基于新环境保护法要求下的化工园区水环境管理政策

从园区的规划布局、监督管理、废水处理及排放标准等方面对化工园区水污染问题的成因进行了系统分析,并结合新修订的《环境保护法》和《水污染防治行动计划》的有关要求,分别从四个方面针对化工园区水污染防治政策提出以下建议：加强管理顶层设计,促进协调监管;严格园区环境准入条件;实行企业废水分质分类管理,加强企业准入标准建设;建立激励机制,推动第三方服务。     

污水再生处理工艺中卡马西平的去除过程模拟及其生态风险评价

卡马西平在污水和水环境中广泛存在,且对水生生态系统安全构成风险,因此成为目前研究较多的药品之一。以北京清河再生水厂为例,研究"超滤—臭氧氧化—氯消毒"处理工艺中卡马西平的去除特性,并针对臭氧氧化和氯消毒工艺建立模拟卡马西平去除过程的机理模型。同时,利用美国环境保护署ECOTOX数据库,获取卡马西平对北京市水生生物物种的毒性数据,并基于毒性数据建立物种敏感度分布(species sensitivity distribution,SSD)模型,评价再生水厂出水补给地表水体时卡马西平产生的生态风险。臭氧氧化和氯消毒模型对卡马西平、总有机碳、氨氮等指标的模拟误差总体低于20%,模型的灵敏参数均可以被较好地识别,且其不确定性显著下降。对比7种SSD模型发现,对数正态分布和对数Logistic分布模型较好地拟合了北京市6个物种的卡马西平毒性数据,二者预测得到的总体生态风险期望值分别为7.4%和8.5%。     

物种敏感度分布(SSD)方法在农药环境风险评估中的应用

物种敏感度分布法(Species Sensitive Distribution,SSD)能够依据不同物种对农药等胁迫因素的敏感度服从一定的累积概率分布,以统计形式将多种非靶标物种的实验室数据进行汇总分析,获得物种对农药的敏感度差异,作为效应评估指标应用于农药风险评估。本文综述了SSD概念、方法原理、国内外研究和应用进展,并以毒死蜱为例进行了数据分析。由此建议继续关注国际上对SSD及更复杂模型模拟研究进展,以便应用于我国农药环境风险评估,推动我国农药管理的持续发展。     

Characterization and speciation of mercury in mosses and lichens from the high-altitude Tibetan Plateau

The accumulation and species of mercury (Hg) in mosses and lichens collected from high-altitude Tibetan Plateau were studied. The altitudes of the sampling sites spanned from 1983 to 5147 m, and a total of 130 mosses and 52 lichens were analyzed. The total mercury (THg) contents in mosses and lichens were in the ranges of 13.1–273.0 and 20.2–345.9 ng/g, respectively. The average ratios of methylmercury (MeHg) in THg in mosses and lichens were 2.4 % (0.3–11.1 %) and 2.7 % (0.4–9.6 %), respectively, which were higher than those values reported in other regions. The contents of THg in both mosses and lichens were not correlated with the THg in soils (p > 0.05). The lipid contents displayed a significantly positive correlation with concentrations of MeHg in mosses (r = 0.461, p < 0.01, n = 90), but not in lichens. The correlations between Hg contents in mosses and the altitudes, latitudes and longitudes of sampling sites indicated the mountain trapping and spatial deposition of Hg in the Tibetan Plateau.     

Novel approach for in situ recovery of cobalt oxalate from spent lithium-ion batteries using tartaric acid and hydrogen peroxide

Journal of Material Cycles and Waste Management - Recycling Co resource from spent lithium-ion batteries (LIBs) is significant for Co deficiency and environmental protection. A novel approach for...     

剩余活性污泥和厨余垃圾续批式混合中温消化试验研究

将加碱水解和未水解剩余活性污泥与厨余垃圾混合后进行序批式中温厌氧消化,对生化产甲烷势(BMP)进行了测定.剩余活性污泥的水解通过添加NaOH进行,合理的NaOH投量为40 mmol/L,在25 ℃和35 ℃下经过6 h的水解后SCOD水解率分别提高27.4%和31.1%.厨余垃圾、25℃和35℃下水解污泥的最终甲烷产量分别为607、284、312 mL/g(VS),两种水解污泥比未水解污泥分别高出43%、57.6%,水解污泥和厨余垃圾混合消化的可降解能力要优于未水解污泥和厨余垃圾的混合进料.     

Use of Remote-Trip Cameras for Wildlife Surveys and Evaluating the Effectiveness of Conservation Activities at a Nature Reserve in Sichuan Province,China

Monitoring the effectiveness of management activities within reserves is always a complicated task. When the focus of management activities is mammals, it is difficult to monitor their populations in a way that is rapid, effective, and inexpensive. We report on a mammal survey of a reserve in southwest China using remote-trip cameras. We surveyed 329 locations over 2 field seasons in 2002 and 2003. Sixteen species of mammals were detected with these cameras, with four species documented for the first time. After accounting for variation due to slope, aspect, elevation, and habitat type, the distribution of six species was positively associated with the location of conservation stations and/or patrolling routes. Species of medium-sized mammals are excellent candidates for monitoring programs based on these cameras, due to their relative abundance, sufficient size to be detected by the camera units, and sensitivity to human activity. The distribution of mammals relative to management efforts is a relatively rapid means to assess reserve effectiveness. The repeat use of the cameras as part of a monitoring plan should provide a quantifiable measure of reserve effectiveness.     

湿法喷雾脱硫塔内雾化器的应用

雾化器是湿法喷雾脱硫的关键部件,本文结合具体工程实例,论述了脱硫塔内雾化器的平面布置和塔内空间立面的设计,以及常见的一些问题。为保证稳定的脱硫效率,必须正确设计雾化器组合件,合理选择雾化器的型号和材料,以及正确的安装和维修方法。     

斜网-混凝沉淀-A/O工艺处理白卡纸废水

采用斜网+混凝沉淀+A/O工艺处理白卡纸废水,平均CODCr去除率为97·9%,平均SS去除率为99·1%,出水各项指标达到《造纸工业水污染物排放标准》(GB3544-92)一级标准。以斜网装置回收废浆,过水量5~12m3/(m2·h),CODCr去除率52·8%,SS去除率53·7%。回收纤维获益相当于每吨纸节省成本33元,占总成本的2·5%。将剩余污泥回流到沉淀反应池,可降低投药量,节约总运行费用25%,并能减轻二次污染。     

北京市环境电磁辐射自动站数据分析及网络建设

选取北京市环境电磁辐射自动监测站点2年多的数据,利用SPSS统计软件,对各站点数据进行了主要电磁辐射源、长期数据趋势、各站点时间代表性分析;并结合网格法监测数据,对自动站点空间代表性进行分析。结果表明,5个环境电磁辐射自动站周围主要电磁辐射源均为移动通信基站;其总体电磁辐射水平为0.69~0.97 V/m,低于北京市1 V/m的电磁辐射环境本底水平,且单站点连续12个月的监测数据可以描述该点位电磁辐射平均水平和变化趋势;经分析,连续5年全市网格法电磁辐射射频电场的监测数据总体具有较好的一致性,但单站点的电磁辐射水平不能代表所在行政区的电磁辐射总体水平。提出了电磁辐射自动监测网络建设建议。