Heavy metal distribution and speciation in the Northern Adriatic Sea

In the present study the concentrations of cobalt, copper, iron, manganese, zinc were analysed and the speciation of copper and zinc performed, with a summer and winter sampling, for two areas in the Northern Adriatic Sea and crossing at the farthest zones of the Po river-sea water interface. Results show that when salinity increases the concentrations of all investigated metals (with the exception of cobalt) present some degree of biogeochemical cycling. Copper is the element whose dissolved phase has the highest importance in metal transport across the salinity gradient. Results of speciation analysis demonstrate that the presence of excess amounts (5-8 fold) of unbound ligands confers a buffering capacity for potential inputs of dissolved metals into the Northern Adriatic Sea. The speciation of both copper and zinc in the dissolved phase was dominated by organic complexation.     

Flooding in Texas: Examination of Temporal Changes and Impacts of Tropical Cyclones

Annual maximum peak discharge measurements from 62 stations with a record of at least 70 years are used to assess extreme flooding in Texas at the regional scale. This work focuses on examination of the validity of the stationarity assumption and on the impact of tropical cyclones (TCs) on the upper tail of the flood peak distribution. We assess the validity of the stationarity assumption by testing the records for abrupt and gradual changes. The presence of abrupt changes in the first two moments of the flood peak distribution is assessed using the Lombard test. We use the Mann‐Kendall test to examine the presence of monotonic trends. Results indicate that violations of the stationarity assumption are most commonly caused by abrupt changes, which are often associated with river regulation. We fit the time series of stationary flood records with the generalized extreme value distribution to investigate whether TCs control the upper tail of the flood peak distribution. Our results indicate that TCs play a diminished role in shaping the upper tail of the flood peak distribution compared with areas of the eastern United States subject to frequent TCs.     

Transport and metabolic fate of sewage particles in a recipient stream

Although the implementation of wastewater treatment plants (WWTP) has dramatically increased the quality of surface waters in urbanized areas, WWTPs can still discharge noticeable amounts of solutes and particles to recipient streams. Although the fate of WWTP nutrients has received considerable attention, transport and in-stream transformation of sewage-derived particulate organic matter (SDPOM) have not. To investigate the transport and transformation of SDPOM in recipient streams, we experimentally injected fluorescently labeled SDPOM into a headwater stream and tracked its downstream fate at baseflow. Most SDPOM disappeared from the streamwater within a 160-m long reach with an average deposition velocity of 0.14 mm s(-1). We further coupled hydrometric measurements of specific water fluxes through the streambed interface with a mixing model to estimate streambed oxygen removal, and found significantly higher oxygen removal in the deposition (0.75 g O2 m(-2) d(-1)) than in the downstream post-deposition (0.36 g O2 m(-2) d(-1)) subreach. Contrary to our expectations, we did not detect any apparent effect of SDPOM deposition on streambed clogging. Our results show the capacity of a recipient stream to retain SDPOM and to reduce its downstream export, and thus contribute to a better understanding of ecosystem services of human-altered streams.     

A Cost-Effectiveness Analysis of Seminatural Wetlands and Activated Sludge Wastewater-Treatment Systems

A cost-effectiveness analysis was performed to evaluate the competitiveness of seminatural Free Water Surface (FWS) wetlands compared to traditional wastewater-treatment plants. Six scenarios of the service costs of three FWS wetlands and three different wastewater-treatment plants based on active sludge processes were compared. The six scenarios were all equally effective in their wastewater-treatment capacity. The service costs were estimated using real accounting data from an experimental wetland and by means of a market survey. Some assumptions had to be made to perform the analysis. A reference wastewater situation was established to solve the problem of the different levels of dilution that characterize the inflow water of the different systems; the land purchase cost was excluded from the analysis, considering the use of public land as shared social services, and an equal life span for both seminatural and traditional wastewater-treatment plants was set. The results suggest that seminatural systems are competitive with traditional biotechnological systems, with an average service cost improvement of 2.1-fold to 8-fold, according to the specific solution and discount rate. The main improvement factor was the lower maintenance cost of the seminatural systems, due to the self-regulating, low artificial energy inputs and the absence of waste to be disposed. In this work, only the waste-treatment capacity of wetlands was considered as a parameter for the economic competitiveness analysis. Other goods/services and environmental benefits provided by FWS wetlands were not considered.

Effects of riparian forest buffers on in-stream nutrient retention in agricultural catchments

In northeastern Austria, marshlands have been turned into the most productive arable land of the country. As a result, most headwater streams show structurally degraded channels, lacking riparian buffer zones, which are heavily loaded with nutrients from the surrounding crop fields. The present study examines whether longitudinally restricted riparian forest buffers can enhance the in-stream nutrient retention in nutrient-enriched headwater streams. We estimated nutrient uptake from pairwise, short-term addition experiments with NH, NH, PO, and NaCl within reaches with riparian forest buffers (RFB) and degraded reaches (DEG) of the same streams. Riparian forest buffers originated from the conservation of the pristine vegetation or from restoration measures. Hydrologic retention was calculated with the model OTIS-P on the basis of conductivity break-through curves from the salt injections. A significant increase in surface transient storage was revealed in pristine and restored RFB reaches compared with DEG reaches due to the longitudinal step-pool pattern and the frequent occurrence of woody debris on the channel bed. Ammonium uptake lengths were significantly shorter in RFB reaches than in DEG reaches, resulting from the higher hydrologic retention. Uptake velocities did not differ significantly between RFB and DEG reaches, indicating that riparian forest buffers did not affect the biochemical nutrient demand. Uptake of NH was mainly driven by autotrophs. Net PO uptake was not affected by riparian forest buffers. The study shows that the physical and biogeochemical effects of riparian forest buffers on the in-stream nutrient retention are limited in the case of highly eutrophic streams.     

