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681.
Liu Z He Y Li F Liu Y 《Environmental science and pollution research international》2006,13(5):328-332
Background, Aim and Scope
The polynitramines, hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX),
are important military explosives and regulated toxic hazardous compounds. Production, testing and use of the compounds has
resulted in numerous acres of contaminated soils and groundwater near many munitions facilities. Economical and efficient
methods for treatment of wastewater and cleanup of soils or groundwater containing RDX and HMX are needed. This study focuses
on the photocatalytic treatment of RDX wastewater with nano-sized titanium dioxide (nano-TiO2) under simulated sunlight, whose
intensity and wavelength are similar to that of the real sunlight in Xi'an at noon. The objective is to determine the potential
for RDX destruction with nano-TiO2 in aqueous solution.
Materials and Methods:
An activated carbon fiber (ACF) cloth-loaded with nano-TiO2 was put into the RDX containing solution, and the concentration
of RDX was measured (by HPLC–UV) at regular time intervals under simulated sunlight.
Results:
The RDX degradation percentage of the photocatalytic process is higher than that of Fenton oxidation before 80 min, equivalent
after 80 min, and it reaches 95% or above after 120 min. The nano-TiO2 catalyst can be used repeatedly.
Discussion:
The photocatalytic degradation kinetics of RDX under simulated sunlight can be described by a first-order reaction kinetics
equation. The possible degradation mechanism of RDX was presented and the degradation performance was compared with that of
biological method.
Conclusions:
It was demonstrated that the degradation of RDX wastewater is very effective with nano-TiO2 as the photocatalytic catalyst
under simulated sunlight. The efficiency of the nano-TiO2 catalyst for RDX degradation under simulated sunlight is nearly
identical to that of Fenton oxidation.
Recommendations and Perspectives:
To date, a number of catalysts show poor absorption and utilization of sunlight, and still need ultraviolet light irradiation
during wastewater degradation. The nano-TiO2 used in the described experiments features very good degradation of RDX under
simulated sunlight, and the manufacturing costs are rather low (around 10 Euro/m2). Moreover, the degradation efficiency is
higher compared to that of the biological method.
This method exhibits great potential for practical applications owing to its easiness and low cost. If it can be applied extensively,
the efficiency of wastewater treatment will be enhanced greatly. 相似文献
682.
- DOI: http://dx.doi.org/10.1065/espr2006.02.294
Background, Aim and Scope. To better address the requirements of the changing multilateral order, the United Nations Industrial
Development Organization (UNIDO) Cleaner Production Programme, in 2004, developed the new Sustainable Industrial Resource
Management (SIRM) approach. This approach is in accordance with the principles decided at the United Nations Conference on
Environment and Development (UNCED) in Rio de Janeiro, Brazil in 1992. Unlike the traditional approaches to environmental
management, the SIRM concept captures the idea of achieving sustainable industrial development through the implementation
of circular material and energy flows in the entire production chain and reduction of the amount of material and energy used
with greater efficiency solutions. The SIRM approach seeks to develop new models to encourage a shift from selling products
to supplying services, modifying, in this manner, the supplier/user relationship and resulting in a win-win situation for
the economy and the environment. Chemical Leasing represents such a new service-oriented business model and is currently being
promoted by UNIDO′s Cleaner Production Programme.
Main Features. One of the potential approaches to address the problems related to ineffective use and over-consumption of
chemicals is the development and implementation of Chemical Leasing business models. These provide concrete solutions to the
effective management of chemicals and on the ways negative releases to the environment can be reduced. The Chemical Leasing
approach is a strategy that addresses the obligations of the changing international chemicals policy by focusing on a more
service-oriented strategy. Mexico is one of the countries that were selected for the implementation of UNIDO's demonstration
project to promote Chemical Leasing models in the country. The target sector of this project is the chemical industry, which
is expected to shift their traditional business concept towards a more service and value-added approach. This is being achieved
through the development of company specific business models that implement the above-indicated Chemical Leasing concept with
the support from the Mexican National Cleaner Production Centre (NCPC).
Results and Conclusions. The implementation of Chemical Leasing in Mexico has proven to be an efficient instrument in enhancing
sustainable chemical management and significantly reducing emissions in Mexico. Several companies from the chemical industrial
sector implement or agreed to implement chemical leasing business models. Based on the positive findings of the project,
several Mexican companies started to negotiate contents of possible Chemical Leasing contracts with suitable business partners.
The project further aimed at disseminating information on Chemical Leasing. It successfully attracted globally operating companies
in the chemicals sector to explore possibilities to implement Chemical Leasing business models in Mexico. At the international
level, the results of the UNIDO project were presented on 20TH September 2005 during a side event of the Strategic Approach
to International Chemicals Management (SAICM) Preparation Conference in Vienna.
