基于流态化作用的吸附反应动力学和穿透特征

基于流态化作用的吸附反应动力学和穿透特征研究还鲜见报道.以苯酚为吸附质、活性炭为吸附剂,探讨了不同流态化紊流强度对基于流态化作用的吸附效率、吸附动力学特性、吸附反应穿透曲线和饱和吸附量的影响,并与相同条件的固定床吸附反应器进行了对比研究.结果表明,表观流速为8 mm·s-1和13 mm·s-1时,基于流态化和固定态的活性炭在5 min内的吸附效率均达到93%以上,吸附反应均符合经典二级动力学方程,且其相关系数大于0.999.穿透实验结果表明,表观流速为6 mm·s-1和8 mm·s-1时,基于流态化的活性炭对苯酚的吸附总量分别较固定态高8.77 mg·g-1和24.70 mg·g-1.可见,基于流态化吸附反应器与基于固定态吸附反应器相比,具有吸附反应效率高,吸附总量大的特征.     

微污染水源水处理技术探析

近年来,我国不少地区饮用水水源水质日益恶化,水质净化面临新的问题。通过对微污染水源水处理技术的分析,阐明了微污染水处理的基本理论,探讨了强化传统处理工艺、预处理技术、深化处理技术的作用效果与机理,展望了我国饮用水源水处理发展趋势。     

Effects of cathode potentials and nitrate concentrations on dissimilatory nitrate reductions by Pseudomonas alcaliphila in bioelectrochemical systems

The effects of cathode potentials and initial nitrate concentrations on nitrate reduction in bio- electrochemical systems （BESs） were reported. These factors could partition nitrate reduction between denitrification and dissimilatory nitrate reduction to ammonium （DNRA）. Pseudomonas alcaliphilastrain MBR utilized an electrode as the sole electron donor and nitrate as the sole electron acceptor. When the cathode potential was set from -0.3 to -I.1 V （vs. Ag/AgC1） at an initial nitrate concentration of 100 mg NO~-N/L, the DNRA electron recovery increased from （10.76 ± 1.6）% to （35.06 ± 0.99）%; the denitrification electron recovery decreased from （63.42 ± 1,32）% to （44.33 ± 1.92）%. When the initial nitrate concentration increased from （29.09 ± 0.24） to （490.97 ± 3.49） mg NO3-N/L at the same potential （-0.9 V）, denitrification electron recovery increased from （5.88 ± 1.08）% to （50.19 ±2.59）%; the DNRA electron recovery declined from （48.79 ±1.32）% to （16.02 ± 1.41）%. The prevalence of DNRA occurred at high ratios of electron donors to acceptors in the BESs and denitrification prevailed against DNRA under a lower ratio of electron donors to acceptors. These results had a potential application value of regulating the transformation of nitrate to N2 or ammonium in BESs for nitrate removal.     

Extraction and characterization of bound extracellular polymeric substances from cultured pure cyanobacterium (Microcystis wesenbergii)

Preliminary characterization of bound extracellular polymeric substances（bEPS） of cyanobacteria is crucial to obtain a better understanding of the formation mechanism of cyanobacterial bloom. However,the characterization of bEPS can be affected by extraction methods. Five sets（including the control） of bEPS from Microcystis extracted by different methods were characterized using three-dimensional excitation and emission matrix（3DEEM） fluorescence spectroscopy combined chemical spectrophotometry; and the characterization results of bEPS samples were further compared. The agents used for extraction were NaOH,pure water and phosphate buffered saline（PBS） containing cationic exchange resins,and hot water. Extraction methods affected the fluorescence signals and intensities in the bEPS. Five fluorescence peaks were observed in the excitation and emission matrix fluorescence spectra of bEPS samples. Two peaks（peaks T1 and T2） present in all extractions were identified as protein-like fluorophores,two（peaks A and C） as humic-like fluorophores,and one（peak E） as a fulvic-like substance.Among these substances,the humic-like and fulvic-like fluorescences were only seen in the bEPS extracted with hot water. Also,NaOH solution extraction could result in strong fluorescence intensities compared to the other extraction methods. It was suggested that NaOH at pH 10.0 was the most appropriate method to extract bEPS from Microcystis. In addition,dialysis could affect the yields and characteristics of extracted bEPS during the determination process. These results will help us to explore the issues of cyanobacterial blooms.     

