Canada’s Mobile Sources Air Pollution Control Program

The chemical and optical properties of particle emissions from onroad vehicles were investigated at the Allegheny Tunnel on the Pennsylvania Turnpike during July 1981. The optical results are in agreement with earlier data: (1) in terms of light extinction per km driven, diesel particle emissions are at least an order of magnitude more important than particle emissions from spark-ignition vehicles; (2) for diesel particle emissions, light absorption is about twice as efficient as light scattering. Chemical analyses showed that: (1) 24% of the vehicle aerosol was extractable material, (2) 75% of the total mass was carbon, (3) 55% of the total mass was unextractable (elemental) carbon, and (4) the stoichiometry of the extractable fraction of the diesel particle emissions was C_nH_t.7nN_0.05n , i.e., the extractable material was composed predominantly of alkanes. The results of the chemical analyses allow the calculation of the massspecific light absorption coefficient for the elemental carbon component of the diesel particle emissions, i.e., 10.9 ± 1.8 m²/g (500 nm).     

Testing and Commercialization of Byproduct Dibasic cids as Buffer Additives for Limestone Flue Gas esulfurization Systems

Pilot plant (0.1 MW) tests and utility boiler full scale demonstration (194 MW) of byproduct organic dibasic acids (DBA) as buffer additives to limestone scrubbers have shown performance improvements equivalent to those achieved by the addition of pure adipic acid. Both SO₂ removal efficiency and limestone utilization increased, and no significant operating problems were observed with three of the four DBA tested. Chemical and biological evaluations of scrubber samples taken during the DBA testing indicated no detectable tOxicity or mutagenicity, and no significant environmental impact is expected as a result of DBA addition. Economic estimates indicate that substitution of DBA for pure adipic acid as a buffer additive will result in additive cost savings of 30 % or greater.     

Effect of fresh green waste and green waste compost on mineral nitrogen, nitrous oxide and carbon dioxide from a Vertisol

Incorporation of organic waste amendments to a horticultural soil, prior to expected risk periods, could immobilise mineral N, ultimately reducing nitrogen (N) losses as nitrous oxide (N₂O) and leaching. Two organic waste amendments were selected, a fresh green waste (FGW) and green waste compost (GWC) as they had suitable biochemical attributes to initiate N immobilisation into the microbial biomass and organic N forms. These characteristics include a high C:N ratio (FGW 44:1, GWC 35:1), low total N (<1%), and high lignin content (>14%). Both products were applied at 3 t C/ha to a high N (plus N fertiliser) or low N (no fertiliser addition) Vertisol soil in PVC columns. Cumulative N₂O production over the 28 day incubation from the control soil was 1.5 mg/N₂O/m², and 11 mg/N₂O/m² from the control + N. The N₂O emission decreased with GWC addition (P < 0.05) for the high N soil, reducing cumulative N₂O emissions by 38% by the conclusion of the incubation. Analysis of mineral N concentrations at 7, 14 and 28 days identified that both FGW and GWC induced microbial immobilisation of N in the first 7 days of incubation regardless of whether the soil environment was initially high or low in N; with the FGW immobilising up to 30% of available N. It is likely that the reduced mineral N due to N immobilisation led to a reduced substrate for N₂O production during the first week of the trial, when soil N₂O emissions peaked. An additional finding was that FGW + N did not decrease cumulative N₂O emissions compared to the control + N, potentially due to the fact that it stimulated microbial respiration resulting in anaerobic micro sites in the soil and ultimately N₂O production via denitrification. Therefore, both materials could be used as post harvest amendments in horticulture to minimise N loss through nitrate-N leaching in the risk periods between crop rotations. The mature GWC has potential to reduce N₂O, an important greenhouse gas.     

