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561.
滇池沉积物有机磷形态分级特征 总被引:10,自引:2,他引:10
考察沉积物磷对湖泊富营养化贡献时,大量研究涉足无机磷,对有机磷的研究十分薄弱.针对滇池的33个沉积物样品,采用有机磷分级提取方法,将沉积物有机磷分为活性磷、中等活性磷、非活性磷等三种具有不同稳定性的有机磷.结果表明:排除滇池西北部外源污染严重的样品后,沉积物有机磷与总磷有自北向南逐渐降低的变化趋势,有机质与总磷、活性有机磷、中等活性有机磷以及非活性有机磷都表现出了显著相关关系.沉积物活性有机磷和中等活性有机磷与NaHCO3提取无机磷均显著相关,说明二者具有潜在的生物有效性. 相似文献
562.
环境浓度抗生素选择性压力改变活性污泥微生物群落结构 总被引:2,自引:0,他引:2
为探究环境浓度抗生素(5μg·L~(-1)和50μg·L~(-1))选择性压力下活性污泥微生物的性能变化,选择四环素及磺胺甲噁唑2种高频检出的抗生素作为研究对象,分别考察2种抗生素单一和复合作用下对序批式活性污泥反应器(SBR)中废水处理效能、微生物活性及群落结构的影响。结果表明,与不添加抗生素的空白对照组相比,2种抗生素在50μg·L~(-1)和5μg·L~(-1)暴露浓度下,经过60 d运行,COD和NH+4-N去除效果未受明显影响(P0.05),微生物的活菌比变化不显著(P0.05),ATP含量显著降低(P0.05)。在微生物群落结构方面,革兰氏阳性菌增加,革兰氏阴性菌减少,原生动物含量减少,香农-威尔生物多样性指数下降。添加抗生素的样品中微生物优势菌群由变形菌门变为放线菌门,放线菌含量(均高于45%),高于空白对照组(30.72%);放线菌门的Micropruina属所占比例最高(24%),且高于空白对照组(18.77%)。抗生素选择性压力可改变活性污泥微生物的活性及群落结构,但长期作用下对污水处理效能及抗生素抗性基因传播的影响还需要进一步研究。 相似文献
563.
太湖不同湖区沉积物重金属含量季节变化及其影响因素 总被引:3,自引:0,他引:3
以太湖东北部梅梁湾、胥口湾、贡湖沉积物中重金属为研究对象,研究各湖区沉积物中As、Cd、Cu、Pb、Zn含量的年际变化规律及其与沉积物间隙水温度、pH、Eh值以及沉积物有机质、总氮、总磷、粒径等理化指标的相关关系.结果表明:沉积物中重金属含量及其年际的变化与其污染状况有一定的相关关系;富营养化程度较高的梅梁湾沉积物中重金属含量的最大值出现在9月,其他两个湖区的最大值均出现在6月;沉积物中重金属含量受到温度、pH值、Eh值等物理因素的影响,且与温度、pH值和Eh值有一定的正相关关系;沉积物有机质、总氮、总磷、粒径等因素也会对沉积物中重金属含量产生影响;有机质含量与重金属含量有很好的正相关性,粒径与重金属含量呈正相关,总氮、总磷与重金属含量呈负相关. 相似文献
564.
Liang T Zhang S Wang L Kung HT Wang Y Hu A Ding S 《Environmental geochemistry and health》2005,27(4):301-311
With the continual increase in the utilization of rare earth elements (REEs) for industrial and agricultural purposes in China,
the research into the environmental biogeochemical behavior of REEs has become a pressing issue. The REEs’ content in soil
and various parts of wheat under different conditions in soil–plant systems were measured by INAA and ICP-MS. The results
showed four aspects. (1) The mean value of total REEs in soil of China was 176.8 mg kg−1. The mean ratio of ΣLREE/ΣHREE in soils was 8.0 and cerium accounts for 42% of the total REEs. The content of REEs in wheat
seed ranged between 10−11 and 10−8 g g−1, 3–4 orders of magnitude lower than that in soil. (2) The REEs contents in ryegrass, especially in roots, were significantly
related to that of soil. The bioavailability of REEs in soil mainly depended on the exchangeable fraction of REEs, which was
strongly affected by the physico–chemical properties of the soil. (3) Long-term foliage-dressing with Changle microfertilizer
of REEs did not affect the contents and distribution patterns of REEs in soil. At the maturing stage of spring wheat, the
REEs content was in the order of root > leaf >stem and crust. Compared with the control, foliage-dressing has a higher accumulation
of REEs in root and leaf. However, no significant difference was found in stem and crust between the two treatments. (4) There
was no significant accumulation with the soil-dressing method. When comparing controls in both foliage- and soil-dressing
methods, no distinct residue of REEs in grains was found. 相似文献
565.
