A STAGE-ACTIVATED TRIGGERING DEVICE FOR AUTOMATIC PUMPING SAMPLERS1

A device to trigger automatic pumping samplers at discrete stages on headwater streams in southeastern Oklahoma was developed. The magnetic switch column employs a sequence of magnetic reed switches wired in parallel and set at 0.03 m (0.10 ft) intervals. A magnetic float inside the column closes the reed switches, therby triggering the sampler as stage rises and falls. The columns were constructed from inexpensive, readily-available materials. Following installation and field calibration, the columns provided relaible and representative sampling during 12 storms, at three sites. The magnetic switch column may be used in a wide range of research and monitoring sites to improve water quality sampling.     

The hazards of risk management

Summary Increasing application of the concept of risk raises several policy and management issues for environmental managers. Functionally, risk can be structured as risk assessment, risk management and risk communication. Each of these functional areas have complex technical issues associated with them that are often unfamiliar to the public.Dr Donald W. Floyd is an Assistant Professor in the School of Natural Resources at The Ohio State University. He specialises in natural resource/environmental policy, with an emphasis on conflict resolution.     

Some stochastic differential equation models of an aquatic ecosystem

A set of stochastic differential equations has been used to model an aquatic ecosystem. The randomness in the system has been introduced through initial conditions of the state variables, parameters, and input variables (light and temperature). These models were analysed using Monte Carlo simulation procedures and the results were similar to those observed in the experimental and field data. They were different, however, from the results of a deterministic simulation. This approach allows us to incorporate the maximum degree of information in the model and to study the behavior of the system without arbitrarily manipulating the values of the parameters. Some possible refinements and generalizations of this approach are also discussed.     

Abiotic reduction reactions of anthropogenic organic chemicals in anaerobic systems: A critical review

This review is predicated upon the need for a detailed process-level understanding of factors influencing the reduction of anthropogenic organic chemicals in natural aquatic systems. In particular, abiotic reductions of anthropogenic organic chemicals are reviewed. The most important reductive reaction is alkyl dehalogenation (replacement of chloride with hydrogen) which occurs in organisms, sediments, sewage sludge, and reduced iron porphyrin model systems. An abiotic mechanism involving a free radical intermediate has been proposed. The abstraction of vicinal dihalides (also termed dehalogenation) is another reduction that may have an abiotic component in natural systems. Reductive dehalogenation of aryl halides has recently been reported and further study of this reaction is needed. Several other degradation reactions of organohalides that occur in anaerobic environments are mentioned, the most important of which is dehydrohalogenation. The reduction of nitro groups to amines has also been thoroughly studied. The reactions can occur abiotically, and are affected by the redox conditions of the experimental system. However, a relationship between nitro-reduction rate and measured redox potential has not been clearly established. Reductive dealkylation of the N- and O-heteroatom of hydrocarbon pollutants has been observed but not investigated in detail. Azo compounds can be reduced to their hydrazo derivatives and a thorough study of this reaction indicates that it can be caused by extracellular electron transfer agents. Quinone-hydroquinone couples are important reactive groups in humic materials and similar structures in resazurin and indigo carmine make them useful as models for environmental redox conditions. The interconversion of sulfones, sulfoxides, and sulfides is a redox process and is implicated in the degradation of several pesticides though the reactions need more study. Two reductive heterocyclic cleavage reactions are also mentioned. Finally, several difficulties (both semantic and experimental) that recur in the studies reviewed are discussed. The subtle effects of various sterilization techniques on extracellular biochemicals and complex chemical reducing agents in sediment have stifled attempts to separate abiotic from biological degradation reactions. The characterization of redox conditions in a natural system is still problematic since measured redox potential is not adequate. Suggestions for future research toward a process-level understanding of abiotic chemical reductions are made.     

A cost function for neutralizing acidic Adirondack surface waters

A cost function for neutralizing acidic surface waters by base addition (liming) is derived based upon constrained cost minimization. The model is estimated using a sample of 547 acidic Adirondack lakes with total costs projected for neutralizing each lake to one of six possible target alkalinity levels. Empirical findings indicate that relatively accurate forecasts of lake neutralization costs can be obtained given target alkalinity levels and various limnological characteristics. The results provide a model for predicting lake neutralization costs which can potentially be used in evaluating the relative merits of alternative strategies for reducing acidic deposition damages.     

UNCERTAINTY ANALYSIS OF RUNOFF ESTIMATES FROM A RUNOFF CONTOUR MAP1

ABSTRACT: The U.S. Environmental Protection Agency (EPA) in cooperation with the U.S. Geological Survey (USGS) conducted an analysis to quantify the uncertainty associated with interpolating runoff to specific sites using a runoff contour map. We interpolated runoff to 93 gaged watersheds from a runoff contour map using (1) hand interpolation to the watershed outlet, (2) a computer interpolation to the watershed outlet, and (3) hand interpolation to the watershed centroid. We compared the interpolated values to the actual gaged values and found that there was a bias in the average interpolated value for runoff estimated at basin outlets, with interpolated values being less than the actual. We found no significant difference between the hand interpolation method and the computer interpolation method except that the computer method tended to have higher variability due to factors inherent to the software used. There were no strong spatial correlations or regional patterns in the runoff interpolations, which indicates that there are no regional biases introduced in the development of the contour map. We determined that we could estimate runoff, on the average, within approximately 8.9 cm (3.5 in; 15 percent) of the measured value using the three methods. The results of this work indicate that runoff contour maps can he used in regional studies to estimate runoff to ungaged systems with quantifiable uncertainty.