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31.
Alkyl nitrates with chain lengths up to fourteen carbons have been detected in the remote troposphere of the South Atlantic Ocean. The concentrations of numerous iso- and n-alkyl nitrates in the range of C3-C12 have been measured. Tenax-GC analysis was applied to determine short chain alkyl nitrates (< C6), while the novel detection of long chain iso- and n-alkyl nitrates was achieved with a high volume sampling technique using silica gel. C3-C12-alkyl nitrates show the lowest concentrations in the trade wind region (3.5 pptv). Higher concentrations in the west wind belt (11.1 pptv) reveal the influence of the South American continent as the source for the alkyl nitrates after long range transport. The concentrations of alkyl nitrates increase in proximity to South America. Measurements of long chain alkyl nitrates in rural air near the city of Ulm (Germany) are given for comparison. In addition, pattern analysis of long chain alkyl nitrates reveal this complex mixture of new compounds to be useful as trace indicators to distinguish continental and marine air masses. Despite the lower photochemical formation yields of primary n-alkyl nitrates compared to secondary n-alkyl nitrates, the primary n-alkyl nitrates are relatively increased in marine air. The reason for this finding cannot be explained so far, but the correlation of secondary/primary n-alkyl nitrates shows a significant differentiation of air samples with continental or marine character. 相似文献
32.
Dirk Bunke Wolfgang Reuter Frank Ebinger Ismene Jäger Klaus Schneider 《Environmental Sciences Europe》2003,15(3):208-212
Background
Aim and Scope. Implementation of the European Union White Paper on chemicals policy shall provide more safety and more transparency in chemicals use. In the past, when assessing existing commercial substances there was often a lack of information in the fields of application of the chemicals and the exposures arising in those contexts. The White Paper therefore calls for ‘shared responsibility’. Processors and commercial users of substances are to be involved much more closely in the risk evaluation process than has hitherto been the case. They are to provide data on substance applications and exposures, and, to some extent, they are also to carry out exposure assessments and risk assessments themselves. By analysing case studies, the paper highlights the consequences of this approach.Results and Discussion
Fear has often been voiced that these new tasks will completely overburden small and medium-sized enterprises. It is assumed that many chemicals are no longer available for smallvolume applications, as — for cost reasons — producers do not include these applications in their registration. The wording of the White Paper is not precise enough to be able to appraise the costs that will be associated with the required intensified communication. In this situation, it is essential to analyse prototypical substances and their applications in order to gain an improved understanding of the principle of shared responsibility.Conclusions
The concrete study of several product chains has shown that the flow of information required between producers and users is very likely feasible within the context of the REACH system. For the producers of chemicals, the intensified communication will presumably make it simpler to procure information in the fields of application and exposures. However, in order to avoid users being overburdened, it will be important that registration requirements and focuses are shaped in a manner doing justice to practical realities. Users will need to undertake community-wide efforts on an industry federation and branch level. In this context, the protection of company know-how also needs to be ensured.Recommendation and Outlook
In practice, implementation of the principle of shared responsibility can lead to intensified communication among the producers and users of chemicals. This can greatly facilitate exposure assessments and risk assessments. There is a need to develop manageable procedures that can also be implemented by small and medium-sized enterprises. Numerous proposals have been made in this context, and extensive reference material is now available. 相似文献33.
Correlating turbulent burning velocity to turbulence intensity and basic flame parameters-like laminar burning velocity for dust air mixtures is not only a scientific challenge but also of practical importance for the modelling of dust flame propagation in industrial facilities and choice of adequate safety strategy. The open tube method has been implemented to measure laminar and turbulent burning velocities at laboratory scale for turbulence intensities in the range of a few m/s. Special care has been given to the experimental technique so that a direct access to the desired parameters was possible minimising interpretation difficulties. In particular, the flame is propagating freely, the flame velocity is directly accessible by visualisation and the turbulence intensity is measured at the flame front during flame propagation with special aerodynamic probes. In the present paper, those achievements are briefly recalled. In addition, a complete set of experiments for diametrically opposed dusts, starch and aluminium, has been performed and is presented hereafter. The experimental data, measured for potato dust air mixtures seem to be in accordance with the Bray Gülder model in the range of 1.5 m/s<u′<3.5 m/s. For a further confirmation, the measurement range has been extended to lower levels of turbulence of u′<1.5 m/s. This could be achieved by changing the mode of preparation of the dust air mixture. In former tests, the particles have been injected into the tube from a pressurised dust reservoir; for the lower turbulence range, the particles have been inserted into the tube from above by means of a sieve–riddler system, and the turbulence generated from the pressurised gas reservoir as before. For higher levels of turbulence, aluminium air mixtures have been investigated using the particle injection mode with pressurised dust reservoir. Due to high burning rates much higher flame speeds than for potato dusts of up to 23 m/s have been obtained. 相似文献
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35.
