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551.
Running Reelfoot Bayou (RRB) is the outlet canal of Reelfoot Lake, the largest natural lake in Tennessee. RRB is not able to contain discharge from Reelfoot Lake greater than the bankfull discharge of 28 m3/s (1000 ft3/s), which typically occurs at the beginning of the growing season (April–June). Historically, the planting of crops has been delayed until flooding subsides and cropland has drained. The objective of this study is a preliminary quantification of cropland inundation to determine its spatial distribution in the RRB floodplain. Inundated croplands in the RRB floodplain were delineated over a range of spillway discharges from 2 to 57 m3/s (70–2000 ft3/s), using one-dimensional–two-dimensional hydrodynamic modeling and multispectral satellite images (Landsat 8 and Sentinel-2). The composite maps made by combining the simulated and image-derived flood maps were overlaid on the United States Department of Agriculture CropScape layer to determine the inundation of individual summer crops during the growing season. About 25% of the inundated croplands are flooded at discharges of RRB less than 28 m3/s, implying wetland hydrology. The results of this analysis can be used to inform operational management of the Reelfoot Lake spillway.  相似文献   
552.
Conservation decisions increasingly involve multiple environmental and social objectives, which result in complex decision contexts with high potential for trade‐offs. Improving social equity is one such objective that is often considered an enabler of successful outcomes and a virtuous ideal in itself. Despite its idealized importance in conservation policy, social equity is often highly simplified or ill‐defined and is applied uncritically. What constitutes equitable outcomes and processes is highly normative and subject to ethical deliberation. Different ethical frameworks may lead to different conceptions of equity through alternative perspectives of what is good or right. This can lead to different and potentially conflicting equity objectives in practice. We promote a more transparent, nuanced, and pluralistic conceptualization of equity in conservation decision making that particularly recognizes where multidimensional equity objectives may conflict. To help identify and mitigate ethical conflicts and avoid cases of good intentions producing bad outcomes, we encourage a more analytical incorporation of equity into conservation decision making particularly during mechanistic integration of equity objectives. We recommend that in conservation planning motivations and objectives for equity be made explicit within the problem context, methods used to incorporate equity objectives be applied with respect to stated objectives, and, should objectives dictate, evaluation of equity outcomes and adaptation of strategies be employed during policy implementation.  相似文献   
553.
Settleable particulate matter (SPM) is an atmospheric pollutant harmful to human health and the environment in high concentrations. Despite this fact, no up‐to‐date information on SPM levels exists for the capital of Chile, Santiago (7 million inhabitants). To address this knowledge gap, SPM sedimentation rates, including soluble and insoluble components, were measured at three different urban sites from July to November of 2016. We compare the measurements with ambient and meteorological information, as well as urban typology settings. Our results indicate SPM deposition rates between 2.5 and 3.9 g/(m2·30 days). Only one site exceeded the national limit of 4.5 g/(m2·30 days), but we found an increasing trend in all three sites. SPM and its insoluble sedimentation rates increased during warm and dry months and presented significant correlations with meteorological parameters. The highest sedimentation rates were measured at the location with the least permeable surfaces and the lowest green spaces, while the lowest sedimentation rates were found in the sites with abundant green spaces and permeable soil. No significant differences were detected in the soluble components. Our results suggest that SPM levels in Santiago are close to the national limit and may increase with climate change and urban expansion.  相似文献   
554.
Over half of globally threatened animal species have experienced rapid geographic range loss. Identifying the parts of species’ distributions most vulnerable to local extinction would benefit conservation planning. However, previous studies give little consensus on whether ranges decline to the core or edge. We built on previous work by using empirical data to examine the position of recent local extinctions within species’ geographic ranges, address range position as a continuum, and explore the influence of environmental factors. We aggregated point‐locality data for 125 Galliform species from across the Palearctic and Indo‐Malaya into equal‐area half‐degree grid cells and used a multispecies dynamic Bayesian occupancy model to estimate rates of local extinctions. Our model provides a novel approach to identify loss of populations from within species ranges. We investigated the relationship between extinction rates and distance from range edge by examining whether patterns were consistent across biogeographic realm and different categories of land use. In the Palearctic, local extinctions occurred closer to the range edge than range core in both unconverted and human‐dominated landscapes. In Indo‐Malaya, no pattern was found for unconverted landscapes, but in human‐dominated landscapes extinctions tended to occur closer to the core than the edge. Our results suggest that local and regional factors override general spatial patterns of recent local extinction within species’ ranges and highlight the difficulty of predicting the parts of a species’ distribution most vulnerable to threat.  相似文献   
555.
Relationships between sedimentary organic matter (SOM) composition and PAH desorption behavior were determined for vegetated and non-vegetated refinery distillate waste sediments. Sediments were fractionated into size, density, and humin fractions and analyzed for their organic matter content. Bulk sediment and humin fractions differed more in organic matter composition than size/density fractions. Vegetated humin and bulk sediments contained more polar organic carbon, black carbon, and modern (plant) carbon than non-vegetated sediment fractions. Desorption kinetics of phenanthrene, pyrene, chrysene, and C3-phenanthrene/anthracenes from humin and bulk sediments were investigated using Tenax® beads and a two-compartment, first-order kinetic model. PAH desorption from distillate waste sediments appeared to be controlled by the slow desorbing fractions of sediment; rate constants were similar to literature values for kslow and kvery slow. After several decades of plant colonization and growth (Phragmites australis), vegetated sediment fractions more extensively desorbed PAHs and had faster desorption kinetics than non-vegetated sediment fractions.  相似文献   
556.
