Sediment phosphorus extractants for phosphorus-31 nuclear magnetic resonance analysis: a quantitative evaluation

The influence of pre-extractant, extractant, and post-extractant on total extracted amounts of P and organic P compound groups measured with 31P nuclear magnetic resonance (31P-NMR) in lacustrine sediment was examined. The main extractants investigated were sodium hydroxide (NaOH) and sodium hydroxide ethylenediaminetetraacetic acid (NaOH-EDTA) with bicarbonate buffered dithionite (BD) or EDTA as pre-extractants. Post extractions were conducted using either NaOH or NaOH-EDTA, depending on the main extractant. Results showed that the most efficient combination of extractants for total P yield was NaOH with EDTA as pre-extractant, yielding almost 50% more than the second best procedure. The P compound groups varying the most between the different extraction procedures were polyphosphates and pyrophosphates. NaOH with BD as pre-extractant was the most efficient combination for these compound groups.     

A transition in the Dutch wastewater system? The struggle between discourses and with lock-ins

ABSTRACT

Recently, calls have increased for a paradigm shift or transition towards resource recovery and a circular economy in the Dutch wastewater system. However, we have observed diverging interpretations on the nature of the transition. This reflects the political environment of sustainability transitions: political struggle emerges over the definition of problems, futures and strategies to be used. In order to help clarify the emerging debate and identify political choices, we conducted a discourse analysis. We identified three discourses that reveal some of the political choices to be made. One discourse is becoming dominant and focusses on optimising the large-scale infrastructure, market development and legislative changes. The discourse draws on the existing infrastructure and current political-economic institutions, which gives it an advantage in becoming dominant. Our findings also suggest that this discourse shapes a transition pathway that is characterised by lock-in effects and, at most, incremental changes instead of a fundamental shift in the established Dutch wastewater system.     

Evidence of Al-Cr interactions affecting Cr-leaching from waste incineration ashes

Leaching tests on flue gas ashes from waste incineration showed low leaching of Cr from ashes that under moist anaerobic conditions also produced hydrogen gas. In some cases, also the redox levels (aerobic/anaerobic conditions) during the leaching test affected Cr leaching. Aerobic ashes tested in an open batch leaching test leached Cr up to 2-3 orders of magnitude more than the ashes kept moist under anaerobic conditions and tested in a closed leaching test. Model experiments showed that metallic Al could reduce Cr and at the same time produce H(2). The hydrogen gas per se could not reduce Cr. Laboratory experiments with ashes provided evidence that metallic Al, present naturally in the ashes or amended, could reduce Cr under moist anaerobic, but not under aerobic storage. Significant Cr reduction was linked to, but not caused by hydrogen formation. The reduced Cr seemed to be partially reoxidizable upon aeration or drying. The observations presented provide a basis for understanding the complexity of Cr leaching from waste incineration ashes, as for example, why some chemical stabilization methods increase Cr leaching, and point out the need for standardizing leaching test conditions with respect to Cr.     

Flanders’ urbanity — an outline

This article deals with Flanders’ urbanity. At the moment Flanders, a part of Belgium, is responsible for its own town and country planning. Nevertheless, today's picture of urbanity is, for the greatest part, the result of Belgian policy. The results are nothing to be proud of. In fact Flanders has no urbanity anymore, nor a real rurality. Everywhere in the countryside there are houses and other constructions; on the other hand and consequently the centres of cities and villages are in decay. The following text tries to draw, very briefly, the problems and the development of the problems in urban and rural Flanders. The roots have to be searched in the 19th century, especially in the constitution of Belgium, which is one of the most liberal on earth. The first part of the article is dealing with the history of urbanisation, whilst the second part deals with some recent evolutions in housing and housing policy, in employment and employment policy, in transport and transport policy. Finally, the third part is concerned with the town and country planning which has to structure the developments in spatial use for housing, industrial building and so on, but which has failed.     

