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251.
Environmental Science and Pollution Research - Aulacoseira granulata (Ehrenberg) Simonsen 1979 are considered as the eco-variable species which varies in density and diversity along with their...  相似文献   
252.
ABSTRACT

Alkyd paint continues to be used indoors for application to wood trim, cabinet surfaces, and some kitchen and bathroom walls. Alkyd paint may represent a significant source of volatile organic compounds (VOCs) indoors because of the frequency of use and amount of surface painted. The U.S. Environmental Protection Agency (EPA) is conducting research to characterize VOC emissions from paint and to develop source emission models that can be used for exposure assessment and risk management. The technical approach for this research involves both analysis of the liquid paint to identify and quantify the VOC contents and dynamic small chamber emissions tests to characterize the VOC emissions after application. The predominant constituents of the primer and two alkyd paints selected for testing were straight-chain alkanes (C9–C12); C8–C9 aromatics were minor constituents. Branched chain alkanes were the predominant VOCs in a third paint. A series of tests were performed to evaluate factors that may affect emissions following application of the coatings. The type of substrate (glass, wallboard, or pine board) did not have a substantial impact on the emissions with respect to peak concentrations, the emissions profile, or the amount of VOC mass emitted from the paint. Peak concentrations of total volatile organic compounds (TVOCs) as high as 10,000 mg/m3 were measured during small chamber emissions tests at 0.5 air exchanges per hour (ACH). Over 90% of the VOCs were emitted from the primer and paints during the first 10 hr following application. Emissions were similar from paint applied to bare pine board, a primed board, or a board previously painted with the same paint. The impact of other variables, including film thickness, air velocity at the surface, and air-exchange rate (AER) were consistent with theoretical predictions for gas-phase, mass transfer-controlled emissions. In addition to the alkanes and aromatics, aldehydes were detected in the emissions during paint drying. Hexanal, the predominant aldehyde in the emissions, was not detected in the liquid paint and was apparently an oxidation product formed during drying. This paper summarizes the results of the product analyses and a series of small chamber emissions tests. It also describes the use of a mass balance approach to evaluate the impact of test variables and to assess the quality of the emissions data.  相似文献   
253.
    
A severe problem has developed with respect to the efficiency of certain hot-side electrostatic precipitators. The problem is manifested by a time dependent degradation of performance in which back corona related to a condition of high ash resistivity is the influencing factor. Performance can be restored by thorough cleaning of the precipitator only to experience the degradation once again. This paper hypothesizes an explanation for these observations. Experiments with both high and low resistivity ashes using resistivity test cells and a laboratory corona discharge device have been run to prove the validity of the suggested explanation. Data substantiate the idea that in the precipitation process a thin layer of ash more or less permanently remains on the collection plates and that the sodium ions serving as charge carriers in the conduction process through the layer are depleted leaving a thin layer of ash having extremely high resistivity. This phenomenon is called electrode polarization, sodium depletion, or an ash layer space charge depending on one's scientific discipline. Suggestions of remedial steps which may be of benefit in counteracting this difficulty are given.  相似文献   
254.
Environmental Science and Pollution Research - There has recently been an increase in the usage of TiO2 nanoparticles (NPs). P25 TiO2 NPs, a mixture of anatase and rutile phase in 3:1 ratio, are...  相似文献   
255.
Environmental Science and Pollution Research - Porous carbon nanospheres were synthesized from agro-waste garlic peels by a one-pot facile and easy to scale-up pyrolysis method. Surface morphology...  相似文献   
256.
    
The purpose of this study is to assess the effect of manganese (Mn) from methylcyclopentadienyl manganese tricarbonyl (MMT) on grass (Tradescancia) species beside the major urban and rural highways in the greater Toronto area. Grass clippings were collected at distances up to 40 m from the roadside of a wooded, weakly exposed site (E+) and two unwooded, highly exposed sites (E++ and E+++) to Mn contamination. Statistical tests, including analysis of variance and correlation coefficients, were used to compare the Mn deposition on grass species with respect to distance and traffic density. A higher deposition of Mn was expected at the highly exposed sites when compared with the weakly exposed site, but a significantly higher concentration of Mn was observed at weakly exposed rural E+ site (Mn = 54.07 microg/g; dry wt) than the highly exposed urban E++ (Mn = 38.17 microg/g; dry wt) and E+++ (Mn = 35.63 microg/g; dry wt) sites. A significant correlation coefficient was found for Mn and traffic density (r2 = 0.311, p = 0.0074) at the weakly exposed site than at the highly exposed (r2 = 0.1589, p = 0.1052) urban sites. These data demonstrate that despite the continuous use of MMT in Canadian gasoline, the levels do not appear to exceed the worldwide tolerable levels (17-334 g/g; dry wt) in grass species inhabiting ecosystems next to major highways in urban regions.  相似文献   
257.
Environmental Science and Pollution Research - The vertical distribution pattern and concentrations of elements (Fe, Al, Ca, Mg, Mn, Cr, Cu, Ni, Co, Pb, Zn, and As) in the estuarine and lagoon...  相似文献   
258.
    
ABSTRACT

Conversion varnishes are two-component, acid-catalyzed varnishes that are commonly used to finish cabinets. They are valued for their water and stain resistance, as well as their appearance. They have been found, however, to contribute to indoor emissions of organic compounds. For this project, three commercially available conversion varnish systems were selected. A U.S. Environmental Protection Agency (EPA) Method 24 analysis was performed to determine total volatile content, and a sodium sulfite titration method was used to determine uncombined (free) formaldehyde content of the varnish components. The resin component was also analyzed by gas chromatography/mass spectroscopy (GC/MS) (EPA Method 311 with an MS detector) to identify individual organic compounds. Dynamic small chamber tests were then performed to identify and quantify emissions following application to coupons of typical kitchen cabinet wood substrates, during both curing and aging. Because conversion varnishes cure by chemical reaction, the compounds emitted during curing and aging are not necessarily the same as those in the formulation. Results of small chamber tests showed that the amount of formaldehyde emitted from these coatings was 2.3–8.1 times the amount of free formaldehyde applied in the coatings. A long-term test showed a formaldehyde emission rate of 0.17 mg/m2/hr after 115 days.  相似文献   
259.
260.
Land change science has demonstrated that rural livelihoods around the world both drive and reflect changing environmental regimes and political economic/structural transformations. This article explores the relationship between increasingly globalized rural livelihoods and in-place land change, assessing results from social surveys of smallholding households in the southern Yucatán region. We examine evidence for a transition in agricultural livelihood strategies as smallholders adjust to changing political economic and institutional conditions, and link these transitioning strategies to land use changes. Based on household surveys in 1997 and 2003, we comparatively assess both changes in the selection of livelihood strategies and in the land use and cover impacts of those strategies. Our results indicate that although impacts of given strategies have changed little over this period, there are increasing proportions of households pursuing two divergent adjustment paths—one of agricultural withdrawal and one of agricultural intensification and commercialization. We investigate what sociodemographic characteristics differentiate the groups of households following distinct livelihood strategies. Our findings point to the possibility of simultaneous and contradictory land change outcomes as smallholders adjust in different ways to their intensified incorporation into global economies.  相似文献   
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