Environmental and biological monitoring of methyl ethyl ketone (MEK)

This study was conducted to evaluate the usefulness of various biological parameters for monitoring of workers exposed to methyl ethyl ketone (MEK). Fifty male workers from a large magnetic videotape factory participated in this study. Personal air samples were collected using 3M organic vapor monitors and analysed for MEK by gas chromatography with flame ionisation detector (FID). 10 mL of urine; blood (1 mL) and exhaled air were also collected at the end of an 8-hour workshift. The headspace GC method was applied for measurement of urinary and blood MEK. MEK in expired air was analysed directly by using a GC/FID.The correlation coefficients (r) between environmental MEK and all other biological parameters measured show significant positive relationships. The r for environmental MEK and urine MEK was 0.84; for blood 0.73 and for breath 0.64. The correlation coefficients between blood and urine was 0.72; blood and breath was 0.88 and urine and breath 0.60. These findings suggest that measurements of unmetabolised MEK in blood, exhaled air and urine can be used for biological monitoring of MEK exposure. Nevertheless, laboratory methodological assessment is in favour of measuring urinary MEK as it is non-invasive and does not have to be analysed immediately after collection.     

Impact of distillery effluent application to land on soil microflora

A pot culture experiment was conducted to evaluate the effect of different treatments of distillery wastewater, i.e. raw, treated, diluted and raw distillery wastewater mixed with domestic waste stabilization pond effluent (1:1) on populations of bacteria, fungi, actinomycetes and nitrogen fixing bacteria. The results indicated that raw wastewater decreased the population of bacteria, fungi and actinomycetes. The growth rates of Rhizobium and Azotobacter were also reduced after raw wastewater application. The toxic effect of raw wastewater was minimized when it was mixed with stabilization pond effluent (1:1), this was demonstrated by an increase in the populations of all the microorganisms studied. When a groundnut plant was irrigated with raw distillery wastewater, no fruits were produced and there was also less nodulation. This study indicates that raw distillery wastewater is very toxic to the soil microorganisms which are important in the soil ecosystem.     

Effect of Humic Acid on the Bioavailability of γ-Hexachlorocyclohexane in Marsilea Minuta (L.)

Effect of various concentrations of humic acid (0.2 to 1%) on thebioavailability of -HCH in vegetative clones of theaquatic fern Marsilea minuta was studied in a staticexperimental bioassay system on different photoperiods. Additionof humic acid showed the reduction in the bioavailability of-HCH in all the photoperiods (72 hr light to 144 hrlight) at the interval of 16 hr light (L) and 8 hr dark (D) inboth aerial and submerged portion as compared to controlindicating its protective role in toxicity.     

Desert Water Harvesting to Benefit Wildlife: A Simple, Cheap, And Durable Sub-Surface Water Harvester for Remote Locations

A sub-surface desert water harvester was constructed in the sagebrush steppe habitat of south-central Idaho, U.S.A. The desert water harvester utilizes a buried micro-catchment and three buried storage tanks to augment water for wildlife during the dry season. In this region, mean annual precipitation (MAP) ranges between about 150–250 mm (6″–10″), 70% of which falls during the cold season, November to May. Mid-summer through early autumn, June through October, is the dry portion of the year. During this period, the sub-surface water harvester provides supplemental water for wildlife for 30–90 days, depending upon the precipitation that year. The desert water harvester is constructed with commonly available, “over the counter” materials. The micro-catchment is made of a square-shaped, 20 mL. “PERMALON” polyethylene pond liner (approximately 22.9 m × 22.9 m = 523 m²) buried at a depth of about 60 cm. A PVC pipe connects the harvester with two storage tanks and a drinking trough. The total capacity of the water harvester is about 4777 L (1262 U.S. gallons) which includes three underground storage tanks, a trough and pipes. The drinking trough is refined with an access ramp for birds and small animals. The technology is simple, cheap, and durable and can be adapted to other uses, e.g. drip irrigation, short-term water for small livestock, poultry farming etc. The desert water harvester can be used to concentrate and collect water from precipitation and run-off in semi-arid and arid regions. Water harvested in such a relatively small area will not impact the ground water table but it should help to grow small areas of crops or vegetables to aid villagers in self-sufficiency.     

