Occurrence of dissolved PAHs in the Jinsha River (Panzhihua)--upper reaches of the Yangtze River,Southwest China

16 priority polycyclic aromatic hydrocarbons (PAHs) were determined in water samples from the Jinsha River (Panzhihua part), Southwest China. Total dissolved PAH concentrations varied from 21.89 microg l(-1) to 382.8 microg l(-1). It was found that the concentration of PAHs decreased along the flow direction due to the higher density distribution of coal chemical industry in the upstream of our study rivers. The pollution levels in our study area are significantly higher than previously reported values in other waters both in China and other countries. The predominance of benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene was clearly observed in all water samples. On average these two compounds accounted for 98.3% of the total dissolved PAH concentration in water. The results showed the positive correlations among total dissolved PAHs, benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene, which suggested that these two predominant PAHs have similar source and environmental behaviors in our study area. When compared with the survey results of organic micropollutants two decades ago, it was found that hydrocarbon pollution both predominated and even increased with the development of coal chemical industry in this area during the past 20 years. The results therefore provide important information on the current contamination status of a key industrial city in China, and points to the need for urgent action to investigate the relationship between the PAH composition and concentration in water from the Jinsha River and the wastewater discharge from coal chemical industry, and to identify the source, transport pathway and fate of PAHs in the area. It should then be necessary to adopt appropriate and instant measures to control the pollution around this area.     

Adsorption of zinc on manganite(γ-MnOOH): particle concentration effect and adsorption reversibility

The adsorption and desorption processes of Zn(Ⅱ) on τ-MnOOH as a function of particle concentrations (Cp) were studied. An obvious Cp effect was observed in this adsorption system. The degree of adsorption hysteresis increased greatly with the increasing of Cp, indicating that the extent of the real metastable-equilibrium states deviating from the ideal equilibrium state was enhanced with the increasing of Cp. The Cp-reversibility relationship confirmed the metastable-equilibrium adsorption (MEA) inequality (Pan, 1998a), which was the core formulation of the MEA theory. Because the MEA inequality was based on the basic hypothesis of MEA theory that adsorption densitιy ι is not a state variable, the Cp-reversibility relationship gave indirect evidence to the basic hypothesis of MEA theory.     

内蒙古发展循环经济的方向与政策初探

本文从内蒙古资源、经济与环境问题现状出发，分析了发展循环经济的必要性、紧迫性和可行性，提出了我区建立循环经济的发展战略应考虑的基本原则，发展方向和法律、政策方面的建议。     

硫酸法钛白生产水洗工序清洁生产技术初探

通过开展水洗工段用水审计并试验了温度、偏钛酸ξ电位和漂白工艺对水洗的影响效果，从实践和理论上探讨了为其提高钛白质量改进水洗工艺的清洁生产方案的可行性和合理性。     

废醋酸锌催化剂回收醋酸锌工艺研究

对从废醋酸锌催化剂中浸取醋酸锌进行了实验研究,考察了废催化剂颗粒大小,浸取剂种类和用量、温度和浸取时间等因素对醋酸锌浸取率的影响。     

21世纪水处理厂考察报告

评介了美国 2 1世纪水处理厂处理和回收城市污水的总体方案、处理工艺、处理效果、处理水应用以及所取得的环境效益、社会效益和经济效益 ,其建厂目的体现了美国治理环境的战略思想 ,其工艺、装备和整体技术代表了美国环境污染综合整治的先进水平 ,有值得借鉴之处。     

利用混合C9重芳烃回收磺酸盐装置的技术经济分析

介绍了回收磺酸盐生产工艺 ,对其装置的产品成本进行了测算 ,并对盈亏平衡及其敏感性进行了分析 ,进而确定了主要经济指标。     

CFB锅炉燃烧高硫石油焦的灰渣综合利用研究

循环流化床锅炉在燃烧含硫石油焦时,通过加入石灰石在燃烧的过程中以固态的形式脱硫,燃烧后将产生大量的灰渣,过去处理灰渣最通常的方式是作土地填埋。从灰渣的化学、物理特性试验研究出发,寻找循环流化床灰渣在建筑材料、农业应用和水泥添加剂方面的利用途径,研究了更加经济有效的灰渣处理方法。     

薄壁深孔件拉深过程的数值模拟

利用上限元技术(UBET)模拟出薄壁深孔件在变薄拉深成形过程中，几种主要工艺参数对断裂的影响程度，由此得出防止断裂产生的措施。     

铜、锌和锰抑制月形藻生长的毒性效应

运用评价化学品毒性藻类测试的标准实验方法，得到铜、锌和锰对月形藻生长的最小无显著差异浓度（LNOEC）分别为31.8μg/L、16.4μg/L和2.7mg/L，抑制月形藻生长的96h半效应浓度（96h-EC50)分别为199.5μg/L、38.0μg/L和12.6mg/L。实验结果表明无论从LNOEC还是从96h-EC50考虑，都证明抑制月形藻生长的毒性由大到小的顺序是锌＞铜＞锰。此结果对铜抑制藻类生长的毒性远远大于锌的毒性这一人们普遍认同的观点构成挑战。月形藻细胞壁表面可能含有较少的硫代基团但包含较多与锌有很强结合能力的官能团可能是导致月形藻对铜的敏感性弱而对锌敏感性强的主要原因。