Pheromone of the elm bark beetle Scolytus laevis (Coleoptera: Scolytidae): stereoisomers of 4-methyl-3-heptanol reduce interspecific competition

Stereoisomers of 4-methyl-3-heptanol (MH) are pheromone components of several Scolytus bark beetles. The elm bark beetle Scolytus laevis (Coleoptera: Scolytidae) has in previous studies been caught in traps baited with commercial MH containing all four stereoisomers, but the lure has been considered a weak attractant. In this study, we addressed the question whether stereospecific responses by S. laevis to stereoisomers of MH might contribute to its niche separation from other sympatric Scolytus species. Using GC–MS, we analyzed extracts of hindguts and abdomens from male and female S. laevis and the sympatric S. triarmatus. We also tested all four MH-stereoisomers individually and in combinations in the field to determine their role for S. laevis. All four stereoisomers were synthesized via a boronic ester method with 1,2-dicyclohexylethanediol as chiral director. In addition, the (3S,4R)-stereoisomer of MH was prepared through enantioselective, lipase-mediated transesterification of a mixture of the four stereoisomers of MH. Females of both species contained small amounts of syn-MH, and males contained trace amounts of anti-MH. The anti stereoisomer (3R,4S)-MH was attractive to male and female S. laevis, whereas the syn stereoisomer (3S,4S)-MH acted as an inhibitor or deterrent and reduced the catch when added to the attractive isomer. The syn isomer is the main aggregation pheromone component of the larger and sympatric S. scolytus and possibly also of S. triarmatus. The avoidance response of S. laevis to the (3S,4S)-stereoisomer may reduce interspecific competition for host trees.     

Environmental Management Systems and Co-operation in Municipalities

Due to the complex character of environmental issues there has been a call for change towards integration and co-operation on the development and environmental management scene. This holds true at all levels of society, from the global to the local. Due to cultural differences between different professions in municipalities, it may be hard to reach co-operation between different actors in municipal environmental management (MEM). Based on the present situation in Sweden in general and the municipality of Västera § s in particular, this paper discusses how co-operation in MEM may be promoted by the adoption of an environmental management system (EMS) in an entire municipality. Results from the study suggest that municipality-wide implementation of EMSs may help to bridge professional culture and language gaps. An EMS may provide the basis of a formal network that functions as a common platform and structure for environment-related discussion and work in different municipal authorities and companies, and thereby facilitate communication and co-operation among the actors in MEM.     

Negative emissions of carbon dioxide through chemical-looping combustion (CLC) and gasification (CLG) using oxygen carriers based on manganese and iron

Carbon capture and storage (CCS) is an economically attractive strategy for avoiding carbon dioxide (CO₂) emissions from, e.g., power plants to the atmosphere. The combination of CCS and biomass combustion would result in a reduction of atmospheric CO₂, or net negative emissions, as plant growth is a form of sequestration of atmospheric carbon. Carbon capture can be achieved in a variety of ways, one of which is chemical looping. Chemical-looping combustion (CLC) and chemical looping gasification (CLG) are two promising technologies for conversion of biomass to heat and power or syngas/methane with carbon capture. There have been significant advances made with respect to CLC in the last two decades for all types of fuel, with much less research on the gasification technology. CLG offers some interesting opportunities for production of biofuels together with carbon capture and may have several advantages with respect to the bench mark indirect gasification process or dual-bed fluidized bed (DFBG) in this respect. In CLG, an oxygen carrier is used as a bed material instead of sand, which is common in indirect gasification, and this could have several advantages: (i) all generated CO₂ is present together with the syngas or methane in the fuel reactor outlet stream, thus in a concentrated stream, viable for separation and capture; (ii) the air reactor (or combustion chamber) should largely be free from trace impurities, thus preventing corrosion and fouling in this reactor; and (iii) the highly oxidizing conditions in the fuel reactor together with solid oxide surfaces should be advantageous with respect to limiting formation of tar species. In this study, two manganese ores and an iron-based waste material, LD slag, were investigated with respect to performance in these chemical-looping technologies. The materials were also impregnated with alkali (K) in order to gauge possible catalytic effects and also to establish a better understanding of the general behavior of oxygen carriers with alkali, an important component in biomass and biomass waste streams and often a precursor for high-temperature corrosion. The viability of the oxygen carriers was investigated using a synthetic biogas in a batch fluidized bed reactor. The conversion of CO, H₂, CH₄, and C₂H₄ was investigated in the temperature interval 800–950 °C. The reactivity, or oxygen transfer rate, was highest for the manganese ores, followed by the LD slag. The conversion of C₂H₄ was generally high but could largely be attributed to thermal decomposition. The K-impregnated samples showed enhanced reactivity during combustion conditions, and the Mangagran-K sample was able to achieve full conversion of benzene. The interaction of the solid material with alkali showed widely different behavior. The two manganese ores retained almost all alkali after redox testing, albeit exhibiting different migration patterns inside the particles. LD slag lost most alkali to the gas phase during testing, although some remained, possibly explaining a small difference in reactivity. In summary, the CLC and CLG processes could clearly be interesting for production of heat, power, or biofuel with negative CO₂ emissions. Manganese ores are most promising from this study, as they could absorb alkali, giving a better conversion and perhaps also inhibiting or limiting corrosion mechanisms in a combustor or gasifier.

