Optimal feed profile for a second order reaction in a semi-batch reactor under safety constraints: Experimental study

Maximising the yield of the second order reaction (2-butanol+propionic anhydride) by manipulating the inlet flow rate is considered for an isothermal semi-batch process. First a procedure for the determination of the kinetic parameters using coupled spectroscopic and calorimetric methods is presented. Then an optimisation of the reaction system is performed numerically and verified experimentally. Constraints on the amount of heat produced and on the temperature attainable in the case of cooling failure are imposed for safety consideration.     

Insecticide resistance may enhance the response to a host-plant volatile kairomone for the codling moth, <Emphasis Type="Italic">Cydia pomonella</Emphasis> (L.)

The behavioral and electroantennographic responses of Cydia pomonella (L.) to the ripe pear volatile ethyl (2E,4Z)-2,4-decadienoate (Et-E,Z-DD), were compared in insecticide-susceptible and -resistant populations originating from southern France. A dose–response relationship to this kairomonal attractant was established for antennal activity and did not reveal differences between susceptible and resistant strains. Conversely, males of the laboratory strains expressing metabolic [cytochrome P450-dependent mixed-function oxidases (mfo)] or physiological (kdr-type mutation of the sodium-channel gene) resistance mechanisms exhibited a significantly higher response to Et-E,Z-DD than those of the susceptible strain in a wind tunnel experiment. No response of the females to this kairomone could be obtained in our wind-tunnel conditions. In apple orchards, mfo-resistant male moths were captured at significantly higher rates in kairomone-baited traps than in traps baited with the sex pheromone of C. pomonella. Such a differential phenomenon was not verified for the kdr-resistant insects, which exhibited a similar response to both the sex pheromone and the kairomonal attractant in apple orchards. Considering the widespread distribution of metabolic resistance in European populations of C. pomonella and the enhanced behavioral response to Et-E,Z-DD in resistant moths, the development of control measures based on this kairomonal compound would be of great interest for the management of insecticide resistance in this species.     

Econometric analysis of the determinants of adoption of alley farming by farmers in the forest zone of southwest Cameroon

Slash-and-burn agriculture continues to expand in many parts of the forest zone of Cameroon. One alternative land use to slash-and-burn system is alley farming. This paper quantifies, using an econometric model, the factors determining farmers’ adoption and use of alley farming variants in southwest of Cameroon, based on a survey of 156 farmers in 11 villages in the region.The analysis showed that male farmers are more likely to adopt than women. Adoption is higher for farmers with contacts with extension agencies working on agroforestry technologies. Adoption is higher for farmers belonging to farmers’ groups. Adoption is lower for farmers in areas with very high population pressure, as farmers in such areas may have greater labor productivity from use of less labor intensive natural resource management technologies like chemical fertilizers. Adoption is higher for farmers in areas facing fuel wood scarcity. Farmers have made adaptations to the conventional alley farming technology recommended by researchers, the most significant adaptation being the introduction of fallow periods into the system. Farmers use alley farming as a land use option, not as a replacement for the slash-and-burn system, since land supply is still relatively elastic. Achieving increased impact with alley farming variants requires effective targeting. Results showed that econometric modeling using farmer and village characteristics, socioeconomic and institutional variables can lead to more effective targeting to farmers and locations where higher adoption rates may occur.