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991.
992.
van Wezel AP Morinière V Emke E ter Laak T Hogenboom AC 《Environment international》2011,37(6):1063-1067
The application of engineered nanomaterials increases strongly. Development of analytical techniques and their application to environmental samples is essential for human and environmental risk assessment of the nanoparticles. The objective of this study was to develop a sensitive analytical method to quantify nC(60) in water, using accurate mass screening liquid chromatography-hybrid linear ion trap Orbitrap mass spectrometry. nC(60) can be transformed by oxidation, reduction and photochemical reaction. Therefore, the formation of some transformation products of nC(60) was studied as well. Finally, the developed analytical method was applied to surface water samples from several locations in the Netherlands. The developed method enabled to detect and quantify aqueous concentrations of the summed nC(60) and its transformation products as low as 5 ng/L. It was observed that nC(60) transformation products exceed quantities of the parent C(60). Despite the high sensitivity of the developed method, no nC(60) or transformation products were detected in an array of Dutch surface waters. This might be due to low emissions, losses in the aqueous phase by sedimentation, sorption or further transformation processes. 相似文献
993.
Sundström M Ehresman DJ Bignert A Butenhoff JL Olsen GW Chang SC Bergman A 《Environment international》2011,37(1):178-183
The widespread presence of perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), and perfluorohexanesulfonate (PFHxS) in human general populations and their slow elimination profiles have led to renewed interest in understanding the potential human neonatal exposures of perfluoroalkyls (PFAs) from consumption of human milk. The objective of this study was to evaluate the concentrations of PFOS, PFHxS, and PFOA in pooled human milk samples obtained in Sweden between 1972 and 2008 (a period representing the most significant period of PFA production) and to see whether the time trend of these analytes parallels that indicated in human serum. Chemical analysis of PFOS, PFHxS, and PFOA was performed on pooled Swedish human milk samples from 1972 to 2008 after methodological refinements. The 20 samples which formed the 2007 pool were also analyzed individually to evaluate sample variations. Analyses were performed by HPLC-MS/MS. Due to the complexities of the human milk matrix and the requirement to accurately quantitate low pg/mL concentrations, meticulous attention must be paid to background contamination if accurate results are to be obtained. PFOS was the predominant analyte present in the pools and all three analytes showed statistically significant increasing trends from 1972 to 2000, with concentrations reaching a plateau in the 1990s. PFOA and PFOS showed statistically significant decreasing trends during 2001-2008. At the end of the study, in 2008, the measured concentrations of PFOS, PFHxS, and PFOA in pooled human milk were 75 pg/mL, 14 pg/mL, and 74 pg/mL, respectively. The temporal concentration trends of PFOS, PFHxS, and PFOA observed in human milk are parallel to those reported in the general population serum concentrations. 相似文献
994.
de Nazelle A Nieuwenhuijsen MJ Antó JM Brauer M Briggs D Braun-Fahrlander C Cavill N Cooper AR Desqueyroux H Fruin S Hoek G Panis LI Janssen N Jerrett M Joffe M Andersen ZJ van Kempen E Kingham S Kubesch N Leyden KM Marshall JD Matamala J Mellios G Mendez M Nassif H Ogilvie D Peiró R Pérez K Rabl A Ragettli M Rodríguez D Rojas D Ruiz P Sallis JF Terwoert J Toussaint JF Tuomisto J Zuurbier M Lebret E 《Environment international》2011,37(4):766-777
995.
Baeza A Vallejo I Guillén J Salas A Corbacho JA 《Journal of environmental radioactivity》2011,102(3):311-315
Adequate radioprotection of the environment requires the identification of biomonitors sensitive to the variation of its radionuclide content. Due to the chemical similarities between calcium and strontium, calcified tissues of mammals are considered to be good 90Sr biomonitors. This work considered Cervus elaphus antlers which, being shed annually, can give information about the importance of radiostrontium contamination in an ecosystem in the time period required for the growth of the antler. The samples were collected at various points of W and SW Spain. The mean value of their 90Sr content was (70 ± 43 (S.D.)) Bq/kg d.w., range (16-218) Bq/kg d.w., and the radionuclide was evenly distributed in the different parts of the antler. There was a good correlation between the antlers’ 90Sr content and the 90Sr deposited in the soil. The antlers’ content of 226Ra (from the natural uranium series) and the contents of some stable elements (Ca, Mg, Sr, and K) were also determined. The values for these stable elements were practically constant in the analyzed samples, and the concentrations measured decreased in the following order:Ca » Mg > K > Sr » 90Sr > 226Ra 相似文献
996.
