聚苯乙烯基硫代磺酸钾树脂的合成及其与卤代烃的反应

由聚苯乙烯基磺酰氯树脂与硫化氢钾反应制备聚苯乙烯基硫代磺酸钾树脂（Ｉ）,树脂Ｉ与亲电的卤代烃反应,生成聚苯乙烯基硫代磺酸酯树脂（Ⅱ）,树脂Ⅱ经过乙硫醇处理,使卤代烃结构部分以不对称二硫醚的形式游离下来,用ＧＣ／ＭＳ对其结构进行鉴定。从不对称二硫醚的结构可推导出原卤代烃的结构,所制备的聚苯乙烯基硫代磺酸钾树脂的转化效率为１．１１ｍｍｏｌ·ｇ＾－１。     

土壤优先流的理论研究和试验分析

在活动流场模型的基础上建立了新的溶质运移控制方程,研究了流场分形特征参数的计算方法;采用4组染色示踪试验资料,分析了活动流场模型模拟土壤水流运动和溶质运移宏观非均匀特征的适用性.模拟分析表明,活动流场模型能较准确地捕捉到土壤中的优先流特别是不稳定流的宏观运动特征;土壤存在大孔隙结构的情况下,水流和溶质将更快的迁移到深层土壤,活动流场模型模拟计算的入渗深度偏小,但大于连续性模型的模拟计算结果;当土壤中的大孔隙结构较少时,活动流场模型模拟预测的土壤含水率分布和溶质浓度分布与实测结果比较一致.     

The estimated reduction in the odds of loss-of-control type crashes for sport utility vehicles equipped with electronic stability control

INTRODUCTION: Using data from the NASS General Estimates System (GES), the method of induced exposure was used to assess the effects of electronic stability control (ESC) on loss-of-control type crashes for sport utility vehicles. METHOD: Sport utility vehicles were classified into crash types generally associated with loss of control and crash types most likely not associated with loss of control. Vehicles were then compared as to whether ESC technology was present or absent in the vehicles. A generalized additive model was fit to assess the effects of ESC, driver age, and driver gender on the odds of loss of control. In addition, the effects of ESC on roads that were not dry were compared to effects on roads that were dry. RESULTS: Overall, the estimated percentage reduction in the odds of a loss-of-control crash for sport utility vehicles equipped with ESC was 70.3%. Both genders and all age groups showed reduced odds of loss-of-control crashes, but there was no significant difference between males and females. With respect to driver age, the maximum percentage reduction of 73.6% occurred at age 27. The positive effects of ESC on roads that were not dry were significantly greater than on roads that were dry.     

Positive affectivity neutralizes transformational leadership's influence on creative performance and organizational citizenship behaviors

This study uses an interactionist approach to examine the moderating effect of follower trait positive affectivity (trait PA) on the relation between transformational leadership and both follower creative performance and organizational citizenship behaviors (OCB). On the basis of responses from 212 employees and their direct supervisors from the research and development department of a company in Mainland China, results support the hypothesized moderation effect. Specifically, the positive influence of transformational leadership on creative performance was significantly reduced for followers who were higher on trait PA (ΔR² = .02, p < .05). The same pattern, in which followers' trait PA appeared to substitute for the influence of transformational leadership, generalized to the outcome of follower OCB as well (ΔR² = .04, p < .01). We discussed theoretical and practical implications of these findings. Copyright © 2012 John Wiley & Sons, Ltd.     

Ergonomics and Quality Management—Humans in Interaction With Technology,Work Environment,and Organization

Abstract

In many studies, ergonomics has been shown to influence human performance. The aim of this paper was to demonstrate imp ortan t ergonomics influences on quality in industrial production, from the perspective of interactions between humans, technology, organization, and work environment. A second aim was to elab orate on the implications of these findings for the development of quality management strategies. This paper shows that ergonomics problems in terms of adverse work environmental conditions, in appropriate design of technology, and an unsuitable org an izatio n are important causes of quality deficiencies. Problem solving aimed at improving ergonomics, quality, and productivity simultaneously is likely to obtain sup po rt from most of the interest parties of the company, and may also enhance participation. Ergonomics has the potential of becoming a driving force for the development of new quality management strategies.