有关水环境修复技术的分析及探讨

随着人类社会的不断发展,人们生产生活活动的加剧,片面追求经济效益的工业超标排放、生活垃圾污染、恶意的植被破坏等行为造成了自然生态系统的进一步恶化,也给水生环境带来了极大破坏,人类在尝到水生环境破坏的苦果后,开始积极加强环境保护,并深入探索水生环境修复技术。基于此,本文对水环境修复相关概念及其主要技术进行了分析,以期能够进一步提升水环境治理成效,促进人与自然的和谐发展。     

Characteristics of nano-/ultrafine particle-bound PAHs in ambient air at an international airport

Concentrations of 22 polycyclic aromatic hydrocarbons (PAHs) were estimated for individual particle-size distributions at the airport apron of the Taipei International Airport, Taiwan, on 48 days in July, September, October, and December of 2011. In total, 672 integrated air samples were collected using a micro-orifice uniform deposition impactor (MOUDI) and a nano-MOUDI. Particle-bound PAHs (P-PAHs) were analyzed by gas chromatography with mass selective detector (GC/MSD). The five most abundant species of P-PAHs on all sampling days were naphthalene (NaP), phenanthrene (PA), fluoranthene (FL), acenaphthene (AcP), and pyrene (Pyr). Total P-PAHs concentrations were 152.21, 184.83, and 188.94 ng/m³ in summer, autumn, and winter, respectively. On average, the most abundant fractions of benzo[a]pyrene equivalent concentration (BaPeq) in different molecular weights were high-weight PAHs (79.29 %), followed by medium-weight PAHs (11.57 %) and low-weight PAHs (9.14 %). The mean BaPeq concentrations were 1.25 and 0.94 (ng/m³) in ultrafine particles (<0.1 μm) and nano-particles (<0.032 μm), respectively. The percentages of total BaPeq in nano- and ultrafine particulate size ranges were 52.4 % and 70.15 %, respectively.     

CeO2-CoO／ACF低温SCR烟气脱氮性能的研究

活性炭纤维（ACF）经硝酸处理后采用浸渍法制备了CeO2-CoO／ACF复合催化剂,测试了其在以氨气为还原剂的低温SCR过程中的催化活性,同时研究了金属氧化物浸渍顺序及负载量、催化剂煅烧温度、空速比（SV）、NH,／NO（摩尔比）、O2含量等因素对NO转化效率的影响。研究发现,负载量为10％的CeO2-CoO／ACF复合催化剂经煅烧后在120—240℃时具有很高的催化活性,并且在N0初始浓度为1000mg／m3、空速比（SV）为6000h～、NH3／NO为1．05、O：体积分数在3．0％时具有较高的NO转化效率。     

CeO_2-CoO/ACF低温SCR烟气脱氮性能的研究

活性炭纤维(ACF)经硝酸处理后采用浸渍法制备了CeO2-CoO/ACF复合催化剂,测试了其在以氨气为还原剂的低温SCR过程中的催化活性,同时研究了金属氧化物浸渍顺序及负载量、催化剂煅烧温度、空速比(SV)、NH3/NO(摩尔比)、O2含量等因素对NO转化效率的影响。研究发现,负载量为10%的CeO2-CoO/ACF复合催化剂经煅烧后在120~240℃时具有很高的催化活性,并且在NO初始浓度为1 000 mg/m3、空速比(SV)为6 000 h-1、NH3/NO为1.05、O2体积分数在3.0%时具有较高的NO转化效率。     

城市中农村迁移家庭的劳动供给行为分析

城市中农村迁移家庭的劳动供给行为一直是发展经济学研究的主题之一.本文建立了中国城市中农村迁移家庭的劳动参与模型和工作时间模型,用于分析城市中农村迁移家庭的劳动供给行为.研究结果表明:农村迁移劳动力劳动参与率高,工作时间长,主要在非正规部门就业;农村迁移家庭中女性和男性的教育收益率分别为3.71％和4.97％,且随着受教育年限的提高,男性工作时间将明显增加;身体健康不仅有助于女性劳动参与率的提高,而且有助于女性和男性工作时间的增加;随着年龄的增长,个体倾向于减少工作时间;但随着经验的增长,个体倾向于增加工作时间;女性工作时间的工资弹性和收入弹性分别为-0.261 3和-0.073 3,而男性工作时间的工资弹性为-0.3443,说明女性和男性的工作时间曲线均向右下倾斜;女性劳动参与的工资弹性为0.539 5,远高于工作时间的工资弹性.因此,政府通过发展农村教育和医疗服务,适当提高城市最低工资标准,将能够有效地促进农村迁移家庭就业水平和收入水平的提高.     