Song H  Carraway ER  Kim YH  Batchelor B  Jeon BH  Kim JG 《Chemosphere》2008,73(9):1420-1427
The effects of hydroxyapatite (HAP) on dechlorination of tetrachloroethylene (PCE) by zero-valent zinc (ZVZ) were examined in batch systems. PCE was primarily transformed to trichloroethylene by ZVZ, with 1,2-trans-dichloroethylene representing a minor product. Dechlorination of PCE was accelerated by the presence of HAP, and the pseudo-first order rate constants increased with increasing amount of HAP. Zn(II), mostly generated from oxidative dissolution of ZVZ by PCE, was effectively removed from the solution by HAP. Ion substitution, coprecipitation, and adsorption are proposed as the possible mechanisms for Zn(II) removal. These reactions appeared to occur simultaneously and the contribution of each reaction to overall removal of Zn(II) was primarily dependent on HAP loading at constant ZVZ loading. The results indicate that the use of HAP in combination with conventional zero-valent metals is promising in that it can achieve both degradation of organic contaminants and stabilization of inorganic contaminants.  相似文献   
557.
Solid-phase microextraction coupled with gas chromatography-mass spectrometry (SPME-GC-MS) was used to analyze two triazine (atrazine and simazine) and three chloroacetamide herbicides (acetochlor, alachlor, and metolachlor) in water samples from a midwest US agricultural drainage ditch for two growing seasons. The effects of salt concentration, sample volume, extraction time, and injection time on extraction efficiency using a 100-mum polydimethylsiloxane-coated fiber were investigated. By optimizing these parameters, ditch water detection limits of 0.5 microgL(-1) simazine and 0.25 microgL(-1) atrazine, acetochlor, alachlor, and metolachlor were achieved. The optimum salt concentration was found to be 83% NaCl, while sample volume (10 or 20 mL) negligibly affected analyte peak areas. The optimum extraction time was 40 min, and the optimum injection time was 15 min. Results indicated that atrazine levels in the ditch water exceeded the US maximum contaminant level for drinking water 12% of the time, and atrazine was the most frequently detected among studied analytes.  相似文献   
558.
The National Academy of Sciences (NAS) definition of resilience is used here to organize common concepts and synthesize a set of key features of resilience that can be used across diverse application domains. The features in common include critical functions (services), thresholds, cross-scale (both space and time) interactions, and memory and adaptive management. We propose a framework for linking these features to the planning, absorbing, recovering, and adapting phases identified in the NAS definition. The proposed delineation of resilience can be important in understanding and communicating resilience concepts.  相似文献   
559.
There are few studies measuring exposure to outdoor tobacco smoke (OTS). Tobacco users often gather at the boundaries of tobacco-free campuses, resulting in unintended consequences. The objective of this study was to measure exposure levels from OTS on sidewalks bordering a tobacco-free university campus. Data were collected while walking along a sidewalk adjacent to a medium traffic road between May and August 2011. Monitoring occurred during “background,” “stop,” and “walk-through” conditions at and near hot spot area to measure fine particulate matter (<2.5 μm; PM2.5) from OTS using a portable aerosol monitor. The average PM2.5 levels during stop and walk-through conditions were significantly higher than during background conditions. PM2.5 peak occurrence rate and magnitude of peak concentration were significantly different depending on smoking occurrence. The peak occurrence rate during the stop condition was 10.4 times higher than during the background condition, and 3.1 times higher than during the walk-through condition. Average peak PM2.5 concentrations during the stop condition were 48.7% higher than during the background condition. In conclusion, individuals could be exposed to high levels of PM2.5 when stopping or even passing by smokers outdoors at the perimeter of tobacco-free campuses. The design and implementation of tobacco-free campus policies need to take into account the unintended consequences of OTS exposure at the boundaries.

Implications:In this study, outdoor tobacco smoke (OTS) exposure was measured at the perimeter of tobacco-free campus. OTS exposure could be determined by peak analysis. Peak occurrence rate and peak concentration for OTS exposure were identified by using peak analysis. People could be exposed to high levels of PM2.5 when standing or even passing by smokers at the perimeter of tobacco-free campus. OTS exposure measurement in other outdoor locations with smokers is needed to support outdoor smoking regulation.  相似文献   
560.
While the age of physical environments is the central tenet of historic preservation, there is a lack of empirical evidence about how everyday people actually value, perceive, and experience age as an intrinsic part of an urban environment. In order to ameliorate this knowledge deficit, this study employs phenomenology to understand the lived experience of being in a “new” versus an “old” or “historic” urban residential environment. The new environment is the I'On new urbanist development in Mt. Pleasant, South Carolina, and the old environment is the location of the United States' first historic district in Charleston, South Carolina. These locations are approximately within five miles of each other. In both places, the physical characteristics of the built environment are remarkably similar in density, form, layout, and design, but the age is dramatically different. Through photo elicitation techniques and interviews, the results of this study reveal that residents of historic Charleston and I'On value their built environments in remarkably similar ways. Surprisingly, elements that evoke a strong sense of attachment tend to be landscape features, such as gates, fountains, trees, and gardens rather than buildings. The informants valued the “mystery” that they felt was part of the landscape and which consisted of layered elements such as fences, gates, and paths, such that these features (including buildings) had to be “discovered.” Lastly, the informants strongly valued landscapes that showed “people care” through regular maintenance. The essential difference in people's experience and valuation of the new environment (I'On) and the old environment (historic Charleston) is in the older environment's ability to instill creative fantasies in the minds of the informants based on a hypothetical past of their own creation. The informants in I'On did not share these kinds of meanings.  相似文献   
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