Growth and Cd accumulation of two halophytes and a non-halophyte grown in a non-saline and a saline soil with different Cd levels

Two halophytes, Salicornia europaea and Atriplex verucifera, and the non-halophyte Chenopodium album were grown in pots on sodic and non-sodic Iranian soils spiked with up to 100 mg Cd kg^?1. The halophytes grew best on the sodic soil in the absence of Cd spiking, while C. album performed better on non-sodic soil. Cadmium spiking reduced the growth of all plants, with Cd tolerance decreasing in the order S. europaea>A. verucifera>C. album. The observed order of Cd tolerance corresponds to the abilities of the plants to tolerate sodic soil properties. The variation of Cd concentration in shoots in response to sodicity was related to different mechanism, including dilution (C. album) Cd solubilisation by Ca²⁺ (S. europea) and Ca²⁺ competition for uptake and translocation of Cd (A. verucifera). Improved understanding of these complex interactions will help to design phytoextraction technology for Cd-polluted soils in arid regions.     

Characterization of Shredder Residues generated and deposited in Denmark

This study presents a detailed characterization of Shredder residues (SR) generated and deposited in Denmark from 1990 to 2010. It represents approximately 85% of total Danish SR. A comprehensive sampling, size fractionation and chemical analysis was carried out on entire samples as well as on each individual size fraction. All significant elemental contents except oxygen were analyzed. The unexplained “balance” was subsequently explained by oxygen content in metal oxides, carbonates, sulphates and in organics, mainly cellulose. Using mass and calorific balance approaches, it was possible to balance the composition and, thereby, estimate the degree of oxidation of elements including metals. This revealed that larger fractions (>10 mm, 10–4 mm, 4–1 mm) contain significant amount of valuable free metals for recovery. The fractionation revealed that the >10 mm coarse fraction was the largest amount of SR being 35–40% (w/w) with a metal content constituting about 4–9% of the total SR by weight and the <1 mm fine fraction constituted 27–37% (w/w) of the total weight. The lower heat value (LHV) of SR samples over different time periods (1990–2010) was between 7 and 17 MJ/kg, declining with decreasing particle size. The SR composition is greatly dependent on the applied shredding and post shredding processes at the shredding plants causing some variations. There are uncertainties related to sampling and preparation of samples for analyses due to its heterogeneous nature and uncertainties in the chemical analyses results (≈15–25%). This exhaustive characterization is believed to constitute hitherto the best data platform for assessing potential value and feasibility of further resource recovery from SR.     

Future waste treatment and energy systems – examples of joint scenarios

Development and use of scenarios for large interdisciplinary projects is a complicated task. This article provides practical examples of how it has been carried out in two projects addressing waste management and energy issues respectively. Based on experiences from the two projects, recommendations are made for an approach concerning development of scenarios in projects dealing with both waste management and energy issues. Recommendations are given to develop and use overall scenarios for the project and leave room for sub-scenarios in parts of the project. Combining different types of scenarios is recommended, too, in order to adapt to the methods and tools of different disciplines, such as developing predictive scenarios with general equilibrium tools and analysing explorative scenarios with energy system analysis tools. Furthermore, as marginals identified in differing future background systems determine the outcomes of consequential life cycle assessments (LCAs), it is considered advisable to develop and use explorative external scenarios based on possible marginals as a framework for consequential LCAs. This approach is illustrated using an on-going Danish research project.     

Use of life cycle assessment as decision-support tool for water reuse and handling of residues at a Danish industrial laundry.

This analysis presents the results of a life cycle assessment (LCA) carried out on six alternative options for the recycling of water at a Danish industrial laundry for workwear. The study focuses on the handling and disposal of the wet residues generated when wastewater is treated for recycling, and in accounting for long-term potential toxicity impacts. The analysed options are a combination of two water-upgrading technologies: biofilter and ultrafiltration, and three residue disposal alternatives: biogas followed by incineration of sludge at local wastewater treatment plant, thermal vitrification treatment for production of vitrified sand, and mineralization in a sludge bed. It is concluded from the results that with the current Danish environmental policy priorities, the environmental impacts of highest priority are the toxicity effects derived from the presence of heavy metals in the residues. Heavy metals originate from the dirt in the workwear that is washed in the laundry. It is further concluded that the studied water treatment technologies satisfy both the need of clean water for recycling and simultaneously help controlling a safe disposal of pollutants by concentration of the residues. The results of the study also confirm the potential of LCA as a decision-support tool for assisting water recycling initiatives and for residue handling management. The handling of residues has been identified as a stage of the water recycling strategy that bears important environmental impacts. This holistic perspective provided by LCA can be used as input for the definition of environmental management strategies at an industrial laundry, and the prioritization of investments to the environmental profile of laundry processes. In this case-study, the results of the LCA are made operational by, for example, selecting the water treatment technology which is associated wih a safe disposal of the wet residue. It is important to bear in mind that such prioritization depends on national boundary conditions. In the case study analysed, the boundary conditions steer the weighing of the environmental impacts, following the current Danish environmental policy priorities.     

Ökologische Situation der Region Leipzig-Halle

Air pollution in the region Leipzig-Halle was investigated using two-year-old pine needles (Pinus sylvestris L.) at 39 sites of a biomonitoring net covering an area of ca. 7 500 km². The concentration values of Al, Ca, Cr, Fe, K, Mg, Mn, Pb and V characterize the immission patterns of the period 1990/91. The method is less suited for Cu, Ni and Zn due to the transfer route soil-pine, and for Cd due to the small total content. There are significant spatial and element-specific variations which require distinct evaluation of the pollution situation. The city of Leipzig itself is a significant source for Pb, Cr, Fe and V emission. Mainly as far as the centre of the region is concerned, the Pb concentration values are beyond those of heavily contaminated reference sites. The bioindication system is also applicable for comparable regions in Eastern Europe where the pine is the dominating conifer type. Immission trends can be monitored over ecologically relevant periods of time.