Jiménez MA Martín-Valdepeñas JM García-Talavera M Martín-Matarranz JL Salas MR Serrano JI Ramos LM 《Journal of environmental radioactivity》2011,102(11):995-1007
In the frame of an epidemiological study carried out in the influence areas around the Spanish nuclear facilities (ISCIII-CSN, 2009. Epidemiological Study of The Possible Effect of Ionizing Radiations Deriving from The Operation of Spanish Nuclear Fuel Cycle Facilities on The Health of The Population Living in Their Vicinity. Final report December 2009. Ministerio de Ciencia e Innovación, Instituto de Salud Carlos III, Consejo de Seguridad Nuclear. Madrid. Available from: http://www.csn.es/images/stories/actualidad_datos/especiales/epidemiologico/epidemiological_study.pdf), annual effective doses to public have been assessed by the Spanish Nuclear Safety Council (CSN) for over 45 years using a retrospective realistic-dose methodology. These values are compared with data from natural radiation exposure. For the affected population, natural radiation effective doses are in average 2300 times higher than effective doses due to the operation of nuclear installations (nuclear power stations and fuel cycle facilities). When considering the impact on the whole Spanish population, effective doses attributable to nuclear facilities represent in average 3.5 × 10−5 mSv/y, in contrast to 1.6 mSv/y from natural radiation or 1.3 mSv/y from medical exposures. 相似文献
997.
Al-Jundi J Li WB Abusini M Tschiersch J Hoeschen C Oeh U 《Journal of environmental radioactivity》2011,102(6):574-580
High indoor radon concentrations in Jordan result in internal exposures of the residents due to the inhalation of radon and its short-lived progeny. It is therefore important to quantify the annual effective dose and further the radiation risk to the radon exposure. This study describes the methodology and the biokinetic and dosimetric models used for calculation of the inhalation doses exposed to radon progeny. The regional depositions of aerosol particles in the human respiratory tract were firstly calculated. For the attached progeny, the activity median aerodynamic diameters of 50 nm, 230 nm and 2500 nm were chosen to represent the nucleation, accumulation and coarse modes of the aerosol particles, respectively. For the unattached progeny, the activity median thermodynamic diameter of 1 nm was chosen to represent the free progeny nuclide in the room air. The biokinetic models developed by the International Commission on Radiological Protection (ICRP) were used to calculate the nuclear transformations of radon progeny in the human body, and then the dosimetric model was applied to estimate the organ equivalent doses and the effective doses with the specific effective energies derived from the mathematical anthropomorphic phantoms. The dose conversion coefficient estimated in this study was 15 mSv WLM−1 which was in the range of the values of 6-20 mSv WLM−1 reported by other investigators. Implementing the average indoor radon concentration in Jordan, the annual effective doses were calculated to be 4.1 mSv y−1 and 0.08 mSv y−1 due to the inhalation of radon progeny and radon gas, respectively. The total annual effective dose estimated for Jordanian population was 4.2 mSv y−1. This high annual effective dose calculated by the dosimetric approach using ICRP biokinetic and dosimetric models resulted in an increase of a factor of two in comparison to the value by epidemiological study. This phenomenon was presented by the ICRP in its new published statement on radon. 相似文献
998.
Fukushima fallout in Northwest German environmental media 总被引:1,自引:0,他引:1
Traces of short- and long-lived fallout isotopes (131I, 134Cs and 137Cs) were found in environmental samples collected in Northwest Germany (rain water, river sediment, soil, grass and cow milk) from March to May 2011, following the radioactivity releases after the nuclear accident in Fukushima, Japan. The measured concentrations are consistent with reported concentrations in air, amount of rainfall and expected values applying simple radioecological models. The [134Cs]/[137Cs] ratio reported for air (about 1) allows for discrimination between “recent” and “old” 137Cs. Expected 136Cs values fell below the detection limits of the instrumentation, despite large sample masses and long counting times. 相似文献
999.
Ecosystem services and hydroelectricity in Central America: modelling service flows with fuzzy logic and expert knowledge 总被引:1,自引:0,他引:1
Bruno Locatelli Pablo Imbach Raffaele Vignola Marc J. Metzger Efraín José Leguía Hidalgo 《Regional Environmental Change》2011,11(2):393-404
Because ecosystem services are generally not produced and used in the same place, their assessment should consider the flows
of services from ecosystems to users. These flows depend on the characteristics and spatial distribution of ecosystems and
users, the spatial relationships between them, and the presence of filters or barriers between ecosystems and users. The objective
of this paper is to map the ecosystem services provided to the Costa Rican and Nicaraguan hydroelectric sectors, which are
crucial sectors for national sustainable development and depend directly on hydrological ecosystem services. The paper presents
an approach for modelling the flows of multiple services from diverse ecosystems to diverse users through different kinds
of filters in a landscape. The approach uses expert knowledge and fuzzy numbers to handle uncertainties. The analyses for
Costa Rica and Nicaragua show how the approach helps identify priority areas for the conservation and restoration of forests
for the services they provide to the hydroelectric sector. As such, it is a useful tool for defining spatially targeted policies
for the conservation of ecosystem services and for involving the users of ecosystem services in ecosystem management. 相似文献
1000.
Meghann E. Jarchow Justin W. Rice Rebekah M. Ritson Sarah K. Hargreaves 《Sustainability Science》2011,6(2):253-254
Conference organizers are increasingly making efforts to reduce resource use at conferences, yet few responsibilities are
placed on attendees. We hosted an ecology conference and offered attendees a discount if they took a sustainability pledge
agreeing to reduce their resource use at the conference. In a post-conference survey, 83% of respondents reported fulfilling
the pledge, but 62% indicated that convenience was the biggest obstacle impeding their ability to continue the pledge during
and after the conference. We found great willingness by attendees to reduce resource use at and beyond our conference, and
facilitating their participation was an important part of our success. 相似文献