Surface compositions of carbon sorbents exposed to simulated low-rank coal flue gases

Bench-scale testing of elemental mercury (Hg0) sorption on selected activated carbon sorbents was conducted to develop a better understanding of the interaction among the sorbent, flue gas constituents, and Hg0. The results of the fixed-bed testing under simulated lignite combustion flue gas composition for activated carbons showed some initial breakthrough followed by increased mercury (Hg) capture for up to approximately 4.8 hr. After breakthrough, the Hg in the effluent stream was primarily in an oxidized form (>90%). Aliquots of selected activated carbons were exposed to simulated flue gas containing Hg0 vapor for varying time intervals to explore surface chemistry changes as the initial breakthrough, Hg capture, and oxidation occurred. The samples were analyzed by X-ray photoelectron spectroscopy to determine changes in the abundance and forms of sulfur, chlorine, oxygen, and nitrogen moieties as a result of interactions of flue gas components on the activated carbon surface during the sorption process. The data are best explained by a competition between the bound hydrogen chloride (HCl) and increasing sulfur [S(VI)] for a basic carbon binding site. Because loss of HCl is also coincident with Hg breakthrough or loss of the divalent Hg ion (Hg2+), the competition of Hg2+ with S(VI) on the basic carbon site is also implied. Thus, the role of the acid gases in Hg capture and release can be explained.     

Control of Tamarix in the Western United States: Implications for Water Salvage, Wildlife Use, and Riparian Restoration

Non-native shrub species in the genus Tamarix (saltcedar, tamarisk) have colonized hundreds of thousands of hectares of floodplains, reservoir margins, and other wetlands in western North America. Many resource managers seek to reduce saltcedar abundance and control its spread to increase the flow of water in streams that might otherwise be lost to evapotranspiration, to restore native riparian (streamside) vegetation, and to improve wildlife habitat. However, increased water yield might not always occur and has been substantially lower than expected in water salvage experiments, the potential for successful revegetation is variable, and not all wildlife taxa clearly prefer native plant habitats over saltcedar. As a result, there is considerable debate surrounding saltcedar control efforts. We review the literature on saltcedar control, water use, wildlife use, and riparian restoration to provide resource managers, researchers, and policy-makers with a balanced summary of the state of the science. To best ensure that the desired outcomes of removal programs are met, scientists and resource managers should use existing information and methodologies to carefully select and prioritize sites for removal, apply the most appropriate and cost-effective control methods, and then rigorously monitor control efficacy, revegetation success, water yield changes, and wildlife use.     

Competitive Distortions In An International Emissions Trading Market

The objective of this paper on international greenhouse gasemissions trading is to find the conditions, if any, under which internationaldifferences in domestic permit allocation procedures lead to competitivedistortions.The paper finds that grandfathered firms or sectors do not have a costadvantage over identical auctioned firms or sectors abroad, as long asmarkets are perfectly competitive, because they have to include theopportunity costs of using the permits in the product price. However,grandfathered permits are a capital gift to the firm, inducing a windfallprofit, which implies that a similar firm abroad which has to buy its permitshas a higher cash outflow and hence less financial resources. This aspect ofgrandfathering becomes relevant when considering imperfect competitionor equity.Firstly, it is concluded that competitive distortions may arise underimperfect competition, mainly because the grandfathered firms can outlastthe auctioned firms abroad in a price war. Secondly, it appears thatcompetition (or: the level playing field) is distorted in terms of equity,because the mere process of permit allocation gives the grandfathered firmsa stronger financial position and thus an unfair competitive advantage overtheir auctioned competitors abroad.In legal terms, these findings imply that grandfathering is WTO compatibleif one is only willing to consider efficiency and assume perfect competition.However, grandfathering constitutes an actionable subsidy under WTO lawif one also considers equity or if competition is imperfect, which couldnecessitate some level of international harmonization of domestic permitallocation rules.     

The Information Content of a Scalar Plume – A Plume Tracing Perspective

The ability of many animals and insects to track a plume to its source is a particularly impressive feat when the fluid dynamics is considered. Inspired by this observation this research seeks to identify the information in a passive scalar plume suitable for developing robust and efficient plume tracing algorithms. The subject of this study is a scalar plume emanating from a point source in a turbulent boundary layer which has been modeled in a laboratory facility built specifically for this purpose. A coupled PIV-LIF technique is used to measure the velocity and scalar field in a time resolved fashion. This data set is analyzed and the convergence rates of five single-point statistics, suitable as kernels of plume tracing algorithms, are investigated. The experimental data shows that the scalar fluctuations over long downstream distances from the source are characterized by filamentary structures that lead to relatively slow convergence rates for any statistic that is based on mean concentrations. The scalar intermittency, however, converges rapidly toward its true value, in fact converging to a testable hypothesis for source location direction faster than the time scale of the larger scale plume meander.     