Model projected heat extremes and air pollution in the eastern Mediterranean and Middle East in the twenty-first century

The eastern Mediterranean and Middle East, a region with diverse socioeconomic and cultural identities, is exposed to strong climatic gradients between its temperate north and arid south. Model projections of the twenty-first century indicate increasing hot weather extremes and decreasing rainfall. We present model results, which suggest that across the Balkan Peninsula and Turkey climate change is particularly rapid, and especially summer temperatures are expected to increase strongly. Temperature rise can be amplified by the depletion of soil moisture, which limits evaporative cooling, prompted by the waning of large-scale weather systems that generate rain. Very hot summers that occurred only rarely in the recent past are projected to become common by the middle and the end of the century. Throughout the region, the annual number of heat wave days may increase drastically. Furthermore, conditions in the region are conducive for photochemical air pollution. Our model projections suggest strongly increasing ozone formation, a confounding health risk factor particularly in urban areas. This adds to the high concentrations of aerosol particles from natural (desert dust) and anthropogenic sources. The heat extremes may have strong impacts, especially in the Middle East where environmental stresses are plentiful.     

Building resilience to water scarcity in southern Spain: a case study of rice farming in Doñana protected wetlands

Agricultural water management needs to evolve in view of increased water scarcity, especially when farming and natural protected areas are closely linked. In the study site of Doñana (southern Spain), water is shared by rice producers and a world heritage biodiversity ecosystem. Our aim is to contribute to defining adaptation strategies that may build resilience to increasing water scarcity and minimize water conflicts among agricultural and natural systems. The analytical framework links a participatory process with quantitative methods to prioritize the adaptation options. Bottom-up proposed adaptation measures are evaluated by a multi-criteria analysis (MCA) that includes both socioeconomic criteria and criteria of the ecosystem services affected by the adaptation options. Criteria weights are estimated by three different methods—analytic hierarchy process, Likert scale and equal weights—that are then compared. Finally, scores from an MCA are input into an optimization model used to determine the optimal land-use distribution in order to maximize utility and land-use diversification according to different scenarios of funds and water availability. While our results show a spectrum of perceptions of priorities among stakeholders, there is one overriding theme that is to define a way to restore part of the rice fields to natural wetlands. These results hold true under the current climate scenario and even more so under an increased water scarcity scenario.     

Interinstrument comparison of remote-sensing devices and a new method for calculating on-road nitrogen oxides emissions and validation of vehicle-specific power

Emissions of nitrogen oxides (NOx) by vehicles in real driving environments are only partially understood. This has been brought to the attention of the world with recent revelations of the cheating of the type of approval tests exposed in the dieselgate scandal. Remote-sensing devices offer investigators an opportunity to directly measure in situ real driving emissions of tens of thousands of vehicles. Remote-sensing NO₂ measurements are not as widely available as would be desirable. The aim of this study is to improve the ability of investigators to estimate the NO₂ emissions and to improve the confidence of the total NOx results calculated from standard remote-sensing device (RSD) measurements. The accuracy of the RSD speed and acceleration module was also validated using state-of-the-art onboard global positioning system (GPS) tracking. Two RSDs used in roadside vehicle emissions surveys were tested side by side under off-carriageway conditions away from transient pollution sources to ascertain the consistency of their measurements. The speed correlation was consistent across the range of measurements at 95% confidence and the acceleration correlation was consistent at 95% confidence intervals for all but the most extreme acceleration cases. VSP was consistent at 95% confidence across all measurements except for those at VSP ≥ 15 kW t^?1, which show a small underestimate. The controlled distribution gas nitric oxide measurements follow a normal distribution with 2σ equal to 18.9% of the mean, compared to 15% observed during factory calibration indicative of additional error introduced into the system. Systematic errors of +84 ppm were observed but within the tolerance of the control gas. Interinstrument correlation was performed, with the relationship between the FEAT and the RSD4600 being linear with a gradient of 0.93 and an R² of 0.85, indicating good correlation. A new method to calculate NOx emissions using fractional NO₂ combined with NO measurements made by the RSD4600 was constructed, validated, and shown to be more accurate than previous methods.

Implications: Synchronized remote-sensing measurements of NO were taken using two different remote-sensing devices in an off-road study. It was found that the measurements taken by both instruments were well correlated. Fractional NO₂ measurements from a prior study, measurable on only one device, were used to create new NO_x emission factors for the device that could not be measured by the second device. These estimates were validated against direct measurement of total NO_x emission factors and shown to be an improvement on previous methodologies. Validation of vehicle-specific power was performed with good correlation observed.     

Environment-health link in a context of urban agricultures: studies of oral exposure to pollutants in order promote the human health

Environmental Science and Pollution Research -