Another outlook to sector-level energy consumption in Pakistan from dominant energy sources and correlation with economic growth

Environmental Science and Pollution Research - The present study seeks to investigate the sector-level energy consumption of oil and natural gas and to explore the linkage between economic growth,...     

Determining the tourism potential of the Altındere Valley National Park (Trabzon/Turkey) with respect to its conservation value

This study was conducted to determine the tourism potential of Alt?ndere Valley National Park with respect to its conservation and utilization. With its natural values, Alt?ndere Valley National Park is one of the internationally prominent areas of potential for the recreational and touristic facilities it offers.

A mathematical method – criterion referenced method – was applied within this study, which was done to portray the touristic potential (resulting from the touristic and recreational utilization of the national park area and recreational zone) of the national park, which was visited by an average of 200,000 local and foreign guests.

According to this method, the conservation and utilization values that appear on two opposite axes were examined in accordance with the natural resource values of the area, and conservation and utilization values for each criterion were determined. Depending on the data, the general exploitable touristic potential of the area was specified.

A survey study was conducted on groups from various disciplines and local & foreign tourists visiting the area in specifying the touristic potential of the National Park. Eleven criteria were defined concerning the area and a criterion reference was prepared for each criterion. Then, conservation and utilization values for each criterion and exploitable touristic potential were mathematically indicated. The fact that the attained values were reduced to a percentage basis provides the opportunity to compare the researched area to similar fields that use the same method. Within the scope of the method, several suggestions were made using the information obtained in the evaluation of the data for every other source value.     

Protective effect of kombucha mushroom (KM) tea on phenol-induced cytotoxicity in albino mice

The present study was carried out to evaluate the protective role of kombucha mushroom (KM) tea on cytotoxicity induced by phenol (PHE) in mice. We used weight gain and micronucleus (MN) frequency as indicators of cytotoxicity and supported these parameters with pathological findings. The animals were randomly divided into seven groups: (Group I) only tap water (Group II) 1000 microl kg(-1) b. wt KM-tea, (Group III) 35 mg kg(-1) body wt. PHE (Group IV) 35 mg kg(-1) body wt. PHE + 250 microl kg(-1) b. wt KM-tea (Group V) 35 mg kg(-1) b. wt PHE + 500 microl kg(-1) b. wt KM-tea (Group VI) 35 mg kg(-1) b. wt PHE + 750 microl kg(-1) b. wt KM-tea, (Group VII) 35 mg kg(-1) b. wt PHE + 1000 microl kg(-1) b. wt KM-tea, for 20 consecutive days by oral gavage. The results indicated that all KM-tea supplemented mice showed a lower MN frequency than erythrocytes in only PHE-treated group. There was an observable regression on account of lesions in tissues of mice supplemented with different doses of KM-tea in histopathological observations. In conclusion, the KM-tea supplementation decreases cytotoxicity induced by PHE and its protective role is dose-dependent.     

Effect of inorganic and organic solutes on zero-valent aluminum-activated hydrogen peroxide and persulfate oxidation of bisphenol A

The effect of varying inorganic (chloride, nitrate, sulfate, and phosphate) and organic (represented by humic acid) solutes on the removal of aqueous micropollutant bisphenol A (BPA; 8.8 μM; 2 mg/L) with the oxidizing agents hydrogen peroxide (HP; 0.25 mM) and persulfate (PS; 0.25 mM) activated using zero-valent aluminum (ZVA) nanoparticles (1 g/L) was investigated at a pH of 3. In the absence of the solutes, the PS/ZVA treatment system was superior to the HP/ZVA system in terms of BPA removal rates and kinetics. Further, the HP/ZVA process was not affected by nitrate (50 mg/L) addition, whereas chloride (250 mg/L) exhibited no effect on the PS/ZVA process. The negative effect of inorganic anions on BPA removal generally speaking increased with increasing charge in the following order: NO₃^? (no inhibition)?<?Cl^? (250 mg/L)?=?SO₄^2??<?PO₄^3? for HP/ZVA and Cl^? (250 mg/L; no inhibition)?<?NO₃^??<?SO₄^2??<?PO₄^3? for PS/ZVA. Upon addition of 20 mg/L humic acid representing natural organic matter, BPA removals decreased from 72 and 100% in the absence of solutes to 24 and 57% for HP/ZVA and PS/ZVA treatments, respectively. The solute mixture containing all inorganic and organic solutes together partly suppressed the inhibitory effects of phosphate and humic acid on BPA removals decreasing to 46 and 43% after HP/ZVA and PS/ZVA treatments, respectively. Dissolved organic carbon removals were obtained in the range of 30 and 47% (the HP/ZVA process), as well as 47 and 57% (the PS/ZVA process) for the experiments in the presence of 20 mg/L humic acid and solute mixture, respectively. The relative Vibrio fischeri photoluminescence inhibition decreased particularly for the PS/ZVA treatment system, which exhibited a higher treatment performance than the HP/ZVA treatment system.     

