X-ray absorption spectroscopy studies of reactions of technetium, uranium and neptunium with mackinawite

Technetium, uranium and neptunium may all occur in the environment in more than one oxidation state (IV or VII, IV or VI and IV or V respectively). The surface of mackinawite, the first-formed iron sulfide phase in anoxic conditions, can promote redox changes so a series of laboratory experiments were carried out to explore the interactions of Tc, U and Np with this mineral. The products of reaction were characterised using X-ray absorption spectroscopy. Technetium, added as TcO4(-), is reduced to oxidation state IV and forms a TcS(2)-like species. On oxidation of the mackinawite in air to form goethite, Tc remains in oxidation state IV but in an oxide, rather than a sulfide environment. At low concentrations, uranium forms uranyl surface complexes on oxidised regions of the mackinawite surface but at higher concentrations, the uranium promotes surface oxidation and forms a mixed oxidation state oxide phase. Neptunium is reduced to oxidation IV and forms a surface complex with surface sulfide ions. The remainder of the Np coordination sphere is filled with water molecules or hydroxide ions.     

On the defensive behavior of the grass snake <Emphasis Type="Italic">Natrix natrix</Emphasis> (Linnaeus, 1758)

Demonstrative imitations in the defensive behavior of grass snakes (Natrix natrix) captured in the Galich’ya Gora Reserve (70 ind.) and Kulikovskii Forestry (13 ind.), Lipetsk oblast, have been analyzed using statistical methods. The results suggest that grass snakes can play dead and imitate a venomous snake independently of their sex, age, and experience in receiving injuries. At the same time, there is evidence that such an ability is a hereditary trait subject to natural selection.     

Animal Care Ethics, ANZCCART, and Public Perceptions of Animal Use Ethics

The public attitude to animal use in Australia and New Zealandcan be inferred from survey results and political activity. The publicis concerned about the rights of animals as far as any uses causing painare concerned, but takes a more utilitarian view of the taking of lifewhere no suffering is involved. Many of the participants in two recentANZCCART conferences fall short in their knowledge of and attitudetoward these concerns. Animal welfare legislation and standards need tobe reformed so that painful animal use is eliminated, even if economicgrowth suffers as a result.     

Integrated hydro- and wind power generation: a game changer towards environmental flow in the Sub-middle and Lower São Francisco River Basin?

Many renewable resources for the generation of electricity, such as hydropower and wind power, are dependent on climatic factors. Reservoirs have been created to overcome the stochastic nature of river flows and to make water supply more reliable. However, reservoirs are affecting the ecological status of river ecosystems, e.g., by modifying the flow regime, triggering discussions regarding the discharge of reservoirs. In Brazil’s northeast region, the installed capacity for wind power generation has increased substantially in recent years. Setting up a modeling system for simulating wind power and hydropower generation in this study, it is analyzed whether wind power generation, peaking in the dry season, can help to achieve a more environmentally oriented flow regime in the Sub-middle and Lower São Francisco River Basin. Simulated higher discharges from reservoirs during the rainy season and lower discharges during the dry season, representing a more natural flow regime, will reduce hydropower generation in the dry season. Under recent conditions, the resulting gap in electricity generation can only be partially covered by wind power. A large share needs to be generated by thermal power plants or be imported from other regions in Brazil. The planned future increase in installed wind power capacity can change this picture; the demand for electricity generated by thermal power plants and imported will decrease. Adopting an integrated approach for hydropower and wind power generation, the flow regime in the Sub-middle and Lower São Francisco River Basin can be modified to improve the ecological status of the river system.     

Evaluating the impact of green roof evapotranspiration on annual building energy performance

The performance of the building envelope predominantly determines the ultimate energy performance throughout the lifecycle of a building. A sustainable alternative to enhance roof performance while limiting heat flux through a roof is integrating passive techniques such as green roof. Particularly, green roof performance is sensitive to local climate. The main objective of this study was to evaluate the evapotranspiration effect of an extensive green roof on annual energy consumption of an office building in relation to the humid continental climate of Republic of Korea. The dynamic behavior of green roof and building energy performance were investigated through a parametric simulation method using green roof module in EnergyPlus coupled with jEPlus. Structural data of the reference building and ASHARE 90.1-2007 operational schedules were used as inputs for baseline building model while inputs for the green roof module were based on experimental data sets. Due to the influence of the humid conditions and local wind current on the evapotranspiration process, it was generally found that high leaf area index (LAI) reduced cooling energy demand and somewhat reduced heating energy demand as well; corresponding to the highest daily evapotranspiration fluxes of 4.79 mm day^?1 in summer and 1.80 mm day^?1 in winter. Increasing LAI from 20% to 100% cover increased evapotranspiration flux by 10.4% in summer and 80.2% in winter. Thus to minimize energy losses in winter, foliage cover must be carefully considered. Within limitations specified, the overall annual building energy consumption deceased by 90.9 GJ (3.7%).     

Knowledge for environmental governance: probing science–policy theory in the cases of eutrophication and fisheries in the Baltic Sea

How science and policy interact has been a major research focus in the International Relations (IR) tradition, using the epistemic community (EC) concept, as well as in the alternative perspective of Science and Technology Studies (STS). Should science be autonomous and as apolitical as possible in order to ‘speak truth to power’, as suggested by EC or should the inevitable entanglement of science and politics be accepted and embraced so as to make advice more conducive to negotiating the explicit travails of political decision-making as suggested by STS? With this point of departure, we compare similarities and differences between science–policy interactions in the issue areas of eutrophication and fisheries management of the Baltic Sea. To examine how knowledge is mobilised, the concepts of ‘uncertainty’ and ‘coherence’ are developed, drawing on both EC and STS thinking. We then reflect on the explanatory value of these approaches in both cases and discuss how a separation of science and policy-making in the pursuit of achieving scientific consensus leads to ineffectual policies. Drawing on STS thinking, we urge for a re-conceptualisation of coherence in order to accommodate a more reflexive practice of science–policy interactions.     