Validation of a Lagrangian dispersion model implementing different kernel methods for density reconstruction

In this paper the inert version of a Lagrangian particle model named photochemical Lagrangian particle model (PLPM) is described and validated. PLPM implements four density reconstruction algorithms based on the kernel density estimator. All these methods are fully grid-free but they differ each other in considering local or global features of the particles distribution, in treating the Cartesian directions separately or together and in being based on receptors or particles positions in space. Each kernel has been shown to have both advantages and disadvantages, but the overall good performances of the model when compared with the well known Copenhagen and Kincaid data sets are very encouraging in view of its extension to fully chemically active simulations, currently under development.     

Aktuelle Entwicklungen bei Umweltindikatorensystemen

The current monitoring of the status of the environment and natural resources is a substantial basis for the implementation of a sustainable development as a model of the environmental policy in the terms of Agenda 21. For the 90s, in particular by the mandate of Rio 1992, both the international institutions (international level), e.g. the OECD, the United Nation Commission of Sustainable Development and the European Environmental Agency, and the environmental protection authorities of the different countries (national level) e.g. Germany, and of the federal states of Germany (regional level) are developing environmental indicator systems. In the context of the Local Agenda 21, indicators for the ecological, economic, social and institutional categories are set up on a communal level. In the environmental indicator systems different issues, e.g. climate change, ozone layer depletion, water quality and water resources, waste, toxic contamination, biodiversity, landscape protection, soil resources, forest resources, etc., are described. Concepts with driving forces, pressure, state, impact and/or response indicators are applied. The German Council of Environmental Advisors (SRU) requires that the selection and aggregation of indicators must be transparent and comprehensibly documented and that the chosen indicators must be oriented at political targets. The following article gives an overview of relevant actual environmental indicator systems, their concepts and structuring, and points to the further research and developmental requirements within this area.     

Fitness benefits of multiple mating versus female mate choice in the cellar spider (Pholcus phalangioides)

Recent studies have demonstrated that mating with multiple males can be beneficial for females and her offspring even if males contribute nothing but sperm. This was mainly established for species in which sperm from several males mix in the reproductive tract of the female, thus allowing sperm competition and/or female sperm choice. However, in species with last male sperm precedence, female re-mating decides against the previous male by strongly limiting his reproductive success. We tested the effect of female re-mating behaviour using the cellar spider Pholcus phalangioides, which shows strong last males sperm precedence and moderate levels of polyandry under natural situations. We predicted that females prevented from remating even though they are receptive would show reduced reproductive success compared to females that accept two copulations and females that reject a second male, since the latter two treatments were allowed to behave according to their decisions. However, if the number of matings per se had an effect on oviposition or on offspring performance, double-mated females should perform better compared to both treatments of once-mated females. We measured female fecundity and fertility over a period of 140 days, comparable to the species' natural reproductive peak season. Two thousand one hundred and fifty-two offspring from 67 first egg sacs were reared under two feeding levels. We registered development time and survival, and measured offspring adult size and mass. We found a positive effect of double mating, as in this treatment, oviposition probability was higher compared to the other treatments. Interestingly, adult female offspring of the DM treatment that were raised under low food level had a higher condition index compared to those from FS and RM, but development time, size and mass at adulthood were not affected by mating treatment. Female choice only seemed to affect hatching latency of the offspring. Overall, the main predictor of female reproductive output and success was female body size.     

Ozone pollution and ozone biomonitoring in European cities. Part I: Ozone concentrations and cumulative exposure indices at urban and suburban sites

In the frame of a European research project on air quality in urban agglomerations, data on ozone concentrations from 23 automated urban and suburban monitoring stations in 11 cities from seven countries were analysed and evaluated. Daily and summer mean and maximum concentrations were computed based on hourly mean values, and cumulative ozone exposure indices (Accumulated exposure Over a Threshold of 40 ppb (AOT40), AOT20) were calculated. The diurnal profiles showed a characteristic pattern in most city centres, with minimum values in the early morning hours, a strong rise during the morning, peak concentrations in the afternoon, and a decline during the night. The widest amplitudes between minimum and maximum values were found in central and southern European cities such as Düsseldorf, Verona, Klagenfurt, Lyon or Barcelona. In the northern European cities of Edinburgh and Copenhagen, by contrast, maximum values were lower and diurnal variation was much smaller. Based on ozone concentrations as well as on cumulative exposure indices, a clear north–south gradient in ozone pollution, with increasing levels from northern and northwestern sites to central and southern European sites, was observed. Only the Spanish cities did not fit this pattern; there, ozone levels were again lower than in central European cities, probably due to the direct influence of strong car traffic emissions. In general, ozone concentrations and cumulative exposure were significantly higher at suburban sites than at urban and traffic-exposed sites. When applying the newly established European Union (EU) Directive on ozone pollution in ambient air, it was demonstrated that the target value for the protection of human health was regularly surpassed at urban as well as suburban sites, particularly in cities in Austria, France, northern Italy and southern Germany. European target values and long-term objectives for the protection of vegetation expressed as AOT40 were also exceeded at many monitoring sites.