ANALYSIS OF DATA FROM BIOLOGICAL SURVEYS OF STREAMS: DIVERSITY AND SAMPLE SIZE1

ABSTRACT: Brillouin's equation (H) for species diversity from information theory is to be preferred for the purposes of applied ecology over the equation of Shannon (H′) or the more commonly used approximate equation (H″). By its use, the difficult problem of delimiting the extent of the community being sampled in a stream survey can be avoided. Moreover, Brillouin's equation gives the exact diversity of the fully censused collection, whreas Shannon's diversity can only be approximated with a biased estimator. If we regard a sample as a message from the environment to the ecologist, Brillouin's equation is the proper one for computing its diversity. The product moment correlation coefficient between Brillouin's H for the total number of individuals from a group of samples and for randomly chosen subsets of 100 individuals from each sample was nearly as high as the correlation between H and H″ based on the total samples. This indicates that small sample sizes may give a useful diversity index. Replicated subsamples show that much smaller samples than are normally used can discriminate between communities from polluted and unpolluted environments. The use of smaller samples should reduce the cost of stream surveys.     

Plant response to utility right of way construction in the Mojave Desert

Disturbance of flora from utility construction tends to generate new plant growth. This growth changes productivity, diversity, and stability. Although the enhancement of vegetation may balance out the biomass destroyed by the original disturbance, it often adversely affects the quality of the vegetation. Percentage composition of the dominant long-lived perennials combined with quantitative measures are used to assess longterm effects of utility corridor construction. Differential effects of enhancement of vegetation are found along road edges, enhancement under wires of powerlines, and over trenches dug for pipelines. Areas under powerline pylons seem to receive the greatest damage and also show the most variable recovery of vegetation. Significant recovery rates are noticeable where the time span between year of construction has allowed for considerable regrowth of the older corridor. Recovery rates depend on soil type, landform, and other physical features of the disturbed sites. Drastic disturbance in one area or transect site may impede vegetation recovery, whereas slight disturbance might enhance vegetation in another, tending to offset the effect of the drastic disturbance. Disturbed areas and control areas may appear to have similar vegetation covers, biomasses, and densities, but these similarities often vanish when one examines qualitative aspects, such as proportion of long-lived species and presence of characteristic dominants.     

Comparison of measurement methods for the characterization of the black carbon emissions from a T63 turboshaft engine burning conventional and Fischer-Tropsch fuels

Emission measurements of black carbon (BC) mass were conducted on a T63 turboshaft engine, operated at idle and cruise power with conventional and alternative fuels, using an Artium LII-300 laser-induced incandescence analyzer (LII) and AVL model 483 micro soot sensor (MSS) photoacoustic instrument using the manufacturer’s calibration for both instruments. These measurements were compared with elemental carbon (EC) determined by manual and semicontinuous thermal-optical transmission analyses according to National Institute for Occupational Safety and Health (NIOSH) method 5040 as the reference method. The results indicate that both the LII and MSS instruments show good linear correlation with EC for the two fuels and two engine power conditions evaluated. The LII measurements were observed to be biased high (27–49%) and the MSS measurements were biased low (24–35%) relative to EC. The agreement between the instruments and the reference method was substantially improved by applying a calibration of the instruments against a common BC aerosol source. Test data also suggest that the two instruments show some sensitivity to particle size (or properties related to size), specifically for particles with a geometric mean diameter (GMD) <30 nm. This sensitivity is problematic, since new engines or certain combustion conditions in current engines will produce smaller particles compared with the T63 model tested in this study. Further assessments of instrument performance for particles within this size range are therefore warranted.

Implications: Accurate black carbon emission measurements are needed to certify new and in-production commercial aircraft engines. Both the Artium LII-300 and AVL 483 micro soot sensor are currently approved by the International Civil Aviation Organization for this purpose. This study compares the two instruments against elemental carbon (EC) using NIOSH method 5040 as the reference using a T63 turboshaft engine. The results indicate that both instruments correlate reasonably well with EC, and the correlation substantially improved when applying a calibration against a common aerosol source. Sensitivity to particle size may be an issue for both instruments.     

Trace metal concentration in scalp hair of occupationally exposed autodrivers

The concentrations of Cr, Pb, Zn, Cu, Ni and Cd wereanalyzed by Atomic Absorption Spectrophotometer in thescalp hair of professional male autodrivers who areoccupationally exposed to the vehicular/industrialpollutants in the industrial city of Coimbatore, TamilNadu. The unwashed hair samples when compared with thewashed hair showed a significantly higher levels of Cr,Zn and Pb. The correlation coefficient showed a strongmutual dependence on the scalp hair of the exposedindividuals and no correlation was found among the tracemetals except for Ni–Pb and Ni–Cd. The results ingeneral showed a positive exogenous contribution of allthe analyzed industrial trace metals. The drivers who are occupationally exposed to vehicular/industrial pollution are at risk.