Availability of geogenic heavy metals in soils of Thiva town (central Greece)

Potentially toxic metals in the urban chemical environment impose risks to both ecosystem and human health. Here, we evaluate the labile pools and availabilities of non-anthropogenic Ni, Cr, Co and Mn in soil samples from Thiva town (central Greece) and investigate their associations with common soil properties and geochemical data obtained by the aqua regia and single selective dissolutions. Experimental work included the initial application of the sequential extraction protocol proposed by the European Community Bureau of Reference and chemical extractions with ethylenediamine tetraacetic acid solution and a modified physiologically based extraction test with the aim to obtain the operationally defined fractions of plant availability and human bioaccessibility, respectively. The leachate results demonstrated that despite the significant contribution of residual metal species especially for Ni and Cr, the studied serpentine soils provide chemically labile pools for all the considered elements. Nickel was found to be the most available metal with the order being Ni?>?Cr?～?Co?～?Mn for plant uptake and Ni?>?Cr?>?Co?～?Mn for human bioaccessibility. The aqua regia extractable concentrations are not predictors of elemental availabilities except for Ni bioaccessible data interpreting however only a moderate percentage of the total variance. The incorporation of basic soil properties (mostly total organic carbon), geochemical data for the major elements Ca, Mg and Fe and ammonium oxalate extractable Cr significantly improved the estimations for individual elements entailing the strong influence of the chemistry and mineralogy of soil materials to the release of focus metals from the soil matrix. This study provides for the first time bioaccessible data for serpentine-derived soils that are more realistic for evaluating potential adverse effects on the human health.     

Intraspecific competition and high food availability are associated with insular gigantism in a lizard

Resource availability, competition, and predation commonly drive body size evolution. We assess the impact of high food availability and the consequent increased intraspecific competition, as expressed by tail injuries and cannibalism, on body size in Skyros wall lizards (Podarcis gaigeae). Lizard populations on islets surrounding Skyros (Aegean Sea) all have fewer predators and competitors than on Skyros but differ in the numbers of nesting seabirds. We predicted the following: (1) the presence of breeding seabirds (providing nutrients) will increase lizard population densities; (2) dense lizard populations will experience stronger intraspecific competition; and (3) such aggression, will be associated with larger average body size. We found a positive correlation between seabird and lizard densities. Cannibalism and tail injuries were considerably higher in dense populations. Increases in cannibalism and tail loss were associated with large body sizes. Adult cannibalism on juveniles may select for rapid growth, fuelled by high food abundance, setting thus the stage for the evolution of gigantism.     

Radon variations during treatment in thermal spas of Lesvos Island (Greece)

The aim of this paper was to study the variations of radon and daughter nuclei during treatment in the thermal spas of Lesvos Island (Greece). For this purpose, in the thermal spas of Lesvos we have measured the radon concentrations of thermal waters, as well as indoor radon, daughter and coarse particle (>500 nm) concentration. Various instruments and procedures were employed for measurements. Radon concentrations of thermal waters were found to lie in the range 10 and 304 Bq l(-1). Concentration peaks both for radon, radon daughter and coarse particle, were found to appear during filling of baths in the treatment process. The doses delivered to the bathers during treatment were in the range of 0.00670 mSv per year to 0.1279 mSv per year, while the doses delivered to personnel were below 20 mSv per year.     

ICAROS: An Integrated Computational Environment for the Assimilation of Environmental Data and Models for Urban and Regional Air Quality

Integrated environmental management in urban areas is nowadaysconsidered a sine qua non objective of Community and nationalenvironmental and development policies. A large amount ofscientific information on the state of the environment is nowavailable from a large pool of data sources. This work presentsan innovative method for integration of these data sources andeffective coupling of environmental information with appropriatemodels and decision-support tools. State-of-the-art Earthobservation techniques, ground-based air quality measurements,atmospheric transport and chemical modelling, and multi-criteriadecision-aid systems are used in an integrated information fusionenvironment in support of environmental and health impactassessment and decision-making at the urban and regional scales. Results of the pilot application of the method in the area ofLombardy in Northern Italy demonstrate the validity andusefulness of this novel approach.     

To dream or not to dream in Havana: multi-criteria decision-making for material and energy recovery from municipal solid wastes

Currently, solid waste management strategies in Havana are outdated. This paper aimed to select the most suitable alternative for integrating material recovery facilities (MRF) with waste-to-energy technologies in the city of Havana, Cuba. Seven scenarios were considered: combustion, gasification, and hydrothermal carbonization (HTC) with and without carbon capture, and anaerobic digestion (AD). The selection was based on environmental, techno-economic, and social parameters using an analytic hierarchy process (AHP) as a multi-criteria decision-making tool (MCDM). The MCDM-AHP accounted for qualitative criteria (based on experts’ judgments) and quantitative (based on Aspen Plus simulation models). From the MRF, 63% of the input recyclable materials were recovered, representing an energy saving of 256 kW-h/t_MSW. The AHP results showed that environmental criteria had the highest priority, resulting in ~63% and ~73% higher than social and techno-economic criteria, respectively. Likewise, from the techno-economic, environmental, and social sub-criteria analysis, investment risk, pollution, and work safety had the major concern compared with the other sub-criteria levels. Overall, MRF+AD was the most suitable scenario (21% preference) for treating Havana’s municipal solid waste (MSW), followed by combustion and gasification with carbon capture, respectively. This study confirms that AD is a preference option for emerging economies like Cuba, mainly due to low environmental pollution, high social acceptance, and financial stability in the long term.