全文获取类型
收费全文 | 325篇 |
免费 | 26篇 |
国内免费 | 93篇 |
专业分类
安全科学 | 33篇 |
废物处理 | 11篇 |
环保管理 | 30篇 |
综合类 | 191篇 |
基础理论 | 42篇 |
污染及防治 | 77篇 |
评价与监测 | 30篇 |
社会与环境 | 20篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 4篇 |
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 23篇 |
2020年 | 18篇 |
2019年 | 12篇 |
2018年 | 15篇 |
2017年 | 16篇 |
2016年 | 22篇 |
2015年 | 29篇 |
2014年 | 28篇 |
2013年 | 34篇 |
2012年 | 28篇 |
2011年 | 31篇 |
2010年 | 25篇 |
2009年 | 20篇 |
2008年 | 18篇 |
2007年 | 20篇 |
2006年 | 18篇 |
2005年 | 10篇 |
2004年 | 6篇 |
2003年 | 8篇 |
2002年 | 8篇 |
2001年 | 3篇 |
2000年 | 10篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
排序方式: 共有444条查询结果,搜索用时 15 毫秒
351.
352.
垃圾填埋场底土层污染状况调查 总被引:14,自引:4,他引:10
通过钻探取样对一个垃圾场底部支的污染状况进行了现场调查。结果表明,垃圾场下方浅层土壤已受到一定程度的污染,Pb、Cd、Hg、Cr等重元素污染较轻,NH3N、TOC值较高。由于该场地下方粘土层的渗透系数很小,污染物的迁移距离在30cm~40cm左右,能较有效地防止垃圾中污染物的快速下渗适移。 相似文献
353.
以低聚丙烯腈(PANX,X=1,2,4,6)作为聚丙烯腈模型物,采用量子化学从头算的HF/3-21G方法研究PANX和乙烯碳酸酯(EC)分子间的作用.研究表明,聚丙烯腈基体与增塑剂EC分子间存在相互作用,其中N原子和O原子是主要的作用原子,形成了C-H桯…N、C-H桯…O(=C)、C-H…O(-C)3类氢键,同时PANX与EC分子的几何参数发生了明显变化.PANX和EC分子的静电势分析表明,PANX桬C体系分子间作用存在静电力.本研究有助于合理选择增塑剂的种类及优化用量,提高聚合物锂离子电池的安全性;有助于了解锂离子在聚合物电解质中的输运机理,提高聚合物电解质的离子电导率. 相似文献
354.
355.
Rapid economic growth in the last two decades in Shanghai has had a great adverse influence on its air quality. Therefore, the atmospheric pollutants of Shanghai have received much concern. In this study, concentrations of 2,3,7,8-substituted PCDD/Fs and PBDD/Fs congeners were measured in the ambient air of four districts in Shanghai. The mean atmospheric concentrations (TEQs) of total 2,3,7,8-PCDD/Fs and 2,3,7,8-PBDD/Fs were 8031 fg m(-3) (497.1 fg I-TEQ m(-3)) and 1358 fg m(-3) (304.1 fg I-TEQ m(-3)) for Jiading District, 5308 fg m(-3) (289.0 fg I-TEQ m(-3)) and 709 fg m(-3) (146.9 fg I-TEQ m(-3)) for Zhabei District, 4014 fg m(-3) (144.4 fg I-TEQ m(-3)) and 1239 fg m(-3) (256.9 fg I-TEQ m(-3)) for Pudong District, 3348 fg m(-3) (143.2 fg I-TEQ m(-3)) and 699 fg m(-3) (148.4 fg I-TEQ m(-3)) for Huangpu District, respectively. Our results showed that almost all the PCDD/Fs and PBDD/Fs congeners were partitioned into the particulate phase except the lower chlorinated or brominated ones. The logarithm of the gas/particle partitioning coefficient K(p) has good linear correlation with that of the sub-cooled vapor pressure p(L). Concentrations of PCDD/Fs and PBDD/Fs were both positively correlated to elemental carbon in all districts except Pudong District, suggesting elemental carbon could be a good indicator for dioxins' air pollution. It is intensively suggested that more detailed and deeper studies about PBDD/Fs should be carried out due to their relatively high atmospheric concentrations in Shanghai. 相似文献
356.
