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包覆型纳米零价铁活化过硫酸处理柴油污染土壤 总被引:1,自引:0,他引:1
采用Tween-20作为包覆材料对纳米零价铁(n ZVI)进行改性(T-n ZVI),并利用T-n ZVI活化过硫酸盐(PS)降解柴油,同时与未改性纳米零价铁活化过硫酸盐体系(n ZVI/PS)进行对比.结果显示,在n ZVI/PS体系中,柴油降解率随着n ZVI及PS用量的增加而增加.在T-n ZVI/PS体系中,反应90 d后,柴油最大降解率为78%.与n ZVI/PS体系相比,T-n ZVI/PS体系所有组别的柴油降解率均有所提升,但提升幅度不大.同时对T-n ZVI活化PS的机理进行了推测. 相似文献
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为探索加油站火灾爆炸事故致因机理,从而建立安全评价模型,在分析加油站火灾爆炸事故因素的基础上,从人的因素和物的因素视角构建加油站安全状态突变模型,并针对常用加油站安全评价中权重获取受主观影响的问题,提出基于突变理论的加油站火灾爆炸事故安全评价方法,该方法通过对评价目标进行多层次分解,利用归一化公式计算出总突变隶属函数值,实现了加油站安全等级评价与动态评判。实例验证表明:突变模型合理地诠释了加油站火灾爆炸事故形成的规律,安全评价结果是合理、可行的,为加油站安全综合评价提供了新思路。 相似文献
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Yun Fei Yao Qiao-Mei Liang Dong-Wei Yang Hua Liao Yi-Ming Wei 《Mitigation and Adaptation Strategies for Global Change》2016,21(6):799-821
Economic and social costs and benefits are critical factors affecting greenhouse gas abatement activities. Recognizing that energy prices are one of the most important factors influencing abatement costs, this study improved the basic China Energy and Environmental Policy Analysis (CEEPA) model by introducing a current energy pricing mechanism for China. The improved model was applied to generate marginal abatement cost (MAC) curves for China including the current energy pricing mechanism and to analyze MACs for the whole country and main abatement sectors in China under different energy pricing mechanisms. The results show that China MACs are sensitive to pricing mechanisms for electricity and refined oil. Ignoring the current regulation of these prices will lead to MAC underestimation, and price liberalization of these two energy sources could lead to a decrease in China MACs. Under a 50 % emission reduction target, if the electricity price regulation is ignored, the China MAC is underestimated by almost 16 %. Energy pricing reforms will lead to variations in sectoral abatement costs and overall abatement potential, and these impacts are projected to be large in the electricity sector. Under a 50 % reduction target, if the electricity price regulation is liberalized, MAC for the electricity sector nearly will decrease 50 %. 相似文献
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Microbial bioavailability of dissolved organic nitrogen (DON) in the sediments of Lake Shankou, Northeastern China 总被引:2,自引:0,他引:2
Mingzhou Su Jingtian Zhang Shouliang Huo Beidou Xi Fei Hua Fengyu Zan Guangren Qian Jianyong Liu 《环境科学学报(英文版)》2016,28(4):79-88
Dissolved organic nitrogen(DON)extracted from Lake Shankou sediments using KCl was isolated into hydrophobic and hydrophilic fractions.The bioavailabilities of the hydrophobic and hydrophilic fractions to three types of bacterial communities collected from sediments,activated sludge and compost products were examined.The DON recoveries obtained by DAX-8 and cation exchange resins treatment were 96.17% ± 1.58% and 98.14% ±0% for the samples obtained from N4 and N14 stations,respectively.After 25 days of incubation at 25°C,most DON(59% to 96%)was degraded.Hydrophilic DON exhibited a higher reduction rate than hydrophobic DON during the growth phase.Untreated wastewater from Changshuihe town was the main degradable DON source to station N4,and 93% of hydrophilic DON and 80% of hydrophobic DON were degraded.Station N14 received a large amount of refractory DON from forest soils and exhibited DON degradation rates of 82% and 71% for the hydrophilic and hydrophobic fractions,respectively.Amino acid contents and fluorescence intensities were also analyzed.Approximately 27% to 74% of amino acids were taken up by day 5,and their concentration gradually increased in the following days due to the decomposition of dissolved proteins.Parallel factor analysis resulted in identification of tryptophan-like proteins,tyrosine-like proteins and FA-like substances.During the growth phase,40%–51% of the tryptophan-like proteins were taken up by bacteria,and the accumulation of tyrosine-like proteins was attributed to the release of biotic substances.The concentration of the FA-like substances decreased due to microbial decomposition. 相似文献
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