The theory of neighbourhood decline due to pariah land uses: Regaining control of the downward cycle
Some neighbourhood environments have become dumping grounds for locally unwanted land uses (LULUs) that middle-class Americans do not want near their homes. LULUs may combine with other pariah land uses to collectively undermine the quality of the local environment, reduce investment, government services, the proportion of middle-income people and associated businesses. As important neighbourhood attributes are lost, illegal activities, derelict structures, trash-strewn lots and the concentration of poor and unhealthy people may increase. This paper describes the theory behind the impact of pariah land uses through examples of the downward spiral experienced by Camden, New Jersey and the south Bronx, New York. It then documents the experience of one community, Elizabethport, New Jersey, in reversing that downward spiral. Success in Elizabethport came from the synergistic activities of local, state and federal governments, community groups, and not-for-profit organizations as they struggled to regain control through local environmental management, rebuilding, and reducing crime. Social capital was also strengthened by using a local community health concern—that of childhood asthma. Efforts to reverse the downward spiral of urban decay from pariah land uses should be multi-faceted, spurred by local efforts that address local concerns. 相似文献
36.
A method was developed for the risk assessment of a military waste site. The method consists of two steps: 1. evaluation of the exposure through different pathways and 2. derivation of substance-specific tolerable intake levels. In this first part of the paper the quantitative exposure analysis will be discussed. Exposure depends on the conditions at the contaminated site (e.g. soil characteristics), the type of utilisation (residential area, industrial area etc.) and the substance properties. In a specific utilisation scenario, e.g. as residential area, different exposure pathways are contributing to the total contaminant uptake. Because of the properties of nitroaromatic compounds like 2,4,6-trinitrotoluene (good resorption through skin and accumulation in plants) exposure via dermal soil contact and via consumption of plants gains special importance. With these two exposure pathways as examples we explain the quantification of the exposure through different pathways by so-called exposure factors. By comparing the total exposure with tolerable intake levels for the compounds, waste site specific soil pollutant levels can be established (see second part of the paper in UWSF 6/94). 相似文献
37.
Friedhelm Schroeder 《Environmental Modeling and Assessment》1997,2(1-2):73-82
A simple zero‐dimensional model was developed which describes the oxygen concentrations and major nutrient processes in the tidal influenced Elbe estuary. The model was calibrated by way of comparison with continuous measurements of the oxygen‐ and chlorophyll concentrations at the non‐tidal part of the estuary. A special calibration method was applied which utilised the fact that natural steady‐state conditions are often found during which the range and the average value of the day–night fluctuations remain constant over a period of several days. Subsequent model runs were carried out to simulate the oxygen concentrations downstream, i.e., after a few days of transport time of the water body. The varying depth of the Elbe downstream of Hamburg harbour was taken into account by altering the model parameters ‘light penetration’ and ‘aeration’. The oxygen concentrations resulting from the model showed a distinct minimum, which agreed well with the minimum measured in longitudinal profiles, thus indicating that the occurrence of the oxygen minimum in the Elbe estuary can mainly be explained by the processes included in our simple model. Sensitivity checks identified some relationships, e.g., light intensity ? growth rate, which are critical for the oxygen balance. With this work it could be demonstrated that even simple zero‐dimensional models can improve our understanding of the complex interrelationship of different physical, chemical and biological processes in rivers and that such models can be used for simple scenarios in water quality management. 相似文献
38.
François Schneider 《Journal of Cleaner Production》2010,18(6):600-602
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