Development and validation of a thermally regulated atmospheric simulation chamber (THALAMOS): A versatile tool to simulate atmospheric processes

Atmospheric simulation chambers, are unique tools for investigating atmospheric processes in the gas and heterogeneous phases. They can provide a controlled yet realistic environment that simulates atmospheric conditions. In the current study, a Teflon atmospheric simulation chamber of 600 L, named THALAMOS (thermally regulated atmospheric simulation chamber) has been developed and cross-validated. THALAMOS can be operated over the temperature range 233 to 373 K under both static and flow conditions. It is equipped with state of the art instrumentation (selective ion flow tube mass spectrometry (SIFT-MS), long path Fourier transform infrared spectroscopy (FTIR), gas chromatography-mass spectrometry (GC-MS), various analyzers) for the in-line monitoring of both reactants and products. THALAMOS was validated by measuring the rate coefficients of well documented reactions, i.e. the reaction of ethanol with OH radicals and the reaction of dichloromethane with Cl atoms, in a wide temperature range. Two different detection techniques were used in parallel, FTIR and SIFT-MS, to internally cross-validate the obtained results. The measured rate coefficients are in excellent agreement, both between each other and with the literature recommended values. Furthermore, the gas phase oxidation of toluene by Cl atoms (kinetics and product yields) was studied in the temperature range of 253 to 333 K. To the best of our knowledge, THALAMOS is a unique facility on national level and among a few smog chambers internationally that can be operated in such a wide temperature range providing the scientific community with a versatile tool to simulate both outdoor and indoor physicochemical processes.     

A WATER RESOURCE PLANNING PROCEDURE FOR RURAL TOWNS1

ABSTRACT: Six new techniques have been developed for lake watershed analysis and water resource management. The techniques are for determining: (1) watershed land use intensity with reference to water quality, (2) lake vulnerability, (3) water quality, (4) watershed carrying capacity, (5) the economic value of the lake, and (6) the potential of undeveloped lake-shore. These analyses are designed for use by rural planning commissions with guidance and assistance from state agencies and the state university. The comprehensive rural watershed land and water use plan developed by this procedure is inexpensive in time and money, understandable by the layman, and scientificially sound. It is based on presently available information. This water resource planning procedure has been demonstrated in several town planning projects. It is suggested that this method, or modification of it, could be adopted in all rural states by action by a few administrators and without any new enabling or appropriations legislation.     

Comparative analysis of diffusion of the ISO 14001 standard by sector of activity

In recent years there have been many approaches to understand the cross-country diffusion rate of the most common environmental management standards issued by the International Organization for Standardization, the ISO 14000 series, due to their spectacular growth around the world, even though a certain saturation has been detected in some countries. However, few studies have shed light on the diffusion process of these standards across sectors of activity. Therefore, the present paper examines whether there are patterns of diffusion of the ISO 14001 standard that are singular at specific sectors of economic activity. The analysis was carried out using a logistic curve that fits quite well to explain the nature of this growth, and instability and concentration indexes were calculated to analyze the evolution of the rankings of the sectors attending the number of certifications ISO 14001. It concludes that the diffusion among sectors is quite homogeneous: all sectors have experienced similar behavior. Moreover, the article proposes some suggestions for future research.