A mathematical model was developed in this paper to describe the nonylphenol (NP) accumulation in the effluent of a wastewater recycling system. The model quantitatively presented the relationships among the NP concentrations in the raw wastewater and the system effluent, the number of wastewater recycling cycles, the water recycling ratio, the system NP removal efficiency, and the NP accumulation factor. The mathematical model was then verified through experimental modeling of a wastewater recycling process, and it was indicated that the Pearson correlation coefficient between mathematical simulation and experimental modeling results was 0.652. The study results indicated that the NP accumulation factor of a wastewater recycling system would approach a constant for large number of wastewater recycling cycles given the wastewater recycling ratio and system NP removal efficiency. The results also revealed that the NP concentration in the effluent increased with the wastewater recycling ratio given the system NP removal efficiency, and the increase of NP removal efficiency would decrease the NP accumulation in the system effluent under a given wastewater recycling ratio condition. The model was then applied to compute the maximum wastewater recycling ratio, predict reclaimed water quality and direct the design and management of sewage recycling systems in China. 相似文献
357.
358.
Extracts of neem (Azadirachta indica A. Juss) are used in the developing world for many purposes including management of agricultural insect pests. The effects of different neem extracts (aqueous (NSKEaq), ethanol (NSKEeth) and hexane (NSKEhex)) on mortality, survival and weight of the brown planthopper, Nilaparvata lugens (St?l) (BPH) (Homoptera: Delphacidae) third and fourth nymphal instars were investigated. When fed rice plants treated with neem derivatives in bioassays, the survival of BPH nymphs is affected. Comparisons were made with the pure neem limonoid, azadirachtin (AZA) to ascertain its role as a compound responsible for these effects. AZA was most potent in all experiments and produced almost 100% nymphal mortality at 0.5 ppm and higher concentrations. When higher concentrations were applied, the effects appeared shortly after treatment and mortality was higher. Many insects died after remaining inactive for several days or during prolonged moulting. At lower concentrations, if moulting was achieved, disturbed growth and abnormalities were then likely to occur in the moulting process. Nymphs that were chronically exposed to neem extract showed a reduction in weight (45-60%). The results clearly indicate the simple NSKE (aqueous, ethanolic or both), containing low concentrations of AZA, can be used effectively to inhibit the growth and survival of BPH. 相似文献
359.
上海城市风暴潮灾害及其预测 总被引:10,自引:2,他引:8
风暴潮是上海地区最主要的自然灾害之一。其特点一是大的风暴潮灾害都是由于台风影响造成的;二是重灾区主要发生在沿杭州湾、长江口地区和市区;三是随首防潮设施防御能力提高而减轻,随地面下沉面加重;四是随着长江口、黄浦江潮位的不断抬高,黄浦江中上游地区潮灾加重。因而,预测可能最高潮位,因害设防,对于防灾减灾具有实践意义。 相似文献
360.
加速碳酸化技术对城市垃圾焚烧飞灰重金属稳定性影响研究 总被引:2,自引:2,他引:0
对南方某城市生活垃圾焚烧厂新鲜焚烧飞灰对CO2的吸收及其碳酸化的过程进行了研究,实验从水分添加量、CO2的分压等因素,考察了飞灰中重金属Pb的稳定化效果,并利用X射线衍射实验(XRD)、扫描电镜实验(SEM)对反应机理进行了分析.结果表明,不添加水分时,焚烧飞灰对CO2的吸收效果较差;当水分添加量大于10%时,焚烧飞灰对CO2的吸收效果较好.焚烧飞灰对纯CO2的吸收效果较好,空气中的CO2含量较低,在反应1 d后吸收效果不是十分明显.XRD实验结果表明,CO2的吸收会使焚烧飞灰中大量的Ca(OH)2与CO2反应转化为CaCO3,从而降低焚烧飞灰的碱性;部分重金属的氧化物会被碳酸化成生相应的碳酸盐.SEM实验结果表明,经过碳酸化处理后的飞灰颗粒表面生成了片状和圆柱状的晶体物质. 相似文献