Asymmetric investigation to track the effect of urbanization,energy utilization,fossil fuel energy and CO2 emission on economic efficiency in China: another outlook

Environmental Science and Pollution Research - The accelerated urbanization in China was already coupled with a steadily increasing demand for energy usage. The present study major aim was to...     

Biodiesel production from vegetable oil and waste animal fats in a pilot plant

In this study, corn oil as vegetable oil, chicken fat and fleshing oil as animal fats were used to produce methyl ester in a biodiesel pilot plant. The FFA level of the corn oil was below 1% while those of animal fats were too high to produce biodiesel via base catalyst. Therefore, it was needed to perform pretreatment reaction for the animal fats. For this aim, sulfuric acid was used as catalyst and methanol was used as alcohol in the pretreatment reactions. After reducing the FFA level of the animal fats to less than 1%, the transesterification reaction was completed with alkaline catalyst. Due to low FFA content of corn oil, it was directly subjected to transesterification. Potassium hydroxide was used as catalyst and methanol was used as alcohol for transesterification reactions. The fuel properties of methyl esters produced in the biodiesel pilot plant were characterized and compared to EN 14214 and ASTM D6751 biodiesel standards. According to the results, ester yield values of animal fat methyl esters were slightly lower than that of the corn oil methyl ester (COME). The production cost of COME was higher than those of animal fat methyl esters due to being high cost biodiesel feedstock. The fuel properties of produced methyl esters were close to each other. Especially, the sulfur content and cold flow properties of the COME were lower than those of animal fat methyl esters. The measured fuel properties of all produced methyl esters met ASTM D6751 (S500) biodiesel fuel standards.     

Nitrogen mineralization in a high altitude ecosystem in the mediterranean phytogeographical region of Turkey

Interrelations exist in the terrestrial ecosystems between the plant type and characteristics of nutrient uptake. Annual net nitrogen mineralization in soils of different plant communities in the high altitude zone of Spil mountain located in the Mediterranean phytogeographical region of Turkey was investigated throughout one year by field incubation method. Seasonal fluctuations resulting from field incubation were markedly higher in autumn and spring than summer. These are mainly associated with the changes in soil moisture being at minimum in the Mediterranean summer. A significant correlation was developed between the net Nitrate (kg NO3(-)-N ha week(-1)) production and soil water content (p<0.05; r = 0.316 in soil of 0-5 cm; r = 0.312 in soil of 5-15 cm). The results showed that the annual productivity of nitrogen mineralization shows different values depending on communities. Annual net ammonium (NH4(+)-N) production in the soils of each community was negatively estimated. However annual net nitrate (NO3(-)-N) production (0-15 cm) was higher in grassland (27.8 kg ha y(-1)) and shrub (25.0 kg ha y(-1)) than forest (12.4 kg ha y(-1)) community. While annual net N(min) values were close to each other in grassland (14.5 kg ha y(-1)) and shrub (14.1 kg ha y(-1)), but negative in forest community (-3.6 kg ha y(-1)). The reasons for these differences are discussed.     

First-trimester maternal serum alpha-fetoprotein and human chorionic gonadotropin screening for chromosome defects

The aim of this study was to determine the efficacy of combined maternal serum alpha-fetoprotein (MSAFP) and maternal serum human chorionic gonadotropin (MShCG) screening in detecting chromosome defects in the first trimester of pregnancy. Sera of 492 women (previously assayed for MSAFP) were analysed for MShCG under code without knowledge of cytogenetic results. Overall, 48 of 492 patients (9·8 per cent) had either an MSAFP multiple of the median ⩽0·5 or an MShCG β/a z ratio multiple of the median ⩽ 0·25, eight of whom had a fetus with a serious chromosome defect. A third of fetuses with Down' s syndrome and 83 per cent with trisomy 18 were detected at a potential‘cost’ of providing chorionic villus sampling or amniocentesis in 8·6 percent of women screened.     

