Plutonium isotopes in the lower reaches of the River Rhône over the period 1945-2000: fluxes towards the Mediterranean Sea and sedimentary inventories

Plutonium isotopes in the Rh?ne River originate from both the weathering of the catchment basin contaminated by global atmospheric fallout, and the liquid effluents released from the Marcoule reprocessing plant since 1961. Due to a new treatment process applied to the liquid effluents, a decrease of two orders of magnitude in the industrial plutonium discharged into the River Rh?ne has been registered from 1991. Today, 238Pu industrial inputs to the River Rh?ne are still about 10 times higher than those derived from global fallout, while 239+240Pu inputs from industrial and global fallout sources are of similar importance, i.e. 1 GBq y(-1). Our results indicate that the river sedimentary compartment act either as a sink or a delayed-source term of plutonium for the freshwaters depending on the hydraulic regime and flood events. This compartment may then represent an important industrial delayed-source term for the River Rh?ne freshwaters in the coming years as the Marcoule reprocessing plant is being dismantled. These results were obtained from samples collected from the lower course of the River Rh?ne over the 1987-1998 period and analysed for 238Pu and 239+240Pu activities. Both river sedimentary inventories of plutonium isotopes and effective outputs from the River Rh?ne towards the Gulf of Lions have been estimated for each year over the 1945-2000 period. Regarding 239+240Pu, the sedimentary inventory accumulated since 1945 is estimated to be 172+/-35 GBq. If mobile, this amount represents a significant delayed-source term of plutonium on the scale of the Rh?ne watershed.     

210Pb geochronology and trace metal fluxes (Cd, Cu and Pb) in the Gulf of Tehuantepec, South Pacific of Mexico

Distributions of Al, Cd, Cu, Fe, Li, Mn and Pb were analyzed in a sediment core collected in the Gulf of Tehuantepec, an important fisheries region located in the South Pacific of Mexico, where data on metal accumulation and accretion rates were previously almost nonexistent. Depth profiles of metal concentrations were converted to time-based profiles by using a 210Pb-derived vertical accretion rate, estimated to be 0.05 cm year(-1) on the average. Sediments were dated up to 8 cm depth, corresponding to a layer of ca. 140 years old. The historical changes of metal accumulation along the sediment core have shown a moderate enrichment of Cd, Cu and Pb concentrations at present, of about threefold the corresponding background concentrations. Chronological trace metal records showed that metal fluxes have increased over the last 20 years, reaching the maximum values at present of 2.5, 22.5 and 45.8 (microg cm(-2) year(-1)) for Cd, Pb and Cu, respectively. These increments in metal fluxes are likely influenced by the development of anthropogenic land-based activities since over this period of time oil production activities in the region have had a significant development.     

"We all knew that a cyclone was coming": disaster preparedness and the cyclone of 1999 in Orissa, India

Imagine that a cyclone is coming, but that those living in the affected areas do nothing or too little to protect themselves. This is precisely what happened in the coastal state of Orissa, India. Individuals and communities living in regions where natural hazards are a part of daily life develop strategies to cope with and adapt to the impacts of extreme events. In October 1999, a cyclone killed 10,000 people according to government statistics, however, the unofficial death toll is much higher. This article examines why such a large loss of life occurred and looks at measures taken since then to initiate comprehensive disaster-preparedness programmes and to construct more cyclone shelters. The role of both governmental organisations and NGOs in this is critically analysed. The good news is that, based on an assessment of disaster preparedness during a small cyclone in November 2002, it can be seen that at community-level awareness was high and that many of the lessons learnt in 1999 were put into practice. Less positive, however, is the finding that at the state level collaboration continues to be problematic.     

Determination of chlorimuron and metsulfuron residues in two soils of Argentina using a rapid seed-bioassay

The presence of chlorimuron ethyl and metsulfuron methyl in two soils was determined by a modified petri dish bioassay. Pregerminated seeds of maize and sunflower were placed in petri dishes containing 85 to 100 g of treated soil. Radicle root lengths were measured after 24 h. Chlorimuron had no effect on maize on the Balcarce soil, however 0.007 microg g(-1) decreased sunflower root length. Chlorimuron decreased maize and sunflower root length regardless application dose on the San Cayetano soil. Metsulfuron decreased maize root length at 0.04 microg g(-1) and sunflower at 0.021 microg g(-1) on the Balcarce soil. On the San Cayetano soil metsulfuron at 0.001 microg g(-1) decreased maize and sunflower root length. The phytotoxicity of chlorimuron and metsulfuron changed according to soil type and dose. Maize and sunflower were 1.3-1.5 and 1.3-1.8 times respectively more sensitive to chlorimuron on the San Cayetano soil than on the Balcarce soil. In the case of metsulfuron, maize was similarly sensitive on both soils but sunflower was 1.7-2.0 times more sensitive on the San Cayetano soil than on the Balcarce soil. Phytotoxicity increased as organic matter (OM) content decreased and/or when the soil pH and concentration increased.     

Environmental chemical cues associated with prey and subsequent prey preference in the wolf spider Hogna carolinensis Hentz (Araneae,Lycosidae)

The purpose of this study was to determine if environmental chemical cues associated with prey can affect subsequent prey choice in wolf spiderlings (Hogna carolinensis). After emergence from the egg sac, three groups of 10 spiderlings were each fed for one-week on one of three naturally-occurring prey species: group 1 fed on nymphs of the field cricket Gryllus pennsylvanicus; group 2 (house cricket, Acheta domesticus); group 3 (mole cricket, Gryllotalpa hexadactyla). They were then tested for subsequent prey preference in choice tests conducted in a plastic arena. Each spiderlings was presented simultaneously with one individual of each prey species in a randomized design. Spiderlings exhibited a significant first preference for the original diet. Thus, experience with certain foods (environmental chemical cues) encountered by newly hatched spiderlings can affect subsequent prey preference in this species.     