常村煤矿综掘面合理除尘方式选择及其应用

为了合理选择常村煤矿综掘面除尘的通风方式,本文根据煤矿中常用的通风方式和气固两相流的理论,利用fluent非稳态的数值模拟方法来模拟压入式和长压短抽两种不同通风方式下常村煤矿掘进面粉尘的运移规律以及司机处粉尘浓度分布,并进行了现场实测验证。结果表明:对于粉尘运移模型,采用非稳态的求解器要比稳态的求解器更加精确;在长压短抽通风方式下,涡流对粉尘运移影响较大,可以通过调整风速和除尘风机的负压来减小涡流的影响区域;采用长压短轴的通风方式比压入式通风方式在数值模拟情况下,前者比后者掘进机前部的粉尘浓度降低了22.2%,通过现场实测得到其降低了31.6%,巷道中部粉尘的平均浓度可由508mg/m3下降到185mg/m3,降幅为63.6%,表明长压短抽通风方式数值模拟和现场实测都要优于压入式通风方式;此外,需要在掘进机的前面和回风侧增加除尘措施,以确保司机处的粉尘浓度符合标准。     

高性能聚乙烯纤维手套防护性能研究

采用实验室测试和现场调查相结合的方法,测试了高性能聚乙烯纤维手套的防护性能,调查手套的适应性、防护时间和费用支出,探讨了其应用前景。     

烧结多孔管的制作及其沸腾传热研究

目的研究烧结多孔管表面多孔层的制造工艺,并对铜粉烧结多孔层表面的传热性能进行测定。方法利用烧结模具在铜管外面烧结铜粉层,并通过实验计算出多孔烧结管的热通量和强化换热系数。结果铜粉烧结后的铜管在酒精中的强化传热效果达到了光管的10倍左右。结论烧结铜粉粒径越小,烧结管的热通量越大,其传热性能越好。     

河流穿越施工的环境风险分析研究——油气管道大开挖及河流穿越

针对油气管道大开挖河流穿越施工影响周边环境问题,在分析大开挖河流穿越施工对空气环境、水环境、声环境、生态环境风险的基础上,以某条输气管道大开挖穿越河流部分为例,建立了环境风险影响评价指标,采用了一种改进的灰色关联分析法确定了大开挖河流穿越施工造成的环境风险影响因素权重,得出该类型施工对环境影响的主要风险因素,并提出了相应的降低环境影响的风险控制措施。     

高效液相色谱荧光检测法测定环境水体中的苯酚的实验研究

苯酚毒性大、难降解,是严重的环境污染物,同时也是环境监测的重要指标。文章介绍了用高效液相色谱荧光检测法测定环境水体中苯酚的分析方法。实验条件,色谱柱VP-ODS（150×4.6 mm,5 um）;柱温25℃;流动相：V（甲醇）∶V（水）=46∶54,检测波长为λex/λem=215/300 nm,进样量20 uL。测定结果,苯酚的线性范围0.20～100 mg/L,r=0.999 3,检出限0.1 mg/L。表明该方法适用于对环境水体中苯酚的测定。     

自动在线监测系统利用软件数据质控有效性研究

自动在线监测设备对排放的污染物进行实时监测,获取真实有效的监测数据。研究自动在线监测设备监测数据质量保证系统是污染源自动在线监控系统科学判断和分析环境问题的前提。软件系统是数据采集、记录和存储、传输、统计分析、自我识别、形成报表和报告的集成,也是监测数据质量保证的有效手段,通过设定“阈值”和“条件”．实现了监测数的自动甄别、纠错和报警。