Nonparametric Ranked-set Sampling Confidence Intervals for Quantiles of a Finite Population

Ranked-set sampling from a finite population is considered in this paper. Three sampling protocols are described, and procedures for constructing nonparametric confidence intervals for a population quantile are developed. Algorithms for computing coverage probabilities for these confidence intervals are presented, and the use of interpolated confidence intervals is recommended as a means to approximately achieve coverage probabilities that cannot be achieved exactly. A simulation study based on finite populations of sizes 20, 30, 40, and 50 shows that the three sampling protocols follow a strict ordering in terms of the average lengths of the confidence intervals they produce. This study also shows that all three ranked-set sampling protocols tend to produce confidence intervals shorter than those produced by simple random sampling, with the difference being substantial for two of the protocols. The interpolated confidence intervals are shown to achieve coverage probabilities quite close to their nominal levels. Rankings done according to a highly correlated concomitant variable are shown to reduce the level of the confidence intervals only minimally. An example to illustrate the construction of confidence intervals according to this methodology is provided.     

Evaluation of PCDD/F levels in ambient air and soils and estimation of deposition rates in Kocaeli, Turkey

PCDD/F analyses were made in soil and ambient air samples taken from Kocaeli, an industrialized area of Turkey. Results showed that the levels of PCDD/F pollution are comparable to the levels observed in the various urban areas in the world. PCDD/F concentrations in surface soils ranged between 0.4 and 4.27 pg I-TEQ kg(-1) with a geometric mean of 0.76 pg I-TEQ kg(-1), while those in ambient air were between 23 and 563 f gm(-3), with geometric mean of 82.0 f gm(-3). Ambient air PCDD/F concentration in the city center was about 10 times higher than those in the rural area. Combustion activities present in the area were assessed to be the most significant source of the PCDD/F pollution based on the congener and homologue profiles and statistical analysis of the data. The deposition rate modeling of USEPA was applied and the deposition rates were determined in the range between 7.6 and 66.3 ng I-TEQ m(-2)year(-1) with a geometric mean of 15.9 ng I-TEQ m(-2)year(-1). The rates were higher than the recommended deposition rates in relation to the tolerable daily intake (TDI) range of PCDD/Fs for humans. The deposition velocities computed were also found to be high in both low and highly chlorinated PCDD/Fs, and this was attributed to the vapor phase deposition of volatile PCDD/Fs, and the scavenging effect of the precipitation on the particle-bound PCDD/Fs.     

How do climatic change,cereal crops and livestock production interact with carbon emissions? Updated evidence from China

Environmental Science and Pollution Research - Carbon dioxide emission and climatic variation have a detrimental influence on the atmosphere as well as on agriculture production. The key aim of the...     

Sampling from partially rank-ordered sets

In this paper we introduce a new sampling design. The proposed design is similar to a ranked set sampling (RSS) design with a clear difference that rankers are allowed to declare any two or more units are tied in ranks whenever the units can not be ranked with high confidence. These units are replaced in judgment subsets. The fully measured units are then selected from these partially ordered judgment subsets. Based on this sampling scheme, we develop unbiased estimators for the population mean and variance. We show that the proposed sampling procedure has some advantages over standard ranked set sampling.     

Water quality assessment and meta model development in Melen watershed – Turkey

Istanbul, being one of the highly populated metropolitan areas of the world, has been facing water scarcity since the past decade. Water transfer from Melen Watershed was considered as the most feasible option to supply water to Istanbul due to its high water potential and relatively less degraded water quality. This study consists of two parts. In the first part, water quality data covering 26 parameters from 5 monitoring stations were analyzed and assessed due to the requirements of the “Quality Required of Surface Water Intended for the Abstraction of Drinking Water” regulation. In the second part, a one-dimensional stream water quality model with simple water quality kinetics was developed. It formed a basic design for more advanced water quality models for the watershed. The reason for assessing the water quality data and developing a model was to provide information for decision making on preliminary actions to prevent any further deterioration of existing water quality. According to the water quality assessment at the water abstraction point, Melen River has relatively poor water quality with regard to NH₄⁺, BOD₅, faecal streptococcus, manganese and phenol parameters, and is unsuitable for drinking water abstraction in terms of COD, PO₄^3?, total coliform, total suspended solids, mercury and total chromium parameters. The results derived from the model were found to be consistent with the water quality assessment. It also showed that relatively high inorganic nitrogen and phosphorus concentrations along the streams are related to diffuse nutrient loads that should be managed together with municipal and industrial wastewaters.