566.
567.
Occurrence of pharmaceuticals in a municipal wastewater treatment plant: mass balance and removal processes 总被引:3,自引:0,他引:3
Occurrence and removal efficiencies of fifteen pharmaceuticals were investigated in a conventional municipal wastewater treatment plant in Michigan. Concentrations of these pharmaceuticals were determined in both wastewater and sludge phases by a high-performance liquid chromatograph coupled to a tandem mass spectrometer. Detailed mass balance analysis was conducted during the whole treatment process to evaluate the contributing processes for pharmaceutical removal. Among the pharmaceuticals studied, demeclocycline, sulfamerazine, erythromycin and tylosin were not detected in the wastewater treatment plant influent. Other target pharmaceuticals detected in wastewater were also found in the corresponding sludge phase. The removal efficiencies of chlortetracycline, tetracycline, sulfamerazine, acetaminophen and caffeine were >99%, while doxycycline, oxytetracycline, sulfadiazine and lincomycin exhibited relatively lower removal efficiencies (e.g., <50%). For sulfamethoxazole, the removal efficiency was approximately 90%. Carbamazepine manifested a net increase of mass, i.e. 41% more than the input from the influent. Based on the mass balance analysis, biotransformation is believed to be the predominant process responsible for the removal of pharmaceuticals (22% to 99%), whereas contribution of sorption to sludge was relatively insignificant (7%) for the investigated pharmaceuticals. 相似文献
568.
569.
Spatial trend and pollution assessment of total mercury and methylmercury pollution in the Pearl River Delta soil, South China 总被引:2,自引:0,他引:2
Total mercury (THg) and methylmercury (MeHg) were measured in large number of soil samples collected from areas with different types of land use, different depth in the Pearl River Delta (PRD) of South China. THg and MeHg concentrations ranged from 16.7 to 3320 ng g−1 and 0.01 to 1.34 ng g−1, respectively. THg levels are highest in the top 0-20 cm soil layer, and decrease from the surface to bottom layer soil. Spatial variation was observed with different types of land use. Urban parks had the highest concentrations and the other areas tended to decrease in the order of residential areas, industrial areas, vegetable fields, cereal fields, and woodlands. Temporal variation was also noted, and two relatively high THg contamination zones located in the northwestern part of the PRD have significantly expanded over the last two decades. Both THg and MeHg concentrations were correlated significantly with soil organic matter (OM), but not with soil pH. THg pollution status was evaluated using two assessment methods. 相似文献
570.
A Pilot Study on Using Urinary 1-Hydroxypyrene Biomarker for Exposure to PAHs in Beijing 总被引:3,自引:0,他引:3
Zhang W Xu D Zhuang G Ding C Wang G Chang J Ren G 《Environmental monitoring and assessment》2007,131(1-3):387-394
To study whether the urinary 1-hydroxypyrene (1-OHP) could be the biomarker of atmospheric PAHs, a small-scale pilot study
was carried out on the relation of 1-OHP vs PAHs with the traffic policemen in Beijing of smokers and nonsmokers to be subgroups
in both the exposure and control groups. Both the PAHs and 1-OHP were analyzed with high performance liquid chromatography
(HPLC). The ambient concentrations of PAHs were different at the different sites (the average sum of PAHs (TPAH) were 12.36,
16.27, 18.37 ng/m3 at the suburban residential, police station and high traffic area, respectively.), but considerably lower than the personal-exposure
concentrations (the average TPAH were 65.84 and 47.28 ng/m3 for patrol cars and inspection station, respectively). Pyrene was correlated well with BaP and the summed PAHs (TPAH), with
the correlation coefficients (R) of 0.79, 0.87 for ambient level and 0.92, 0.96 for personal exposure, respectively. The average of 1-hydroxypyrene of smokers
and nonsmokers were 0.39, 0.15 μmol/mol creatinine in control group and 0.57, 0.33 μmol/mol creatinine in exposure group,
respectively. The better correlation of pyrene to BaP and TPAH especially for personal exposure samples indicated that the
probability of urinary 1-hydroxypyrene, the metabolite of pyrene, to be the biomarker of total PAH. Nonsmokers in the exposure
and control groups had indistinguishable levels of 1-OHP, presumably because the ambient levels of pyrene were so similar
(the average were 3.25, 3.20 ng/m3 at the police station and high traffic area, respectively.). Smokers in the control group had significantly higher 1-OHP
than that of the nonsmokers, but showed indistinguishable differences in the exposure group. These results suggested that
urinary 1-OHP could be a biomarker of PAHs only when the level of PAHs was at a relatively higher level. Smoking as an important
influencing factor need to be controlled carefully. 相似文献