Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere

The hydroxyl radical (?OH) has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health. Nevertheless, high reactivity, low atmospheric abundance, determination of hydroxyl, and hydroperoxyl radical's quantity is very difficult. In the atmosphere and troposphere, hydroperoxyl radicals (HO₂) are closely demanded in the chemical oxidation of the troposphere. But advances in technology have allowed researchers to improve the determination methods on the research of free radicals through some spectroscopic techniques. So far, several methods such as laser-induced fluorescence (LIF), high-performance liquid chromatography (HPLC), and chemical ionization mass spectroscopy have been identified and mostly used in determining the quantity of hydroxyl and hydroperoxyl radicals. In this systematic review, we have advised the use of scavenger as an advance for further researchers to circumvent some of these problems caused by free radicals. The primary goal of this review is to deepen our understanding of the functions of the most critical free radical (?OH, HO₂) and also understand the currently used methods to quantify them in the atmosphere and troposphere.     

掘进面出风口风流与风幕调控下的粉尘分布响应曲面优化研究*

为了解决煤矿掘进面风筒出风口参数不能动态变化,而传统风幕全断面控尘效果不理想引起的粉尘浓度高等问题,通过分析风幕和出风口参数对粉尘分布规律的影响,以此得到合理的出风口风流与风幕综合调控方案,降低粉尘浓度。以陕西神木柠条塔煤矿N1212巷道为研究对象,利用Fluent软件建立出风口风流与风幕综合调控的粉尘场有限元模型,设计出风口风流及风幕综合调控响应曲面实验,得到最佳综合调控方案为:风幕射流出口宽度为0.16 m,风幕射流出口速度为6 m/s,出风口口径为0.9 m,出风口右偏角度为3°。搭建相似模拟实验平台来验证最佳综合调控方案,研究结果表明:调控后回风侧行人呼吸处和司机位置处粉尘平均浓度分别降低89%和81%,有效改善掘进面作业环境。     

经济战略研究与可持续发展的若干思考

本文分析了战略研究演化的轨迹,揭示了可持续发展的深刻内涵,指出了21世纪我国可持续发展面临的机遇。     

基于LS-DYNA的交错扇形深孔崩落法排间间隔时间优化研究

为了同时解决"隐患资源高效回收"和"空区隐患安全治理"这对矛盾问题,提出交错扇形深孔崩落法;采用室内试验和数值模拟相结合的方法,根据交错扇形布孔形式建立数值计算模型,按照1#矿体岩石的物理力学指标确定模型材料参数,采用LS-DYNA动力仿真软件优选扇形排间间隔时间.研究结果表明:当采空一区排间间隔为100 ms时,岩石...     

氮源对枯草芽孢杆菌WSHDZ-01合成过氧化氢酶的影响

为提高枯草芽孢杆菌WSHDZ-01合成过氧化氢酶的水平,尝试了不同种类氮源的添加.结果表明,硝酸钠(NaNO3)为适宜氮源,虽然生物量仅1.25 g/L,但过氧化氢酶活力最高可达3 200 U/mL.在添加NaNO,的基础上,研究了添加其它氮源麦芽汁、酵母膏、玉米浆对提高wsHDz.0l生物量的影响,发现适宜浓度的麦芽汁不仅可以提高生物量,并且能够缩短发酵周期.经进一步优化,在3 L发酵罐中,WSHDZ-01生物量提高到6 g/L,过氧化氢酶活力达到11 000 U/mL,与优化前相比,发酵周期缩短了近60%,生产强度提高了3倍.     

原子荧光光谱法及其在水分析中的应用

主要介绍了原子荧光光谱分析法的产生、基本原理和特点;以及原子荧光光谱法应用于分析测定水中As、Hg、Pb、Se等元素。同时对原子荧光光谱分析方法的发展状况作了阐述。     

Adsorption thermodynamics and kinetic investigation of aromatic amphoteric compounds onto different polymeric adsorbents

The adsorption behavior of p-aminobenzoic acid and o-aminobenzoic acid onto the different polymeric adsorbents was systematically investigated as a function of the solution concentration and temperature.Experimental results indicated that the equilibrium adsorption data of the four polymeric adsorbents fitted well in the Freundlich isotherm.The adsorption capacity of multi-functional polymeric adsorbent NJ-99 was the highest,which might be attributed to the strong hydrogen-bonding interaction between the amino groups on the resin and the carboxyl group of aminobenzoic acid.The adsorption capacity of o-aminobenzoic acid onto any adsorbent was higher than p-aminobenzoic acid.Thermodynamic studies suggested the exothermic,spontaneous physical adsorption process.Adsorption kinetics results showed that the adsorption followed the pseudo-second-order kinetics model and the intraparticle mass transfer process was the rate-controlling step.     

流动污染源的排放控制现状及发展趋势

评述了４种主要的流动污染源即汽车、内燃机车、船舶、航空发动机的排放现状，介绍了欧美及中国为了控制排气污染所采用的排放标准，并阐述了各种流动污染源相应的排放净化措施，指出了流动污染源严格监控的迫切性，并提出了相应的建议。     

辽东湾近岸冰区生态环境初步调查研究

１９９６年１月２６－３１日，在辽东湾近岸冰区选设４个站位进行了一次内容较为全面的生态环境调查研究，其项目包括温度、盐度、ｐＨ、ＤＯ、ＣＯＤ、ＴＯＣ、ＰＯＣ、营养盐、微生物、叶绿素、浮游植物、浮游动物和度栖动物。结果表明，辽东湾近岸冰区营养盐含量丰富，叶绿素ａ含量较低，存在一定数量的浮游生物。海水中硝酸盐、铵盐和磷酸盐含量均为冰中含量的１．５倍左右，海水中硅酸盐含量是冰的４．１６倍，亚硝酸盐和叶绿素     

华北平原的水土资源平衡研究

采用精确的水土资源平衡计算模型 ,辅以田间观测资料 ,分析计算了华北平原农业水资源量与作物需水量之间的平衡问题。结果显示 :在充分供水的条件下 ,本区农田 (884.8万hm₂)需水量为744.36亿m3,相应的作物亏水量为309.37亿m3,有效灌溉面积 (653.2万hm₂)上的亏水量为228.73亿m3;而1995年水利工程提供的农业总用水量已达261.78亿m3,但仍有116.16亿m3的亏水量 ;文中同时对评价区内农田的有效降水量、灌溉水的田间利用量、毛管上升水量等进行估算。指出 ,虽然冬小麦的平均水分满足率为82 % ,但关键期的水分满足率 (64 % )仍然制约粮食产量的增长 ,设想通过提高渠系利用系数和优化灌溉等措施 ,华北平原的农业可望达到水土资源平衡利用的状态