Recommendations and Outlook. To facilitate the promotion and application of Chemical Leasing project at international level,
UNIDO is currently developing a number of tools to standardize Chemical Leasing projects. These include, among others, Chemical
leasing contract models; Chemical Leasing data base to find partners for chemical leasing; and guidelines to implement Chemical
Leasing projects and work programmes. 相似文献
683.
Angioni A Sarais G Dedola F Caboni P 《Journal of environmental science and health. Part. B》2006,41(6):833-841
Residues of the pyrimidine fungicide pyrimethanil [N-(4,6-dimethylpyrimidin-2yl)aniline] were determined in table grapes "Italia" by gas chromatography nitrogen-phosphorus detector (GC-NPD). Pesticides were extracted from grapes with ethyl acetate and hexane solution (1:1 v/v), and were analyzed without any further clean up. Pyrimethanil was confirmed by high-performance liquid chromatography (HPLC) fitted with a diode array detector (DAD) and electrospray ionization mass spectrometry (ESI-MS) in the select ion-monitoring mode (SIM). The residue of pyrimethanil was under the legal limit immediately after treatment, and showed a half-life time, calculated as a reaction of pseudo first order, of 12 days, with a regression coefficient of 0.9954. Recoveries from fortified grapes ranged between 90 and 113% with a maximum coefficient of variation (CV) of 11%. The calculated limits of detection and quantitation for pyrimethanil were 0.005 and 0.01 mg/kg, respectively. 相似文献
684.
Gallardo-Lara F Azcón M Polo A 《Journal of environmental science and health. Part. B》2006,41(7):1187-1201
Little is known about the effects of applying composted urban wastes on the phytoavailability and distribution of iron (Fe) and manganese (Mn) among chemical fractions in soil. In order to study this concern several experiments in pots containing calcareous soil were carried out. The received treatments by adding separately two rates (20 and 80 Mg ha-1) of municipal solid waste (MSW) compost and/or municipal solid waste and sewage sludge (MSW-SS) co-compost. The cropping sequence was a lettuce crop followed by a barley crop. It was observed that treatments amended with composted urban wastes tended to promote slight increases in lettuce yield compared to the control. The highest Fe levels in lettuce were found when higher rates of MSW-SS co-compost were applied; these values were significant compared to those obtained in the other treatments. In all cases, the application of organic materials increased the concentration and uptake of Mn in lettuce compared to the control; however, these increases were significant only when higher rates of MSW compost were applied. The organic amendments had beneficial delayed effects on barley yields, showing, in most cases, significant increases compared to the control. In this context, treatments with MSW compost were found to be more effective than the equivalent treatments amended with MSW-SS co-compost. Compared to the control, composted urban wastes increased Fe concentration in straw and rachis, and decreased Fe concentration in barley grain. Similarly, a decreased concentration of Mn in the dry matter of barley crop grown in soils treated with composted urban wastes was observed. 相似文献
685.
Qureshi A Lo KV Mavinic DS Liao PH Koch F Kelly H 《Journal of environmental science and health. Part. B》2006,41(7):1221-1235
A combined approach of biological treatment, solids digestion and nutrient recovery was tested on dairy manure. A sequencing batch reactor (SBR) was operated in three modes, in order to optimize nutrient (nitrogen and phosphorus) removals. The highest average removal efficiencies of 91% for NH4-N, 59% for PO4-P and 80% for total chemical oxygen demand (COD) were achieved. Staining experiments suggested the coexistence of glycogen and phosphorus accumulating organisms. Anaerobic digestion of wasted bio-solids was able to produce a PO4-P concentration of 70 mgL-1 in the supernatant. A pilot-scale experiment, designed to recover phosphorus in the supernatant as struvite (magnesium ammonium phosphate), was able to remove 82% of soluble PO4-P. 相似文献
686.
Environmental contamination of heavy metals from zinc smelting areas in Hezhang County, western Guizhou, China 总被引:14,自引:0,他引:14
Total heavy metal (Cd, Cr, Cu, Pb and Zn) concentrations were evaluated in smelting waste, soil, crop and moss samples collected from the Hezhang artisanal zinc smelting areas, Guizhou, China. Soil samples from the cornfield near the smelting sites contained extremely high Cd (5.8-74 mg kg(-1)), Pb (60-14,000 mg kg(-1)) and Zn (260-16,000 mg kg(-1)) concentrations. Elevated heavy metal concentrations were also found in corn plants and total Pb (0.80-1.5 mg kg(-1)) and Cd (0.05-0.76 mg kg(-1)) concentrations in corn grain have totally or partially exceeded the national guidance limits for foodstuff. Thus, the soil-to-crop transfer of heavy metals might pose a potential health risk to the local residents. Similar to the high heavy metal levels in soil and corn, Cd, Cr, Cu, Pb and Zn concentrations in moss samples collected from the smelting sites ranged from 10 to 110, 10 to 55, 26 to 51, 400 to 1200 and 330 to 1100 mg kg(-1), respectively, exhibiting a local spatial pattern of metals deposition from the atmosphere. Based on examination of Zn/Cd and Pb/Cd ratios of the analyzed samples, we have distinguished between the flue gas dust derived and smelting waste derived metals in different environmental compartments. 相似文献
687.
