Dynamics of soil inorganic nitrogen and their responses to nitrogen additions in three subtropical forests, south China

Three forests with different historical land-use, forest age, and species assemblages in subtropical China were selected to evaluate current soil N status and investigate the responses of soil inorganic N dynamics to monthly ammonium nitrate additions. Results showed that the mature monsoon evergreen broadleaved forest that has been protected for more than 400 years exhibited an advanced soil N status than the pine （Pinus massoniana） and pine-broadleaf mixed forests, both originated from the 1930＇s clear-cut and pine plantation. Mature forests had greater extractable inorganic N pool, lower N retention capacity, higher inorganic N leaching, and higher soil C/N ratios. Mineral soil extractable NH4^＋-N and NO3-N concentrations were significantly increased by experimental N additions on several sampling dates, but repeated ANOVA showed that the effect was not significant over the whole year except NH4^＋-N in the mature forest. In contrast, inorganic N （both NH4^＋-N and NO3^--N） in soil 20-cm below the surface was significantly elevated by the N additions. From 42% to 74% of N added was retained by the upper 20 cm soils in the pine and mixed forests, while 0%-70% was retained in the mature forest. Our results suggest that land-use history, forest age and species composition were likely to be some of the important factors that determine differing forest N retention responses to elevated N deposition in the study region.     

蚯蚓活动对重金属在土柱中淋溶行为的影响

采用土柱淋溶方法,以溴离子为示踪离子,研究了蚯蚓活动形成的土壤大孔隙对铜和锌离子在土柱中迁移行为的影响.运用平衡和非平衡对流-弥散模型对溴离子和铜、锌离子在不同土柱中的穿透曲线进行拟合.结果表明,蚯蚓活动形成的蚯蚓孔能够产生明显的优势流现象,这种优势流极大地加快了重金属离子在土柱中垂直向下迁移的速度.非平衡对流-弥散模型能很好地预测溴离子和铜、锌离子在蚯蚓孔土柱中的流出趋势,而平衡对流-弥散模型适合于预测溶质在对照（匀质）土柱中的流出趋势.     

水生植物种植场磷素分布特征与植物吸收

研究了水生植物种植场水体、沉积物及植物的磷含量及分布特征,结果表明进水的P浓度高于V类水标准,水生植物种植区内的由于受到沉淀、吸附及植物吸收的影响,水体P浓度远低于进水,水体不同形态P与TP之间呈现良好的相关关系;沉积物的TP质量分数在335～672 mg.kg-1之间,表层沉积物P质量分数是影响底层沉积物P质量分数的主要因素之一,沉积物中的TP和IP、OP之间同样存在相关性;水生植物对P均具有较好的吸收富集能力,不同水生植物的迁移系数均在0.5以上,平均为0.82,其中的黄花蔺(Limnocharis flava)与欧慈菇(Sagittaria sagittifolia)显示对P的良好吸收和迁移能力。基于本次调查的水生植物P质量分数统计分析表明,95%的水生植物地上部P质量分数正常值范围在1 415～4 947mg.kg-1之间,而地下部的P质量分数正常值范围在2 178～5 702 mg.kg-1之间。     

崖角藤的化学成分

从天南星科崖角藤茎95%乙醇提取物中分离得到10个化合物,通过波谱数据鉴定为羽扇豆醇乙酸酯(1)、羽扇豆醇(2)、β-谷甾醇(3)、桦木醇(4)、桦木酸(5)、硬脂酸(6)、ficubee A(7)、ficubee B(8)、artelastin(9)和β-胡萝卜苷(10).     

基于DO-stat流加培养控制的L-异亮氨酸发酵条件优化

L-异亮氨酸(L-lie)产生菌代谢流的前期研究报道认为,较低的溶氧浓度有利于L-异亮氨酸的积累.为进一步提高L-异亮氨酸的产量,采用DO-stat流加培养控制方法,分别研究了溶氧浓度20%、30%、35%和40%下乳糖发酵短杆菌发酵液中葡萄糖浓度的变化以及L-异亮氨酸的合成情况.结果表明,当发酵罐中溶氧浓度控制在20...     

