Scale and causes of lead contamination in Chinese tea

We investigated the scale and causes of Pb contamination in Chinese tea. Lead concentrations in 1,225 tea samples collected nationally between 1999 and 2001 varied from <0.2 to 97.9 mg kg(-1) dry weight (DW), with 32% of the samples exceeding the national maximum permissible concentration (MPC) of 2.0 mg kg(-1) DW and a significant difference between tea types. There was an increasing trend in tea Pb concentration from 1989 to 2000. Proximity to highway and surface dust contamination were found to cause elevated Pb concentrations in tea leaves. Furthermore, Pb concentration in tea leaves correlated significantly and positively with soil extractable Pb, and negatively with soil pH, suggesting that root uptake of Pb from soils also contributed to Pb accumulation in tea. Potential contributions to human Pb intake from drinking tea were small at the median or national MPC Pb values, but considerable at the highest concentration found in the study.     

Predicting phosphorus availability from soil-applied composted and non-composted cattle feedlot manure

Prediction of phosphorus (P) availability from soil-applied composts and manure is important for agronomic and environmental reasons. This study utilized chemical properties of eight composted and two non-composted beef cattle (Bos taurus) manures to predict cumulative phosphorus uptake (CPU) during a 363-d controlled environment chamber bioassay. Ten growth cycles of canola (Brassica napus L.) were raised in pots containing 2 kg of a Dark Brown Chernozemic clay loam soil (fine-loamy, mixed, Typic Haploboroll) mixed with 0.04 kg of the amendments. Inorganic P fertilizer (KH2PO4) and an unamended control were included for comparison. All treatments received a nutrient solution containing an adequate supply of all essential nutrients, except P, which was supplied by the amendments. Cumulative P uptake was similar for composted (74 mg kg-1 soil) and non-composted manures (60 mg kg-1 soil) and for the latter and the fertilizer (40 mg kg-1 soil). However, the CPU was significantly higher for organic amendments than the control (24 mg kg-1 soil) and for composted manure than the fertilizer. Apparent phosphorus recovery (APR) from composted manure (24%) was significantly lower than that from non-composted manure (33%), but there was no significant difference in APR between the organic amendments and the fertilizer (27%). Partial least squares (PLS) regression indicated that only two parameters [total water-extractable phosphorus (TPH2O) and total phosphorus (TP) concentration of amendments] were adequate to model amendment-derived cumulative phosphorus uptake (ACPU), explaining 81% of the variation in ACPU. These results suggest that P availability from soil-applied composted and non-composted manures can be adequately predicted from a few simple amendment chemical measurements. Accurate prediction of P availability and plant P recovery may help tailor manure and compost applications to plant needs and minimize the buildup of bioavailable P, which can contribute to eutrophication of sensitive aquatic systems.     

Veterinary antimicrobials in feedlot manure: dissipation during composting and effects on composting processes

Composting of manure may lead to the degradation of veterinary antimicrobials, but it is largely unknown if the presence of antimicrobials affects the composting process. Open-air windrow composting of manure from beef cattle (Bos taurus) administered chlortetracycline, sulfamethazine, and tylosin was investigated in a 2-yr study. At windrow construction, chlortetracycline had extensively isomerized to iso-chlortetracycline. Sulfamethazine, tylosin, and iso-chlortetracycline dissipated by first-order kinetics, whereas the dissipation of enol/keto-chlortetracycline was better described by exponential equations. At the end of the composting period, proportions of antimicrobials remaining were as follows: iso-chlortetracycline (< 1%), chlortetracycline (1 to 4.5%), tylosin (6.3%), and sulfamethazine (6.8% [2005], 41% [2006]). Times for 50% dissipation (DT50) decreased in the order: tylosin (20.3 to 43.5 d) > iso-chlortetracycline (13.5 to 26.5 d) > enol/keto-chlortetracycline (5.5 to 9.8 d). The DT50 values for sulfamethazine varied from 26.8 d in 2005 to 237 d in 2006. Treatments with chlortetracycline showed significantly reduced temperature rises (10.1 to 11.0 degrees C) between Days 21 to 28 in 2006 compared with rises of 26.6 to 31.0 degrees C for control and tylosin treatments, suggesting an inhibition of microbial activity. During composting in 2005, manure from cattle administered chlortetracycline at 44 mg kg(-1) of feed lost significantly less dry matter, carbon, and nitrogen than manure from cattle fed 11 mg chlortetracycline kg(-1) of feed, implying that the higher level of chlortetracycline inhibited microbial decomposition of organic matter. The study shows that while composting leads to dissipation of antimicrobials, the microbially driven composting process may be inhibited by their presence.     