Northern Rivers Ecosystem Initiative: Nutrients and Dissolved Oxygen – Issues and Impacts

Anthropogenic inputs of nitrogen (N), phosphorus (P) and oxygen-consuming material to aquatic ecosystems can change nutrient dynamics, deplete oxygen, and change abundance and diversity of aquatic plants and animals. The Northern Rivers Ecosystem Initiative required a research and assessment program to establish the contribution of pulp mill and sewage discharges to eutrophication and depressions in dissolved oxygen (DO) in the Athabasca and Wapiti rivers of northern Alberta, Canada and examine the adequacy of existing guidelines for protecting these systems. Analysis of long-term data showed that total N (TN) and total P (TP) concentrations in exposed river reaches exceeded concentrations in reference reaches by ≤ 2 times for the Athabasca River, and by 9.6 (TP) and 2.6 (TN) times for the Wapiti River. Results from nutrient limitation experiments conducted in situ and in mesocosms showed that benthic algal production was nutrient sufficient downstream of pulp mill discharges but constrained in upper river reaches by insufficient P (Athabasca River) or N + P (Wapiti River). Dissolved oxygen (DO) concentrations in both rivers declined during winter such that median concentrations in the Athabasca River 945 km downstream of the headwaters were approximately 8 mg L⁻¹ in mid-February. Although water column DO rarely approached the guideline of 6.5 mg L⁻¹, DO studies undertaken in the Wapiti River showed that pore water DO often failed to meet this guideline and could not be predicted from water column DO. Results from this integrated program of monitoring and experimentation have improved understanding of the interactions between nutrients, DO and aquatic ecosystem productivity and resulted in recommendations for revisions to nutrient and DO guidelines for these northern rivers.The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright.     

Linking stream and landscape trajectories in the southern Appalachians

A proactive sampling strategy was designed and implemented in 2000 to document changes in streams whose catchment land uses were predicted to change over the next two decades due to increased building density. Diatoms, macroinvertebrates, fishes, suspended sediment, dissolved solids, and bed composition were measured at two reference sites and six sites where a socioeconomic model suggested new building construction would influence stream ecosystems in the future; we label these "hazard sites." The six hazard sites were located in catchments with forested and agricultural land use histories. Diatoms were species-poor at reference sites, where riparian forest cover was significantly higher than all other sites. Cluster analysis, Wishart's distance function, non-metric multidimensional scaling, indicator species analysis, and t-tests show that macroinvertebrate assemblages, fish assemblages, in situ physical measures, and catchment land use and land cover were different between streams whose catchments were mostly forested, relative to those with agricultural land use histories and varying levels of current and predicted development. Comparing initial results with other regional studies, we predict homogenization of fauna with increased nutrient inputs and sediment associated with agricultural sites where more intense building activities are occurring. Based on statistical separability of sampled sites, catchment classes were identified and mapped throughout an 8,600 km(2) region in western North Carolina's Blue Ridge physiographic province. The classification is a generalized representation of two ongoing trajectories of land use change that we suggest will support streams with diverging biota and physical conditions over the next two decades.     

Feasibility of ultraviolet-light-emitting diodes as an alternative light source for photocatalysis

The objective of this study was to determine whether ultraviolet-light-emitting diodes (UV-LEDs) could serve as an efficient photon source for heterogeneous photocatalytic oxidation (PCO). An LED module consisting of 12 high-power UV-A (lambda max = 365 nm) LEDs was designed to be interchangeable with a UV-A fluorescent black light blue (BLB) lamp for a bench scale annular reactor packed with silica-titania composite (STC) pellets. Lighting and thermal properties of the module were characterized to assess its uniformity and total irradiance. A forward current (I(F)) of 100 mA delivered an average irradiance of 4.0 mW cm(-2) at a distance of 8 mm, which is equivalent to the maximum output of the BLB, but the irradiance of the LED module was less uniform than that of the BLB. The LED and BLB reactors were tested for the oxidization of ethanol (50 ppm(v)) in a continuous-flow-through mode with 0.94 sec residence time. At the same average irradiance, the UV-A LED reactor resulted in a lower CO2 production rate (19.8 vs. 28.6 nmol L(-1) s(-1)), lower ethanol removal (80% vs. 91%), and lower mineralization efficiency (28% vs. 44%) than the UV-A BLB reactor. Ethanol mineralization was enhanced with the increase of the irradiance at the catalyst surface. This result suggests that reduced ethanol mineralization in the LED reactor relative to the BLB reactor at the same average irradiance could be attributed to the nonuniform irradiance over the photocatalyst, that is, a portion of the catalyst was exposed to less than the average irradiance. The potential of UV-A LEDs may be fully realized by optimizing the light distribution over the catalyst and utilizing their instantaneous "on" and "off" feature for periodic irradiation. Nevertheless, our results also showed that the current UV-A LED module had the same wall plug efficiency (WPE) of 13% as that of the UV-A BLB, demonstrating that UV-A LEDs are a viable photon source both in terms of WPE and PCO efficiency.