(137)Cs and (90)Sr background levels in soil and plant around Tianwan Nuclear Power Plant (NPP) are reported. Eighty-four soil samples and 44 plant samples were collected from March 2000 to April 2002. The samples were analyzed by gamma spectrometry and radiochemical separation procedure to quantify (137)Cs and (90)Sr radioactivities. The concentrations (Bqkg(-1) dry weight) have been observed in the range of 0.6-1.6 for (90)Sr and 1.4-6.9 for (137)Cs in soils, their average values are 1.0+/-0.3 and 4.6+/-1.6, respectively, which are relatively lower than the reported values in neighboring countries. The mean concentrations (in Bqkg(-1) fresh weight except for tea and grass which is expressed in Bqkg(-1) dry weight) of (137)Cs and (90)Sr are 0.1+/-0.03 and 7.7+/-4.1 in pine needle, 0.27+/-0.05 and 3.0+/-1.1 in tea, 0.65+/-0.19 and 2.1+/-0.3 in grass, 0.033+/-0.021 and 0.084+/-0.045 in wheat, 0.019+/-0.01 and 0.23+/-0.06 in China cabbage, and 0.009+/-0.007 and 0.024+/-0.084 in rice, respectively. The pine needle and tea can be regarded as indicator species for (90)Sr and (137)Cs. The soil-to-plant transfer factor (TF) values of (90)Sr and (137)Cs are, respectively, 0.022 and 0.031 for rice, 0.066 and 3.83 for China cabbage, 0.0088 and 0.089 for wheat, and 0.037 and 0.56 for grass. 相似文献
688.
Experimental assessment of bio-reduction of di-2-thylhexyl phthalate (DEHP) under aerobic thermophilic conditions 总被引:3,自引:0,他引:3
The reduction of organic contaminants in sewage sludge is of great importance for a further sludge disposal or agricultural utilization. Laboratory scale batch experiments were performed to assess the potential use of the aerobic thermophilic treatment technique to reduce the concentration of difficult to degrade organic chemicals. Di-2-ethylhexyl phthalate (DEHP) was chosen as a model representative of these chemicals. The effect of the sludge temperature and aeration rate on the reduction of DEHP concentration as well as on the reduction of the organic dry solid (oDS) was investigated. With a specific air flow rate of 16 m3/m3.h and a thermophilic temperature of 63 degrees C it was possible to achieve up to 70% reduction of the DEHP concentration and 61% of oDS within 96 hours. The maximum degradation of the oDS matter occurred within the first 24 hours of operation whereby only little oDS was degraded afterward. During the experiments the reactor content was routinely monitored for pH, COD, along with the ammonia nitrogen and orthophosphate concentrations. 相似文献
689.
Malins C Doyle A MacCraith BD Kvasnik F Landl M Simon P Kalvoda L Lukas R Pufler K Babusík I 《Journal of environmental monitoring : JEM》1999,1(5):417-422
The realisation of an opto-chemical ammonia sensor suitable for personal monitoring tasks is described, comprising a cyanine dye immobilised in a microporous glass thin film. The fabrication of sensor platforms incorporating embossed grating couplers provides a compact optical design with effective waveguiding characteristics, resulting in reversible ammonia sensitivity in the 5-100 ppm range in under 2 min. Cross-sensitivity of sensor response with water and other potential interferents is considered. 相似文献
690.
Promoting the use of environmental data collected by concerned citizens through information and communication technologies 总被引:3,自引:0,他引:3
Public participation within environmental monitoring may contribute to increasing the knowledge on the state of the environment at the same time it promotes citizens' involvement in environmental protection. However, the use of voluntary collected data is limited due to a lack of confidence in data collection procedures. Additionally, data quality is often unknown and the data are usually dispersed and non-structured. Information and communication technologies (ICT) may promote the use of voluntary collected data through the development of a collaborative system that incorporates tools and methodologies to facilitate data collection, access and validation. Furthermore, the use of ICT may promote public involvement within environmental monitoring, since it facilitates communication among all the stakeholders. This paper analyses the role of ICT in developing a system for environmental collaborative monitoring intending to promote the use of volunteer collected data. It starts by analysing the role of volunteers within environmental monitoring and continues analysing the potential of ICT to take advantage of the benefits of using data collected by citizens. A collaborative system that allows the public to express its knowledge on the state of the environment is described. Special emphasis is given to tools that explore non-traditional types of environmental data such as images, sounds and videos in association with spatial information. To illustrate the above mentioned concepts, a case study for beach quality monitoring developed within the Senses@Watch project, is described. 相似文献