The history of seabird colonies and the North Water ecosystem: Contributions from palaeoecological and archaeological evidence

The North Water (NOW) polynya is one of the most productive marine areas of the Arctic and an important breeding area for millions of seabirds. There is, however, little information on the dynamics of the polynya or the bird populations over the long term. Here, we used sediment archives from a lake and peat deposits along the Greenland coast of the NOW polynya to track long-term patterns in the dynamics of the seabird populations. Radiocarbon dates show that the thick-billed murre (Uria lomvia) and the common eider (Somateria mollissima) have been present for at least 5500 cal. years. The first recorded arrival of the little auk (Alle alle) was around 4400 cal. years bp at Annikitsoq, with arrival at Qeqertaq (Salve Ø) colony dated to 3600 cal. years bp. Concentrations of cadmium and phosphorus (both abundant in little auk guano) in the lake and peat cores suggest that there was a period of large variation in bird numbers between 2500 and 1500 cal. years bp. The little auk arrival times show a strong accord with past periods of colder climate and with some aspects of human settlement in the area.     

Metals pollution and human bioaccessibility of topsoils in Grugliasco (Italy)

Polluted soils can present a significant health risk especially in an urban environment. Most current legislation and health risk frameworks are based on pseudototal metal content. However, only a fraction of these concentrations is available for plant and human uptake. The aim of this work was to study the diffuse metal contamination in the soils of a municipality in Northern Italy in terms of: (i) metal availability, and (ii) metal accessibility to the human body and its relationship to soil properties, considering lead, copper, zinc, nickel, and chromium. Soil metal content was measured simulating availability conditions. Human bioaccessibility was derived from a modified physiologically-based extraction test. The human bioaccessible content was then estimated taking into account the relationships between pseudototal content and selected soil parameters. For the case study, the prediction of human bioaccessibility based on pseudototal content, organic matter and soil texture produced statistically significant models, with r² = 0.60 for Cu, r² = 0.53 for Pb and r² = 0.42 for Zn.     

Industrial Zoning as a Means of Controlling Area Source Air Pollution

The simple ATDL urban dispersion model Is based on the formula Xo(g/m³) = CO(g/m²s)/U(m/s). The diurnal variation of the stability factor C, which can be thought of as the width of the urban area divided by the vertical dispersion of the pollution cloud, has not before been satisfactorily estimated. Using observed diurnal variations of CO concentrations and traffic frequencies reported by DeMarrais of the EPA for many stations in the states of Maryland, New Jersey, and Colorado, and using wind data from these states, hourly values of C - XoU/Q were calculated. The ratio of C to the daily average C is found to equal about 2.5 at 4 a.m., drops to about 0.5 by 8 a.m., and remains at 0.5 until about 6 p.m.., when it starts to climb slowly again. Application of this new stability factor to independent CO data from Los Angeles yields correlations between measured and predicted concentrations of about 0.7.     

Algal tests with soil suspensions and elutriates: a comparative evaluation for PAH-contaminated soils

An algal growth inhibition test procedure with soil suspensions is proposed and evaluated for PAH-contaminated soil. The growth rate reduction of the standard freshwater green alga Pseudokirchneriella subcapitata (formerly known as Selenastrum capricornutum) was used as the toxicity endpoint, and was quantified by measuring the fluorescence of solvent-extracted algal pigments. No growth rate reduction was detected for soil contents up to 20 g/l testing five non-contaminated Danish soils. Comparative testing with PAH-contaminated soil elutriates and soil suspensions showed that the suspensions had toxicity endpoints 2.5-3000 times lower than tests with the corresponding elutriates. Algal growth inhibition tests with soil suspensions are recommended for screening purposes as a supplement to elutriate testing. Experiments with a phenanthrene-spiked soil, showed that the sorbed compound did not contribute to the toxicity. However, the soil did act as a reservoir for phenanthrene, allowing desorption to occur continuously during the algal test which maintained higher concentrations of phenanthrene in the dissolved phase. Phenanthrene-spiked soil incubated for 90 days before algal testing, resulted in a reduction of the toxicity to P. subcapitata by a factor of 76 (from EC10 = 0.3 to 23.6 g soil/l). However, during this 90-day period the total concentration of phenanthrene in the soil decreased by 38% (from 322 to 199 mg/kg) indicating that phenanthrene in the aged soil had become less bioavailable.