Climate change effects on hydroecology of arctic freshwater ecosystems

In general, the arctic freshwater-terrestrial system will warm more rapidly than the global average, particularly during the autumn and winter season. The decline or loss of many cryospheric components and a shift from a nival to an increasingly pluvial system will produce numerous physical effects on freshwater ecosystems. Of particular note will be reductions in the dominance of the spring freshet and changes in the intensity of river-ice breakup. Increased evaporation/evapotranspiration due to longer ice-free seasons, higher air/water temperatures and greater transpiring vegetation along with increase infiltration because of permafrost thaw will decrease surface water levels and coverage. Loss of ice and permafrost, increased water temperatures and vegetation shifts will alter water chemistry, the general result being an increase in lotic and lentic productivity. Changes in ice and water flow/levels will lead to regime-specific increases and decreases in habitat availability/quality across the circumpolar Arctic.     

In situ fixation of metals in soils using bauxite residue: biological effects

Soils polluted with heavy metals can cause phytotoxicity and exhibit impared microbial activities. In this paper we evaluate the responses of different biological endpoints to in situ remediation processes. Three soil amendments (red mud, beringite and lime) were applied to two soils polluted by heavy metals. Oilseed rape, wheat, pea and lettuce were grown successively in pots on the untreated and amended soils and their yield and metal uptake were determined. A suite of microbial tests (lux-marked biosensors, Biolog and soil microbial biomass) were performed to determine the effect of the soil amendments on the functionality and size of the soil microbial community. In both soils all three amendments reduced phytotoxicity of heavy metals, enhanced plant yields and decreased the metal concentrations in plants. The red mud treatment also increased soil microbial biomass significantly. The microbial biosensors responded positively to the remediation treatments in the industrially-contaminated soil used in the experiment. Red mud applied at 2% of soil weight was as effective as beringite applied at 5%. The results also showed that since the biological systems tested respond differently to the alleviation of metal toxicity, a suite of biological assays should be used to assess soil remediation processes.     

Linking empowering leadership to safety participation in nuclear power plants: A structural equation model

IntroductionSafety participation is of paramount importance in guaranteeing the safe running of nuclear power plants.MethodThe present study examined the effects of empowering leadership on safety participation.ResultsBased on a sample of 495 employees from two Spanish nuclear power plants, structural equation modeling showed that empowering leadership has a significant relationship with safety participation, which is mediated by collaborative team learning. In addition, the results revealed that the relationship between empowering leadership and collaborative learning is partially mediated by the promotion of dialogue and open communication.ConclusionsThe implications of these findings for safety research and their practical applications are outlined.Impact on IndustryAn empowering leadership style enhances workers' safety performance, particularly safety participation behaviors. Safety participation is recommended to detect possible rule inconsistencies or misunderstood procedures and make workers aware of critical safety information and issues.     

The use of artificial neural networks to forecast biological atmospheric allergens or pathogens only as Alternaria spores

The monitoring of atmospheric Alternaria spores is of major importance due to their adverse effects on crops and their role as human allergens. Most species act as plant pathogens, prompting considerable economic losses worldwide on important crops such as potato, tomato or wheat. Fungal spores can also have serious detrimental effects on human health, triggering respiratory diseases and allergenic processes. The aim of this study was not only to examine the relationship between the atmospheric Alternaria spore content and the prevailing meteorological parameters, but also to predict the atmospheric Alternaria spore content in the Northwest Spain using a novel data analysis technique, ANNs (Artificial Neural Networks). A Hirst-type LANZONI VPPS 2000 volumetric 7-day recording sampler was used to collect the airborne spores from 1997 to 2008. Neural networks provided us with a good tool for forecasting Alternaria airborne spore concentration, and thus could help the automation of the prediction system in the aerobiological information diffusion to the population suffering from allergic problems or the prevention of considerable economic worldwide losses on important crops. Our proposed model would be applied to different geographical areas; nevertheless, the adjustment of the model, by using the available and adequate variables, would be realised in each case.     

Quantity and quality of runoff from a beef cattle feedlot in southern Alberta

Southern Alberta, which has a cold climate dominated by strong chinook winds, has the highest density of feedlot cattle in Canada. However, the quantity and quality of runoff from beef cattle (Bos taurus) feedlots in this unique region has not been investigated. Our objectives were to compare runoff quantity (1998-2002) with catch-basin design criteria; determine concentrations of selected inorganic chemical parameters (1998-2000) in runoff in relation to water quality guidelines and the potential implications of irrigating adjacent crop-land; and determine if total heterotrophs, total coliforms, and Escherichia coli (1998-2000) persisted in the catch-basin water and soil. Runoff (< 0.1 to 42.5 mm) for a 24-h duration that included maximum peak discharge was less than the recommended design criteria of 90 mm based on runoff from 24 h of rainfall with a 30-yr return period. We found that curve numbers between 52 and 96 (mode of 90) were required to match the USDA Natural Resources Conservation Service predicted runoff and actual runoff volumes. Total P posed the greatest threat to water quality guidelines, and K posed the greatest threat for exceeding crop fertilizer requirements if catch-basin effluent was used as irrigation water. Water in the catch basin had continually high populations of E. coli throughout the study, with values ranging between log10 2 and log10 8 100 mL(-1). In contrast, soil in the catch basin generally had low populations of E. coli that were < log10 2 g(-1) wet wt., but at times higher populations between log10 2 and log10 6 g(-1) wet wt. were also found.