复合催化氧化技术对油气田压裂返排液的处理研究

酸化压裂作业废水是石油天然气生产过程中的主要污染源,它的污染成份复杂,有害物质浓度高,特别是含有胍胶和表面活性剂等高分子物质,具有高COD、高稳定度、高粘度的特点.本文通过对压裂液的来源、水质特征、治理现状等常用方法的分析,确定了物理化学脱稳,过滤、O3/H2O2复合催化氧化、深度氧化的达标治理工艺路线.经过处理后的压裂液澄清透明,达到国家二级排放标准(GB8978-96).     

复合诱变菌处理氨氮废水

采用诱变技术对微生物菌种进行了诱变处理，分别研究了紫外线诱变菌、硫酸二乙酯（DES）诱变菌和复合诱变菌对含氨废水的降解性能。结果表明，复合诱变后获得的变异菌株Z5对含氨废水中NH4^ -N的去除率比单独采用紫外线或DES诱变后获得的菌株有明显的提高。混合菌种对化肥行业废水中COD的NH4^ -N的去除率可以达到95%～98%，出水能达到行业一级排放标准。     

Seed yeast cultivation for salad oil manufacturing wastewater treatment

The mixture of five yeast strains obtained from soil could remove about 85% TOC of oil-rich wastewater in batch test.While the highest MLSS was obtained at an N:C of 1:5,the oil removal decreased with the increase of N:C during yeast sludge cultivation.Ammonium chloride was the best nitrogen source for yeast cultivation from the viewpoint of yeast growth and oil utilizxation.An ammonia concentration of over 1300 mg/L led to mass death of yeast at a pH of 5.The ammonia concentration should be controlled at a level of 1000 mg/L or lower.     

乙烯废碱液综合治理技术探讨

分析了乙烯裂解气碱洗过程所排放废液的组成及性质，讨论了该废液的除油方法及综合治理和利用的途径。     

水质特性和NOM在臭氧氧化和PAC吸附去除MIB、GEOSMIN上的作用

介绍了臭氧氧化、活性炭吸附去除MIB、GEOSMIN时的主要影响因素，分析了各因素对去除率的影响程度及原因。还介绍了臭氧、PAC去除痕量异味物质的机理。     

汞在鲤鱼组织中的蓄积、排出与血流速度的关系

本试验在10±1℃、不喂食条件下测定鲤鱼在30天受汞毒期间鳃、脑和肝胰脏蓄积汞和尾鳍微血管血流速度及30天解毒期间排出汞和血流速度的变化。试验结果:受毒期间鳃中汞的蓄积量最多,解毒期间鳃中汞的排出速度最快;受毒期间血流速度随受毒时间的延长而减慢,又随试验浓度的增高而减慢,解毒期间血流速度随解毒时间的延长而加快;受毒期间高浓度试验组鱼鳃、脑和肝胰脏中汞的蓄积量与血流速度呈负相关,解毒期间鱼鳃中汞的排出量与血流速度呈正相关,汞的浓度与血流速度呈负相关。     

孔板结构脱硫脱水性能的试验研究

通过真实规模的试验台对应用于烟气湿法脱硫洗涤塔中的孔板结构进行了脱硫、脱水效果的试验研究 ,得出了孔板结构与其他结构的脱硫效率间的差异 ,比较了不同结构孔板的脱水效率 ,并进行了理论分析     

Fulvic acid removal by nanoparticle TiO2 using a submerged membrane photocatalysis reactor

The degradation of fulvic acid（FA） by nanoparticle TiO2 in a submerged membrane photocatalysis（SMPC） reactor was studied. In this reactor, photocatalytic oxidation and membrane separation co-occured. The continuous air supplier provided O2 for the photocatalytical reaction and mixed the solution through an airflow controller. The particle TiO2 could automatically settle due to gravity without particle agglomeration so it could be easily separated by microfiltration（MF） membrane. It was efficient to maintain high flux of membranes. The effects of operational parameters on the photocatalytic oxidation rate of FA were investigated. Results indicated that photocatalyst at 0.5 g/L and airflow at 0.06 m^3/h were the optimum condition for the removal of fulvic acid, the removal efficiency was higher in acid media than that in alkaline media. The effects of different filtration duration on permeate flux rate of MF with P25 powder and with nanoparticle TiO2 were compared. Experimental results indicated that the permeate flux rate of MF was improved and the membrane fouling phenomenon was reduced with the addition of nanoparticle TiO2 catalyst compared with conventional P25 powder. Therefore, this submerged membrane photocatalysis reactor can faciliate potential application of photocatalytic oxidation process in drinking water treatment.     

常温酸性腐蚀对热障涂层性能的影响

采用酸性盐雾腐蚀试验对物理气相沉积法制备的热障涂层进行了常温腐蚀,研究了常温酸性盐雾腐蚀对热障涂层的微观形貌以及高温性能的影响.试验结果表明：常温酸性腐蚀使热障涂层表面变得粗糙不平,产生了较大的裂纹.经过150次高温循环氧化后,顶层氧化锆晶粒排列疏松,裂纹进一步扩展,中间层--粘结层氧化速度加快,生成了疏松的TGO层.TGO的体积膨胀效应使得陶瓷/粘结层界面结合力降低,缩短了涂层的使用寿命.     

城市污水高效低耗生物脱氮工艺研究

采用活性污泥与生物膜法相结合工艺处理城市生活污水，可以高效去除污水中的有机物和NH4^ -N。研究结果表明：水力停留时间为7．5h、回流比为1．5、无外加碳源时，COD的去除率大于90％，NH4^ -N的去除率大于99％；平均出水COD小于40mg／L，NH4^ -N小于1mg／L，TN的去除率60％左右；反硝化过程的适宜C／N为4～5。