类Fenton反应对偶氮染料橙黄Ⅱ的脱色研究

以橙黄Ⅱ染料溶液为研究对象,通过正交实验确定了Fe-NTA/H2O2构成的类Fenton反应中各影响因子的最佳操作条件为:[H2O2]=20 mmol/L,[Fe-NTA]=2.5 mmol/L,pH=3.同时考察了反应时间、溶液pH值、H2O2浓度、Fe-NTA浓度对脱色效率的影响.实验表明脱色反应在30 min内基本完成,类Fenton试剂能在较宽的pH范围内保持较好的脱色效果,而且在pH=6时,类Fenton试剂比传统Fenton试剂的脱色效率提高约75%.增加双氧水浓度可以提高橙黄Ⅱ溶液脱色率,但超过20 mmol/L后效果提高不明显.在0.5～2.5 mmol/L的范围内,Fe-NTA浓度对脱色效果的影响不显著.     

中国进入WTO以来与欧盟棉花贸易的虚拟水资源总量研究

中国在与欧盟国家的商晶贸易中,直接进口的是初级农产品,但闻接进口的却是隐藏在这些农产最中的虚拟水.研究这些潜在的水资源,对缓解我国水资源压力,保障粮食安全具有重要的现实意义.本文采用联合国粮农组织FAO的CROPWAT Model计算模型,借助CropWat for Windows计算软件,从资源当量转换的角度出发,计算中国自进入WTO以来与欧盟国家的棉花贸易中水资源转换以及虚拟水贸易情况.计算结果表明,2003-2005年中国在与欧盟的棉花贸易中,间接进口了151.28×106m3的水资源,相当于节约了国内同等数量的水资源.本文可以为解决中国日益短缺的水资源问题提供有益参考.     

基于Verhulst模型的新建隧道顶板下沉预测研究

隧道顶板下沉量预测对隧道安全施工十分重要.通过分析隧道下沉过程,指出其具有"S"型曲线特征,探讨了采用Verhulst模型进行隧道顶板下沉预测的适用性和可行性,并运用MATLAB软件开发相关程序,模拟遵赤高速公路中枢隧道YK39+134.6断面沉降过程,获得相应的预测方程.通过对比其预测结果、回归分析预测结果和实测值,发现该模型的顶板沉降预测值与实测值最接近,证实运用灰色Verhulst模型预测隧道顶板沉降量是合理、可行的.     

水处理滤料填充床流动电位测定的可行性研究

根据流动电位与ζ电位的关系,设计研制了一台测定滤料表面流动电位的装置,并测定了石英砂、核桃壳、沸石滤料的流动电位.研究滤料流动电位的稳定时间及压差对稳定时间的影响,并讨论电解质溶液pH值对滤料流动电位的影响.结果表明,1)pH=7.0、压差为2 cm水柱时,石英砂、核桃壳和沸石流动电位的稳定时间分别为45 min、60 min和120 min;2)压差越大,各滤料流动电位的稳定时间越短,因此在保证水流流态为层流条件下,应尽量在大压差条件下测定流动电位;3)随着电解质溶液pH值的升高,各滤料流动电位由正值向负值转变,其中石英砂滤料的等电点约在pH=5.0,核桃壳和沸石滤料约在pH=3.0.可见,研究滤料表面的流动电位对提高过滤效率以及开发改性滤料十分重要.     

Effect of the milling solution on lead stabilization in municipal solid waste incinerator fly ash during the milling processes

The wet milling process had been found to effectively stabilize lead in fly ash. This study adopts this method and looks at the effect of different milling solutions to improve the efficiency of lead stabilization. Different milling solutions (water, phosphoric acid and ethanol) and different milling times (1, 24, 48 and 96 h) were selected as parameters. Since lead oxide can be identified by XRD in this experiment’s samples, 5% lead oxide was added to the extracted mixed fly ash to make instrumental analysis easier. The experimental results indicate that the effect of stabilization of lead after milling could exceed 96%. During milling with water, considerable lead leached into the water in the initial stage (1 h) of the process, but a stable level was reached as the milling time increased. After milling with ethanol and 0.2 M phosphoric acids, the efficiency could exceed 93% after 1 h of milling time. The results of the sequential extraction procedure (SEP) results show that the residual fraction could be increased from 8.93% to 56.16% when a 0.2 M phosphoric acid solution was used. Clearly the choice of an appropriate milling solution can enhance lead stabilization in the fly ash.