Fate of 17β-estradiol in terrestrial model ecosystems amended with contaminated composted biosolids

Biosolids spread onto agricultural soils are potential sources of steroidal hormones that are able to adversely affect the soil ecosystem. Here we studied the fate of the [4-¹⁴C]-17-β-estradiol hormone in laboratory experiments. First, our results show that only 2.9% of the hormone was mineralized in the soil from a French vineyard. By contrast, the mineralization increased to 7.1% when the hormone was provided in composted biosolids. Second, we found that only a minor part of the estradiol-derived ¹⁴C was mobile and partly transferred to soil leachates. Indeed, the hormone was mainly stabilized in the soil as non-extractable residues. Overall, our findings show that estradiol undergoes two main processes, complete degradation and stabilisation. We therefore conclude that the environmental risk of hormones provided to the soil through composted biosolids is negligible under the conditions of our experiments.     

Impact of UV-irradiation on the formation of odorous chloroaldimines in drinking water

In order to explain some of the possible origins of an odor episode which took place in a drinking water supply in the region of Paris (France), the impact of disinfection on the formation of odorous by-products was investigated. We have previously established that very odorous and stable chloroaldimines are formed during amino acid chlorination in conditions relevant to those of drinking water treatment. As chlorination is preceded by a UV-irradiation step, we examined here the impact of this irradiation on the formation of chloroaldimines. Irradiation (30 m W cm(-2)) of various amino acids (glycine, valine, phenylalanine) and peptides (Phe-Gly-Gly-Phe, Phe-Ala) led to a degradation of the compounds but it was negligible at the doses applied in drinking water supplies. As peptides were concerned, contrary to what we previously expected, the degradation did not involve the peptidic bond breaking: irradiation induces therefore no increase in the quantity of free amino acids, precursors of odorous chloroaldimines. However chlorination of peptides (Phe-Ala-Ala-Val, Phe-Gly-Gly-Phe and Ala-Phe) showed that chloroaldimines are also probably formed during combined amino acids chlorination.     

Estimating the safety performance of urban intersections in Lisbon,Portugal

According to official statistics, a large percentage of crashes in Portugal are reported on urban roads. For instance, from 2004 to 2007, about 70% of all injury accidents and 43% of the fatalities occurred inside urban agglomerations. This important safety problem has also been observed on the urban network of Lisbon. Understanding this significant problem, the Government of the Portuguese Republic via its research grant agency – The Foundation for Science and Technology – funded a project whose primary objective consists of developing tools that would help estimating the safety performance of various components of the urban highway system in Lisbon. This paper documents one component of the safety tools that were developed and describes the steps that were taken to develop predictive models for estimating the safety performance of signalized and unsignalized intersections of Lisbon. Several crash predictive models were developed using the Poisson-gamma modeling framework. Two types of models were estimated: flow-only and models with covariates. They were estimated using crash and other related data collected at 44 three-legged and 50 four-legged intersections for the years 2004–2007, inclusively. It was found that some highway geometric design characteristics were associated with the crashes occurring at urban three- and four-legged intersections in Lisbon.     

Spatial interpolation of air temperature using environmental context: Application to a crop model

The air temperature is one of the main input data in models for water balance monitoring or crop models for yield prediction. The different phenological stages of plant growth are generally defined according to cumulated air temperature from the sowing date. When these crop models are used at the regional scale, the meteorological stations providing input climatic data are not spatially dense enough or in a similar environment to reflect the crop local climate. Hence spatial interpolation methods must be used. Climatic data, particularly air temperature, are influenced by local environment. Measurements show that the air above dry surfaces is warmer than above wet areas. We propose a method taking into account the environment of the meteorological stations in order to improve spatial interpolation of air temperature. The aim of this study is to assess the impact of these corrected climatic data in crop models. The proposed method is an external drift kriging where the Kriging system is modified to correct local environment effects. The environment of the meteorological stations was characterized using a land use map summarized in a small number of classes considered as a factor influencing local temperature. This method was applied to a region in south-east France (150×250 km) where daily temperatures were measured on 150 weather stations for two years. Environment classes were extracted from the CORINE Landcover map obtained from remote sensing data. Categorical external drift kriging was compared to ordinary kriging by a cross validation study. The gain in precision was assessed for different environment classes and for summer days. We then performed a sensitivity study of air temperature with the crop model STICS. The influence of interpolation corrections on the main outputs as yield or harvest date is discussed. We showed that the method works well for air temperature in summer and can lead to significant correction for yield prediction. For example, we observed by cross validation a bias reduction of 0.5 to 1.0°C (exceptionally 2.5°C for some class), which corresponds to differences in yield prediction from 0.6 to 1.5 t/ha.     

Dwelling and the experience of burglary

This study attempts to define the fundamental dimensions of the home experience through its dramatization, in this case, when one is burgled. It is based on thirty-six interviews conducted with middle-class urban dwellers who had been burgled a year prior to the interview. The analysis of the data was mainly thematic and hermeneutical. It shows that the dwelling experience is the experience of boundaries, the door being a limit between inside and outside, and also a limit within oneself. Moreover, the uncontrolled access by another person to the hidden/secret subspaces of the dwelling incites reactions which reveal the importance of the dweller's visibility. Lastly, the re-appropriation processes which take place after the burglary show that dwelling is essentially a sum of future-orientated actions.     

Heavy metal load and effects on biochemical properties in urban soils of a medium-sized city,Ancona, Italy

Environmental Geochemistry and Health - Urban soils are often mixed with extraneous materials and show a high spatial variability that determine great differences from their agricultural or natural...     

Revitalization of Chinese’s manufacturing industry under the carbon neutral goal

Since the beginning of the Industrial Revolution, the manufacturing industry has been crucial for economic growth. China’s manufacturing activity began after China approved and opened legal reform to the rest of the world in 1978. There are usually three stages of development, including the catch-up period. At the same time, they reflect the private economic sector, manufacturing, and foreign exchange industries, and the opening up to the international markets. This advancement comes along with high energy consumption, leading to a high rate of pollution. Therefore, this study provides a detailed overview of the “Made in China 2025” pilot target and implementations of policies to achieve a carbon-neutral goal. We assessed the efficiency of implementing policies in the Chinese manufacturing sector and recommended decision-making policies to achieve the “Made in China 2025” plan and the 2030 carbon-neutral goal. The Quantitative Strategic Programming Matrix (QSPM) and SWOT analysis matrix were used to put forward some development strategies to transform and upgrade China’s manufacturing industry by combining relevant strategic theories. This study is significant in terms of energy-saving and carbon emission-reducing policy implementations for the Chinese manufacturing industry. In addition, we suggested some measures to achieve a sustainable environment in line with carbon-neutral policies.