Drainage Effects on Stream Nitrate-N and Hydrology in South-Central Minnesota (USA)

Excessive nitrate-N in south-central Minnesota ditches and streams is related to land-use change, and may be contributing to the development of the zone of hypoxia in the Gulf of Mexico. Intensive land-use (agricultural management) has progressively increased as subsurface drainage has improved crop productivity over the past 25 years. We have examined water at varying scales for delta18O and, nitrate-N concentrations. Additionally, analysis of annual peak flows, and channel geomorphic features provided a measure of hydrologic change. Laboratory and field results indicate that agricultural drainage has influenced riverine source waters, concentrations of nitrate-N, channel dimensions and hydrology in the Blue Earth River (BER) Basin. At the mouth of the BER shallow ground water comprises the largest source water component. The highest nitrate-N concentrations in the BER and tributaries typically occurred in May and June and ranged from 7-34 mg L(-1). Peak flows for the 1.01-2-yr recurrence intervals increased by 20-to-206% over the past 25 years. Geomorphic data suggest that small channels (ditches) were entrenched by design, whereas, natural that are disconnected from an accessible riparian corridor. Frequent access to a functioning riparian zone is important for denitrification.     

TPH-contaminated Mexican Refinery Soil: Health Risk Assessment and the First Year of Changes

The soil of a coastal Mexican refinery is quite contaminated, especially by hydrocarbons, with detected concentrations up to 130000 mg kg(-1) as TPHs (total petroleum hydrocarbons). The main sources of contamination are pipelines, valves, and old storage tanks, besides the land disposal of untreated hydrocarbon sediments derived from the cleaning of storage tanks. A health risk assessment (HRA) was carried out in order to measure the risk hazard indexes and clean-up standards for the refinery soil. HRA suggested the following actions to be taken: benzene concentrations must be reduced in eight of the 16 studied refinery zones to 0.0074-0.0078 mg kg(-1). Also, vanadium concentration must be reduced in two zones up to a concentration of 100 mg kg(-1). In only one of all of the studied zones, benzo(a)pyrene concentration must be reduced to 0.1 mg kg(-1). After 1 yr, TPHs showed a diminution of about 52%. Even though TPHs concentrations were variable, during 1999 the average concentrations were as much as 15.5 times the goal concentration. For year 2000, TPHs concentrations were only 7.4-fold the proposed value. For the 1999-2000 period, PAHs (polycyclic aromatic hydrocarbons) concentrations decreased by 82%. Some PAHs with 2, 3, 4, and 5 aromatic rings were removed up to 100% values.     

Effects of Roadway Crossings on Leaf Litter Processing and Invertebrate Assemblages in Small Streams

The effects of the Maine Turnpike (Interstate 95) on leaf litter processing were examined in five first- and second-order coastal plain streams in southern Maine, U.S.A. Invertebrate assemblages and red maple leaf softening and loss rates were compared at 53 stations arrayed upstream and downstream of the turnpike. Litter softening rate was not affected by the roadway. Litter loss rate was significantly faster at downstream stations (-0.0024 degree-day(-1)) than at upstream stations or at stations nearest the roadway, which were not different from each other (-0.0022 degree-day(-1)). Litter softening and loss rates were more strongly related to physical and chemical habitat variables than to shredder assemblage characteristics. Significant among-stream differences were observed in most community structural metrics and in biomass of important shredder taxa, but effects of the roadway were rarely consistent among streams. This is attributed in part to habitat variation, which was greater among streams than within streams. This study suggests that while the presence of the Maine Turnpike may influence stream water quality and habitat structure, the relatively subtle effects of roadway runoff and associated habitat modifications on stream ecosystem processes are masked by within- and among-stream variability in litter processing and leaf pack invertebrate assemblage structure.     

Organochlorine Pesticide Residues in Wheat and Drinking Water Samples from Jaipur, Rajasthan, India

The organochlorine pesticide contamination in dietary sources has caused serious threat to the human progeny. The present study was therefore conducted to evaluate the pesticide contamination in wheat flour and drinking water from Jaipur City, Rajasthan, India using Gas Chromatograph. All the wheat and water samples were found to be contaminated with various organochlorine pesticide residues of DDT and its metabolites, HCH and its isomers, heptachlor and its expoxide and aldrin. The amount of pesticide detected in wheat flour was higher than the permissible limits prescribed by WHO/FAO. In drinking water only a few pesticides exceeded the permissible limits. Seasonal variations of pesticides residues were also observed during the study period.     

Selection and Calibration of Numerical Modeling in Flow and Water Quality

Numerical modeling is frequently used in coastal engineering research and application. One possible issue associated with using this method however, is that initial outcomes might differ from expectation. Modeling manipulation addresses this issue by changing the initial parameters which in turn affects the final output results. The advancement of modeling techniques in recent years has seen a gradual but steady accruement of knowledge regarding the relationship between input parameters and possible outputs, which has resulted in improved accuracy and efficiency methods. The advancements within this field have predominantly occurred on an individual basis and as such lack standardisation. An expert numerical modeler may use this knowledge subconsciously, yet may not know how to convey it to the model users. This paper has been written to introduce a systematic intelligent coding schema designed to organise current coastal engineering modeling manipulation knowledge into a standardised format. This system is relevant to the development of appropriate strategies for improved accuracy and efficiency as well as model modification to simulate specific real phenomena in prototype application cases.