Removal efficiencies of PCDDs/PCDFs by air pollution control devices in municipal solid waste incinerators

Removal efficiencies of polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDDs/PCDFs) by air pollution control devices (APCDs) in the commercial-scale municipal solid waste (MSW) incinerators with a capacity of above 200 ton/day were evaluated. The removal efficiencies of PCDDs/PCDFs were up to 95% when the activated carbon (AC) was injected in front of electrostatic precipitator (EP). Spray dryer absorber/bag filter (SDA/BF) had high removal efficiency (99%)) of PCDDs/PCDFs when a mixture of lime and AC was sprayed into the SDA. When the AC was not added in scrubbing solution, the whole congeners of PCDDs/PCDFs were enriched in the wet scrubber (WS) with negative removal efficiencies of -25% to -5731%. Discharge of PCDDs/PCDFs was decreased with increasing the proportions of AC added in scrubbing solution. Selective catalytic reduction (SCR) system had the removal efficiencies of up to 93% during the test operation.     

Facile synthesis of graphene-based hyper-cross-linked porous carbon composite with superior adsorption capability for chlorophenols

In this work, we proposed a green and cost-effective method to prepare a graphene-based hyper-cross-linked porous carbon composite (GN/HCPC) by one-pot carbonization of hyper-cross-linked polymer (HCP) and glucose. The composite combined the advantages of graphene (GN) and hyper-cross-linked porous carbon (HCPC), leading to high specific surface area (396.93 m²/g) and large total pore volume (0.413 cm³/g). The resulting GN/HCPC composite was applied as an adsorbent to remove 2,4-dichlorophenol (2,4-DCP) from aqueous solutions. The influence of different solution conditions including pH, ionic strength, contact time, system temperature and concentration of humic acid was determined. The maximum adsorption capacity of GN/HCPC composite (calculated by the Langmuir model) could reach 348.43 mg/g, which represented increases of 43.6% and 13.6% over those of the as-prepared pure GN and HCPC, respectively. The Langmuir model and pseudo-second-order kinetic model were found to fit well with the adsorption process. Thermodynamic experiments suggested that the adsorption proceeded spontaneously and endothermically. In addition, the GN/HCPC composite showed high adsorption performance toward other organic contaminants including tetracycline, bisphenol A and phenol. Measurement of the adsorption capability of GN/HCPC in secondary effluent revealed a slight decrease over that in pure water solution. This study demonstrated that the GN/HCPC composite can be utilized as a practical and efficient adsorbent for the removal of organic contaminants in wastewater.     

磁性吸附剂CeO2/MZFS去除水中盐酸四环素

利用废碱性电池制备得到尖晶石结构的锰锌铁氧体Mn_0.6Zn_0.4Fe₂O₄（MZF）,利用原位聚合制备得到硅包覆的磁性纳米复合物MZF@SiO₂（MZFS）,采用浸渍法制备得到集磁分离、吸附与类Fenton催化活性于一体的CeO₂/MZFS磁性吸附剂,并对其形貌和磁性能等进行了表征.结果表明,CeO₂/MZFS对水中盐酸四环素（TH）表现出良好的吸附性能,160 min吸附过程可达平衡,TH的去除率达到95%.吸附过程可用准二级动力学方程描述,化学吸附为速控步骤;Freundlich等温吸附模型能较好地描述该吸附过程,热力学计算结果表明,CeO₂/MZFS对TH的吸附是以物理吸附为主的自发吸热过程;利用红外光谱初步揭示了吸附机制.吸附TH后的CeO₂/MZFS可利用其非均相类Fenton催化活性以H₂O₂作为再生剂进行原位再生,6次循环使用后,CeO₂/MZFS对TH仍能保持较高的平衡吸附量.研究结果可为抗生素废水的治理提供理论指导和技术支持.     