土壤有机质对宁夏农业综合开发活动的响应

为深入分析宁夏农业综合开发活动对土壤有机质的影响,认识其对气候变化的适应意义,分别于北部平原灌区、中部干旱带和南部黄土丘陵区的3个农发项目典型示范点,选取典型用地、玉米地、未利用地3种土地利用类型,分析表层10～20 cm土壤有机质的变化规律。研究发现,生态区和土地利用类型是影响土壤有机质的重要因素,并存在极显著的交互作用。研究区土壤有机质在4.53～14.70 g·kg-1范围内变化,典型用地有显著改善,平均质量分数达10.40 g·kg-1。限定生态区条件下,北部平原灌区无论水稻还是玉米利用方式下,土壤有机质含量相对未利用地都出现显著提升,但是南部黄土丘陵区3种土地利用类型间并无显著差异,中部干旱带只有甘草地土壤有机质含量显著提升,幅度高达145%。限定土地利用类型条件下,3个生态区间典型用地土壤有机质出现显著差异,但是北部平原灌区和南部黄土丘陵区间未利用地以及玉米地表层土壤有机质差异并不显著。研究区农业综合开发活动对土壤有机质储存的作用以正效应为主,但是不同农业土地利用类型在不同生态区对土壤有机质的作用不尽相同。宁夏农业综合开发活动需要综合考虑生态区水土资源特征,选取适宜的农业土地利用类型,有效提升土壤有机质含量,积极应对气候变化。     

西部特大城市FDI比较研究——以西安、成都、重庆为例

自1993年开始,中国连续18年成为FDI流人量最大的发展中国家,并在地区上呈现出“东多西少”的不平衡现象。自2004年以来,我国FDI逐渐向西部地区转移,相关研究尚不多见。以我国西部地区吸引FDI的主要城市西安市、成都市和重庆市为研究对象,从引资规模、投资质量、产业分布、投资来源地和投资方式五个方面进行比较分析,并运用SPSS软件比较了FDI对当地经济增长、产业结构和城市发展等方面的影响。结论为：①重庆市引资规模最大,西安市利用FDI质量最高;西安市的FDI主要投资于第二产业,重庆市和成都市集中于第三产业;三大城市的投资来源地和方式基本相同。②西安市的FDI对经济的拉动作用和对地区资本形成的影响最大,但溢出效应最小,落后于成都市和重庆市。③FDI对西安市城市规模的促进作用最大,而对成都市的城市化水平提升最显著。     

江苏省“十二五”废旧家电处理预测及环境监管对策研究

废弃电器电子产品具有较高的回收利用价值,同时处理不当会导致二次污染。介绍了江苏废弃电器电子产品回收、处理现状,并作预测分析,提出了管理对策和措施。     

Effects of hydrodynamics on the distribution of trace persistent organic pollutants and macrobenthic communities in Bohai Bay

In recent years, the rapid economic development along Bohai Bay, has brought out continuous increasing of the pollution loads in the Bohai Sea, especially by the large coastal reclamation project, Tianjin Binhai New Area. In the period of 2007-2009, we collected the sediments of the main rivers, estuaries, intertidal zone, and near-shore area of Bohai Bay, and Macrobenthos associated with the marine sediments to assess the influence of hydrodynamics in the coastal environment on the pattern of trace contaminants and the macrobenthic community. Based on data derived from these samples, the levels of polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) in sediments followed the order PAHs > OCPs > PCBs > PBDEs. The higher concentrations of PCBs, OCPs, PAHs and PBDEs were found in the estuarine and near-shore environment of the Dagu Drainage River. The spatial distribution of OCPs was different to that of PCBs due to the direction of the velocity field of Bohai Bay in its old and new topography, and the higher water-solubility of OCPs than that of PCBs. The results of the Pearson correlation and the PCA indicate that the medium diameter (MD) of sediments was the predominant factor influencing the distribution of PCBs and OCPs, most sampling sites were characterized mainly by TOC of sediments and biomass of macrobenthos. The results indicate that the distribution of trace contaminants and macrobenthic community in Bohai Bay are mainly affected by the hydrodynamic conditions.     

Polycyclic aromatic hydrocarbons in urban soils of Beijing: status, sources, distribution and potential risk

We studied the source, concentration, spatial distribution and health risk of 16 polycyclic aromatic hydrocarbons (PAHs) in urban soils of Beijing. The total mass concentration of 16 PAHs ranged from 93 to 13 141 μg kg⁻¹ with a mean of 1228 μg kg⁻¹. The contour map of soil PAH concentrations showed that the industrial zone, the historical Hutong district and the university district of Beijing have significantly higher concentrations than those in remainder of the city. The results of sources identification suggested that the primary sources of PAHs were vehicle exhaust and coal combustion and the secondary source was the atmospheric deposition of long-range transported PAHs. The incremental lifetime cancer risks (ILCRs) of exposing to PAHs in the urban soils of Beijing for adult were 1.77 × 10⁻⁶ and 2.48 × 10⁻⁵, respectively under normal and extreme conditions. For child, they were 8.87 × 10⁻⁷ and 6.72 × 10⁻⁶, respectively under normal and extreme conditions.