     

Spatial characterization of the Baltic sea drainage basin and its unmonitored catchments

We present an updated, harmonized hydrologic base map of the entire Baltic Sea Drainage Basin (BSDB), including 634 subdrainage basins. The updated map has a level of detail approximately 5 to 10 times higher than the current standard and includes various spatial-aggregation possibilities of relevance for water management. All 634 subdrainage basins and their various spatial aggregations are characterized in terms of population, land cover, drainage density, and slope. We identify, quantify, and characterize, in particular, drainage basins that are unmonitored with regard to the combination of water-flow and nutrient-concentration measurements needed to monitor coastal nutrient and pollutant loading. Results indicate that out of a total BSDB population of 84 239 000 in 2002, 24% lived in unmonitored coastal drainage basins that cover 13% of the total BSDB area. A more detailed analysis of Swedish catchments indicates that Sweden has a particularly large proportion of unmonitored coastal catchment areas (20% of the total Swedish area) with high population pressures (55% of the total Swedish population), when compared with average conditions for the whole BSDB. In general, the investigated characteristics of unmonitored coastal basins vary and differ largely from those in adjacent monitored drainage basins within the BSDB.     

Immersed solid phase microextraction to measure chemical activity of lipophilic organic contaminants in fatty tissue samples

It is known that solid phase microextraction (SPME) fibers can be equilibrated directly within environmental matrices such as water, sediment and soil slurries. Here it is shown that this method can also be applied to biological tissue. SPME extraction of biological matrices reportedly causes lipophilic fouling of the fiber. However, we found no significant measurement bias when combining equilibrium sampling with fiber surface cleaning. The uptake of lipophilic organic pollutants from the tissue and into the SPME fiber coating was characterized by fast equilibrium partitioning without sample depletion and without impacting the sorptive properties of the fiber. The precision of the method when applied to hexachlorobenzene and several PCB congeners in harbor porpoise blubber was 15%, which includes the variation between SPME samplings, manual injections and the instrumental analysis. A good correlation (r(2)=0.95) was obtained between SPME measurements of PCB 153 in blubber and concentrations obtained via a traditional analytical approach. These results indicate that SPME is a promising technique for measuring chemical activity in biological tissue, which would make it a useful tool for studying chemical distribution in organisms as well as biodilution and biomagnification phenomena.     

Searching efficient protection strategies for the eutrophied Gulf of Finland: the combined use of 1D and 3D modeling in assessing long-term state scenarios with high spatial resolution

An experiment combining the use of two ecosystem models was conducted to search for effective protection strategies for the Gulf of Finland (Baltic Sea). Reference and scenario simulations were first run with a one-dimensional (1D) model for seven main basins of the entire Baltic Sea until steady state was achieved. The obtained basinwise distributions of inorganic nitrogen (N) and phosphorus (P), as well as sediment labile P, were then used to initiate 5-y simulations with a three-dimensional (3D) ecosystem model. The results suggest that relatively small local load reductions (the "Finland" scenario) would improve only the state of adjacent coastal waters significantly. This would be the case, even for runs covering several decades, which clearly exceed the residence times of nutrients in the Gulf of Finland. A significant decrease from a substantial loading source to the Gulf (the "St. Petersburg" scenario) would decrease cyanobacterial biomasses in the entire Gulf of Finland and also immediately outside it. A reduction in the current Polish nutrient loads would improve the situation in the whole Baltic Proper and cause an extensive decline in cyanobacterial biomasses in the Gulf of Finland, as well. However, it would take several decades until the improvement caused by reducing loads in the "Poland" scenario is seen, while in the "St. Petersburg" scenario the corresponding time lag would only be a few years. Our results suggest that the common water protection policy in the Baltic Sea region should have the largest nutrient sources as its primary target, regardless of their location and country.     