流动式二氧化硫快速遥测系统的原理与应用研究

介绍了流动式二氧化硫快速遥测系统的原理和测试方法，对该系统应用于遥测大气二氧化硫的空浓度分布，不的二氧化硫排放量和沉降量，烟羽的水平扩散参数σｙ和抬升高度△Ｈ进行了研究。     

A model of objective weighting for EIA

In spite of progress achieved in the research of environmental impact assessment (EIA), the problem of weight distribution for a set of parameters has not as yet, been properly solved. This paper presents an approach of objective weighting by using a procedure of P _ij principal component-factor analysis (P _ij PCFA), which suits specifically those parameters measured directly by physical scales. The P _ij PCFA weighting procedure reforms the conventional weighting practice in two aspects: first, the expert subjective judgment is replaced by the standardized measure P _ij as the original input of weight processing and, secondly, the principal component-factor analysis is introduced to approach the environmental parameters for their respective contributions to the totality of the regional ecosystem. Not only is the P _ij PCFA weighting logical in theoretical reasoning, it also suits practically all levels of professional routines in natural environmental assessment and impact analysis. Having been assured of objectivity and accuracy in the EIA case study of the Chuansha County in Shanghai, China, the P _ij PCFA weighting procedure has the potential to be applied in other geographical fields that need assigning weights to parameters that are measured by physical scales.     

钢渣预处理含铬废水及其废渣与铬渣的固化

用钢渣对含铬废水进行预处理，探讨了钢渣粒度、用量、废水pH值和添加硫酸亚铁还原剂的影响。结果表明，经硫酸亚铁还原处理后再用钢渣处理比单纯用钢渣处理的效果明显提高，采用钢渣／总铬质量比为40的100目钢渣处理经硫酸亚铁还原后的含铬废水，总铬和Cr^6＋去除率分别达79％和84％，采用钢渣柱进行的两级淋滤实验进一步表明该方法可作为工业上含铬废水处理的预处理段。处理后的废钢渣同工业铬渣一起进行水泥固化，标准养护20d后固化体表面Cr^6＋浸出率、破碎至5mm粒径以下和酸雨淋溶下的浸出液Cr^6＋浓度均符合安全标准，可作为普通建材或进行填埋处置。     

GIS支持下的土壤侵蚀量估算——以江西省泰和县灌溪乡为例

在地理信息技术（ＧＩＳ）的支持下，应用通用土壤侵蚀方程（ＵｎｉｖｅｒｓａｌＳｏｉｌＬｏｓｓＥｑｕａｔｉｏｎ，简称ＵＳＬＥ）估算了江西省泰和县灌溪乡的土壤侵蚀量。研究结果表明，当地表覆盖率大于１５％时，计算的结果与实测的数据有良好的相关性（０８７）。     

秦皇岛港煤三、四期码头及附近区域大气降尘环境污染分析

论述了煤炭港口大气降尘与煤尘污染的关系。通过对秦皇岛港煤三、四期码头及附近区域大气降尘的长期连续监测以及对资料进行整理，分析了大气降尘的分布特征，从而得到港口投产以来的煤尘污染变化及趋势。     

板料成形有限元分析的牛顿一致迭代算法

此文针对塑性成形有限元分析大增量加载的收敛性困难,推导了用于板料成形弹塑性有限元分析的牛顿一致迭代公式.数值算例表明,此迭代算法对于大增量步长加载,也能保证解的收敛,是无条件稳定的.     

赣东北中生代火山岩微量元素与稀土元素丰度及其演化

本文论述了赣东北中生代火山岩中微量元素与稀土元素在不同岩性岩相及时空上的分布规律:潜火山岩中Au、Ag、Cu、Pb、Zn平均含量高于火山岩,尤以中酸性岩中较高,Ⅰ,Ⅱ旋回高于其他旋回。稀土元素由Ⅰ向Ⅱ旋回,由扬子地体向华夏地体,由爆发相向溢流相、潜火山岩相,由偏基性向中酸性岩演化;稀土配分模式是“L”型,火山岩物质来源于下地壳的部分熔融。