Advanced oxidation treatment of physico-chemically pre-treated olive mill industry effluent

In this study, the applicability of physico-chemical methods was investigated for the pre-treatment of the olive mill effluents prior to the discharge into the common sewerage ending with a municipal wastewater treatment plant. The samples were taken from an olive oil industry operated as three-phase process located in Turkey. Various pre-treatment methods including acid craking, polyelectrolyte and lime additions were applied. Advanced oxidation study using Fenton's process was also investigated following pre-treatment by acid cracking and cationic polyelectrolyte. Acid cracking alone gave satisfactory treatment efficiencies and polyelectrolite additions to the acid-cracked samples enhanced treatment efficiency. Since a complete treatment plant is available at the end of the sewer system, results indicated that the effluents of the investigated industry could be discharged into the municipal sewerage in the case of total chemical oxygen demand (COD_tot), suspended solid (SS) and volatile suspended solid (VSS) concentrations according to the Turkish Water Pollution Control Regulation after pre-treatment with 5 ppm anionic polyelectrolyte following acid cracking. The minimum COD_tot, SS and VSS removals were observed when raw wastewater was pre-treated with lime and the discharge standards to the municipal sewer system could not be met. Advanced oxidation with Fenton's process was applied after acid cracking and cationic polyelectrolyte treatment in order to investigate further reduction in chemical oxygen demand (COD) concentration for minimizing the influence of this industrial discharge on the existing municipal wastewater treatment plant. Results indicated that COD_tot removal increased up to 89% from 74% after Fenton's oxidation for the acid cracked samples in which cationic polyelectrolite (10 ppm) was added.     

Analysis of airborne pollen fall in Nicosia (Cyprus)

Airborne pollen distribution in the city of Nicosia (Cyprus) was measured volumetrically during two consecutive years 2007–2008 on weekly basis using Lanzoni trap (Lanzoni VPPS 2000). A total of 7,880 pollen grains/m³ belonging to 44 taxa, in 2007 were 3,593 pollen grains/m³ and in 2008 it was 4,287 pollen grains/m³, were determined. Out of these, 25 belonged to the arboreal and 19 to the non-arboreal taxa. At the end of 2 years, total pollen counts were 78.76% arboreal, 19.32% non-arboreal, and 1.92% unidentified taxa. The number of pollen in the arboreal plants followed the trend as Pinaceae (29.96%), Cupressaceae/Taxaceae (18.33%), Olea europaea L. (6.92%), and Quercus spp. (4.92%), and for non-arboreal representatives, these were Poaceae (8.46%), Chenopodiaceae/Amaranthaceae (2.61%), Plantago spp. (1.69%), and Parietaria spp. (1.51%). The distribution of pollen in the atmosphere of Nicosia followed the trend as March, April, May, and June.     

Relationship between chromium(VI) resistance and extracellular polymeric substances (EPS) concentration by some cyanobacterial isolates

BACKGROUND, AIM, AND SCOPE: Chromium(VI) resistance and its association with extracellular polymeric substance (EPS) concentration in cyanobacteria was investigated. Increased EPS concentration was associated with Cr(VI) resistance. The most resistant isolate, Chroococcus sp. H(4), secreted the most EPS (427 mg/L). MATERIALS AND METHODS: EPS concentration of the two most resistant isolates (Chroococcus sp. H(4) and Synechocystis sp. S(63)) was investigated following exposure to 15 and 35 ppm Cr(VI). The composition of EPS produced by Chroococcus sp. H(4) following exposure to 10 ppm Cr(VI) was analyzed using high-performance liquid chromatography. Control EPS was composed of glucose (99%) and galactronic acid (1%); in the presence of 10 ppm Cr(VI), EPS composition changed to glucose (9%), xylose (75%), rhamnose (14%), and galacturonic acid (2%). RESULTS AND DISCUSSION: Results indicated that (1) exposure to elevated concentrations of Cr(VI) affected the composition of EPS produced by Chroococcus sp. H(4), and (2) there was a correlation between Cr(VI) resistance and EPS concentration in some cyanobacteria.     

Order restricted randomized designs and two sample inference

This paper develops a new design that relies on subjective judgment ranking to compare subsets of experimental units. This judgment ranking is used along with restricted randomization to improve statistical inference for the contrast between two levels of a treatment. The new design assigns the judgment ranked units in a subset to different treatments. Such an assignment translates the positive dependence among units within each subset into negative dependence for the estimators of treatment means, and hence leads to a reduction in variance for the contrast. For the proposed design, a test for the difference in means of two treatment levels is developed along with an associated confidence interval. It is shown that the null distribution of the proposed test is approximated reasonably well with the Student’s t-distribution for sample sizes as small as 6. A simulation study indicates that the proposed design is advantageous compared to its competitors in the literature for both high and low quality rankings. The new design’s advantage increases with the quality of rankings.     

A chemical substitution study for a wet processing textile mill in Turkey

Wet processing textile industry has many different processing stages (dyeing, sizing, de-sizing, scouring, softening, etc.). Many chemicals currently used in the wet processing textile industry affect the amount and the type of waste produced and their influence on the aquatic life of the receiving stream. One of the critical steps in pollution prevention studies is auditing the use of chemicals and making the necessary chemical substitutions. This chemical substitution study was conducted on one of the major textile factories in Turkey with a capacity of 20,000 tons of denim fabric per year. During this study, chemical consumption level, receipts applied, environmentally problematic and alternative chemicals were examined. Integrated Pollution Prevention and Control (IPPC) Reference Document on Best Available Techniques (BAT) for the Textiles Industry was accepted as main reference document and also related case studies were examined. According to the study, over 70% reduction in sulphide, which is very toxic to aquatic life, was achieved by replacing sulphur dyestuff with low sulphide content. By replacing an alternative complexing agent, the mill not only prevented the 3100 kg/month COD load to the wastewater treatment plant (WWTP), but also obtained more biodegradable wastewater generated during production. On the other hand, some of the chemical substitution options were on progress or dropped.