Measuring acid volatile sulphide in floodplain lake sediments: effect of reaction time, sample size and aeration

For the routine measurement of acid volatile sulphide (AVS) in floodplain lake sediments, an earlier published diffusion method was adapted and optimised. We evaluated the effect of reaction time, sample weight and passive sample aeration on AVS recovery, and determined the method's reproducibility. The optimal reaction time was 4 h. Losses of AVS due to sample aeration did not occur within 15 min of sample-air contact. Relative standard deviation was <2.5% for known sulphide solutions, was between 10% and 15% for AVS concentrations in sediments and <12% for SEM concentrations in sediments, generally. Sediment samples with known SEM and AVS content were used to compare results of the developed method with the purge-and-trap method. There is a good agreement with the purge-and-trap method for SEM concentrations. AVS concentrations measured with the diffusion method are higher than with the purge-and-trap method. We conclude that the adapted diffusion method is well suited for the routine measurement of AVS concentrations in floodplain sediments.     

Determining the agricultural ammonia immission using bark bio-monitoring: comparison with passive sampler measurements

Bark samples of spruce, pine and oak trees were collected at two sites in southern Bavaria which are characterized by high agricultural ammonia emissions. The samples were taken using a recently developed bark sampling device which removes a defined layer of the bark. The bark was then analysed for ammonium concentration in order to reflect the environmental ammonia immission. The measured bark concentrations decreased with rising distance between the sample trees and the ammonia source. This applied (i) to measurements inside a closed forest stand ranging from forest edge with high immission to forest interior with much lower immission, and (ii) to the open field where single-standing trees were sampled. Comparing the ammonium concentrations among the three different tree species revealed significant correlations. Thus, it could be shown that old spruce trees are as usable for bark bio-monitoring as the traditionally used pine and oak trees. The ammonium concentrations of the bark were significantly correlated to measurements taken by ammonia passive samplers at the same locations. These results indicate that bark samples may be used for a standardised monitoring of airborne ammonia load. A major advantage of the technique is the determination of the long-term accumulative ammonia load using a single measurement.     

Earthquake-related chemical and radioactivity changes of thermal water in Kuzuluk-Adapazan,Turkey

The movements of the North Anatolian Fault Zone (NAFZ) caused two devastating earthquakes within an 87-day interval, epicentered on G?lcük-Izmit (17 August, 1999) and Düzce-Bolu (12 November, 1999). The Kuzuluk geothermal area (KGA) is located in the middle of the epicenters and the distance between the geothermal area and the fault zone is less than 5 km. Hot water samples were collected from two thermal boreholes that supply hot water to the Kuzuluk thermal complex. The water samples taken prior to and after earthquakes were analysed by Neutron Activation and Atomic Absorption Spectroscopy. Particularly, increase in total a and total beta activities, in the content of Pb, Cr, Ni, Cu and decrease in the content of Fe, Zn, Cd, Mn, and Co are significant. The highest values are 75, 35, 12 and 65 ppb for Pb, Cr, Ni and Cu, respectively. The lowest values are 45, 55, 15, 135 and 6 ppb for Fe, Zn, Cd, Mn and Co, respectively.     

Arsenic adsorption from aqueous solutions by activated red mud

Heat treatment and acid treatment methods have been tested on red mud to increase its arsenic adsorption capability. The results indicate that the adsorptive capacity of red mud can be increased by acid treatment. This treatment causes sodalite compounds to leach out. As(III) and As(V) adsorption characteristics of activated red mud have similar tendencies with raw red mud. Batch adsorption studies have shown that activated red mud in dosages ranging from 20 to 100 g l(-1) can be used effectively to remove arsenic from aqueous solutions. The process is pH dependent, the optimum range being 5.8-7.5 for As(III) and 1.8-3.5 for As(V). The maximum removals are 96.52% for As(V) and 87.54% for As(III) for solutions with a final pH of 7.25 and 3.50, respectively, for the initial arsenic concentration of 133.5 micromol l(-1) (10 mg l(-1)), activated red mud dosage of 20 g l(-1), contact time of 60 min and temperature of 25 degrees C. The adsorption data obtained follow a first-order rate expression and fit the Langmuir isotherm well. Isotherms have been used to obtain the thermodynamic parameters. It was found that the adsorption of As(III) was exothermic, whereas As(V) adsorption was endothermic.     

Estimating runoff phosphorus losses from calcareous soils in the Minnesota River basin

Bioavailable phosphorus (BAP) in stormwater runoff is a key issue for control of eutrophication in agriculturally impacted watersheds. Laboratory experiments were conducted in soil runoff boxes to determine BAP content in simulated storm runoff in 10 (mostly) calcareous soils from the Minnesota River basin in southern Minnesota. The soluble reactive phosphorus (SRP) portion of the runoff BAP was significantly correlated with soil Mehlich-III P, Olsen P, and water-extractable P (all r2 > 0.90 and p < 0.001). A linear relationship (r2 = 0.88, p < 0.001) also was obtained between SRP in runoff and the phosphorus saturation index based on sorptivity (PSIs) calculated with sorptivity as a measure of the inherent soil P sorption capacity. Runoff levels of BAP estimated with iron oxide-impregnated paper were predicted well by various soil test P methods and the PSI, of the soils, but correlation coefficients between these variables and runoff BAP were generally lower than those for runoff SRP. Using these relationships and critical BAP levels for stream eutrophication, we found corresponding critical levels of soil Mehlich-III P and Olsen P (which should not be exceeded) to be 65 to 85 and 40 to 55 mg kg(-1), respectively.