorating the toxic effects of Pb on rice growth, preventing Pb transfer from rice roots to aboveground parts, and blocking Pb accumulation in rice grains, especially in high-Pb-accumulating rice cultivars and in heavily Pb-polluted soils. 相似文献
147.
In this study, palladium-loaded titania nanotubes was fabricated on a titanium plate (Pd/TiO2NTs/Ti) for efficient electrodechlorination of 2,4-chlorophenol with a mild pH condition. The nature of Pd/TiO2NTs/Ti electrodes was characterized by field-emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) techniques. The characterization results indicated the generation of Pd0 nanoparticles which were evenly dispersed on titania nanotubes arrays on the Pd/TiO2NTs/Ti surface. An effective degradation efficiency of up to 91% was achieved within 60 min at cathode potential of −0.7 V (vs. SCE) and initial pH of 5.5. The effects of the applied cathode potential and initial pH on the degradation efficiency were studied. A near neutral condition was more favorable since very low and very high pHs were not conducive to the dechlorination process. Furthermore, the intermediates analysis showed that the Pd/TiO2NTs/Ti electrode could completely remove chlorine from 2, 4-dichlorophenol since only phenol was detected as the byproduct and the concentration of released chlorine ions indicated near-complete dechlorination. This work presents a good alternative technique for eliminating persistent chlorophenols in polluted wastewater without maintaining strong acidic environment. 相似文献
148.
以鲤鱼为实验生物,应用流动式摄取及释放装置,进行了2,6-二硝基甲苯(2,6-DNT)的生物浓缩与释放研究。取得了2,6-DNT在鲤鱼(全鱼)、肝及肠部的生物浓缩曲线。全鱼的浓缩曲线可以稳态(平台式)曲线描述,但是肝、肠部浓缩曲线均呈峰形。肝部峰快速下降后渐趋稳态,肠部峰下降未得稳态。峰形,肝在先,肠在后。对比2,6-DNT在全鱼及肝、肠的生物浓缩曲线,并参照报道(1,2)指出,全鱼摄取曲线上各点所表现的浓度值为各时刻鱼体内各组织摄取化学品总重对全鱼重量的比值。肝、肠部峰形曲线预示了在肝、肠内生物浓缩过程发生了生物转化作用。对全鱼的生物浓缩过程应用单区一级动力学模型,求得BCF值与消除速率常数K1与K2,由K1/K2计算得到的BCF值与实测值相符。释放较慢,释放曲线呈双曲线形,半减期为4.8h。 相似文献
149.
对乌鲁木齐市燃煤点派数量、耗煤量、污染物的排放量以及在各功能区的分布分别进行了统计分析,对污染物的排放量在不同高度空间的分布也进行了统计分析,从而得出了确切的结论并提出了相应的建议。 相似文献
150.
Seasonal trend of ambient PCDD/Fs in Tianjin City, northern China using active sampling strategy 总被引:2,自引:0,他引:2
Lei Ding Yingming Li Pu Wang Xiaomin Li Zongshan Zhao Qinghua Zhang Ting Tuan Guibin Jiang 《环境科学学报(英文版)》2012,24(11):1966-1971
The spatial concentrations, seasonal trends, profiles and congener pairs of ambient polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were investigated within a seasonally active sampling scheme during Jun 2008 and Jan 2009 in Tianjin City, northern China. The PCDD/F concentrations ranged 14.2-172 fg I-TEQ/m3 (average 69.3 fg I-TEQ/m3) in summer and (89.8-1.01) × 103 fg I-TEQ/m3 (average 509 fg I-TEQ/m3) in winter, respectively, except for the E-waste dismantling site where much higher values were observed (1.04 × 103 fg I-TEQ/m3 in summer and 7.123 × 103 fg I-TEQ/m3 in winter). The results indicated a significantly seasonal trend with higher TEQ values in winter as compared with summer, which could be related to increased emission sources and seasonal variations of the atmospheric boundary layer height. 2,3,4,7,8-PeCDF was the dominant contributor to the total PCDD/F toxic equivalents, and 2,3,7,8-TCDD was detected at almost all the sampling sites in winter. Most of the similarly substituted PCDD/F congener pairs exhibited high correlations, suggesting that they might have similar environmental fate or sources. But different seasonal and spatial distributions of PCDD/F concentrations indicated that the emission sources might be intermittent. 相似文献