Animal community structure and energy budget calculations of a Daphnia magna (straus) population in relation to the rock pool environment

The fauna and environmental conditions in a freshwater rock pool ecosystem were followed by a weekly quantitative sampling program from April to August, 1974. The rock pool, situated on a small island in the northern Baltic Sea, was heavily eutrophicated by droppings from the surrounding colony of sea birds. The intermittent flushing of the pool with rainwater and the input of bird droppings, as well as the biological activity, contributed to the large seasonal variations in nutrients and organic matter that were observed. A dense algal bloom of flagellates occurred in April but vanished when the animal population started to increase in the middle of May. During the rest of the summer, most of the photosynthetic pigments were found in the bottom sediment, mostly as degraded phaeo-pigments due to intensive grazing by the animals in the pool. Very few animal taxa were found and the phyllopod Daphnia magna (Straus) dominated throughout the whole sampling period. D. magna contributed to more than 50% of the total biomass, except in late July when chironomid larvae were most abundant. The total biomass in the pool increased from about 15 mg (dry weight) l^?1 in May to a maximum of about 60 mg l^?1 at the end of June. There were few carnivores in the system, except during the spring when the water bug Deronectes griseostriatus (de Geer) was common.Analyses of size, age and sex structure and calculations of birth and death rates of the D. magna population showed large seasonal variations, correlated with the volume fluctuations and flushings of the pool which stimulated both the algal production and the growth and reproduction of Daphnia. Data from the extensive literature that exists on D. magna and other species of the same genus were used, together with field and experimental data from the rock pool population, in a numerical model describing the energy budget of this species. The model describes variations in weight-specific growth, reproduction, moulting, feeding and respiration rates in relation to temperatures and food concentrations. Energy budget relationships that maximise the chances for survival and utilisation of the available energy for a population exposed to varying food concentrations are predicted by the model. The energy budget model was also used to estimate the secondary production of the rock pool population of D. magna. The total production between April and August was 203 mg (dry weight) l^?1 and the average production per biomass ratio was 0.094 day^?1. The average net production efficiency was 42%, very close to other values reported for D. magna from other biotopes. The relative importance of different factors controlling the production was also analysed with the model. Production per biomass ratio was calculated, assuming a constant temperature and/or food concentration for the whole sampling period. The varying food concentrations in the rock pool had the most pronounced influence, greater than that of temperature and size structure variations in the population.     

Utilisation of steel slags as neutralising agents in biooxidation of a refractory gold concentrate and their influence on the subsequent cyanidation

A study on the possibilities to utilise steel slag as neutralising agent in biooxidation of a refractory gold concentrate has been done with reference to commercial grade slaked lime. The idea has been to reduce the operating costs for neutralisation in the biooxidation plant, which is known to be the second largest operating cost. Other benefits would be savings in cost for landfilling of slag, possibilities to recycle elements present in the slag and savings of virgin limestone deposits. The slags used were an EAF slag and a slag from ladle refining; both originating from Swedish scrap based steel-making. Continuous biooxidation of the refractory gold concentrate was conducted in a single-stage 5 L reactor at a retention time of 56 h. The neutralisation capacity was determined by comparing the amount needed, per ton of feed concentrate added, to maintain the desired pH of 1.5 during steady state operation. Slaked lime had the highest neutralisation capacity with 110 kg/ton feed followed by ladle slag and EAF slag with values of 152 and 267 kg/ton feed, respectively. Sulphide mineral oxidation was similar and high in all cases although the ladle slag results were slightly better. Gold recoveries after cyanide leaching on the residues obtained were also similar and were in the range of 86-89%. However, the cyanide consumption expressed as kilogram cyanide per ton of concentrate fed to biooxidation, was double in the case of ladle slag and three times as much for the EAF slag compared to the slaked lime experiment. The increased cyanide consumption could not be explained only by the increased amount of elemental sulphur obtained in the slag experiments. The elemental sulphur formed had different reactivities as seen from the thiocyanate formation and cyanide losses due to thiocyanate formation were 16%, 32% and 40% for EAF slag, slaked lime and ladle slag, respectively. It is concluded that the ladle slag could be a possible replacement for limestone if they are mixed in proper proportions so that the microbial carbon dioxide demand is met whereas the EAF slag is less suitable due to the very fine reaction products obtained which gave operational problems with filtration and washing. To come further, experiments with the normal multi-stage biooxidation set-up with total retention time of 120 h should be performed which would increase the sulphur oxidation and eventually also reduce the cyanide consumption.